Crystallization behaviour and phase coexistence at morphotrophic phase boundaries in PZT thin films prepared by sol-gel processing

Pb(Zr_0.53Ti_0.47)O₃ (PZT) thin films, prepared by sol-gel techniques and deposited on to Si/SiO₂/Ti/Pt substrates, have been subjected to thermal annealing in a range of temperatures from 550–800 °C. The crystallization behaviour and phase coexistence (tetragonal and rhombohedral) were studied by X-ray diffraction. According to the values of the {110} peak intensity and {110} peak values, the crystallization full-width at half-maximum was more complete at higher temperatures (750, 800 °C). At a fixed Zr/Ti ratio close to the morphotropic phase boundary, the lattice parameters of the two phases changed with the annealing temperature. However, the tetragonality degree had relatively low values and the angular rhombohedral distortion was associated with a narrow angular range. The phase coexistence and the variation of the lattice parameters could be explained by the titanium diffusion through the platinum layer. Thus the formation of a {0 1 1} titanium rich layer at Pt-PZT interface will supply a titanium excess for the nucleation and growth of textured PZT grains.     

CMMN evaluation: the modelers’ perceptions of the main notation elements

Software and Systems Modeling - Case Management Model and Notation (CMMN) has been introduced as a graphical modeling language targeting the modeling of human-centric processes. Despite its growing...     

Semantic Web computing in industry

The Semantic Web has attracted significant attention during the last decade. On the one hand, many research groups have changed their focus towards Semantic Web research and research funding agencies particularly in Europe have explicitly mentioned Semantic Web in their calls for proposals. On the other hand, industry has also begun to watch developments with interest and a number of large companies have started to experiment with Semantic Web technologies to ascertain if these new technologies can be leveraged to add more value for their customers or internally within the company, while there are already several offers of vendors of Semantic Web solutions on the market. The essence of the Semantic Web is to structure Web-based information to make it more interoperable, machine-readable and thereafter to provide a means to relate various information concepts more easily and in a reusable way. The Semantic Web acts as an additional layer on the top of the Web, and is built around explicit representations of information concepts and their relationships such as ontologies and taxonomies. Furthermore, Semantic Web technologies are not only valuable on an open environment like the Web, but also in closed systems such as in industrial settings. Hence, these technologies can be efficiently deployed for domains including Web Services, Enterprise Application Integration, Knowledge Management and E-Commerce, fulfilling existing gaps in current applications. This paper focuses on this synthesis between Semantic Web technologies and systems problems within industrial applications. There will be a short review of Semantic Web standards, languages and technologies followed by a more detailed review of applications of Semantic Web computing in industry. The paper covers theoretical considerations as well as use cases and experience reports on the topic, and we also present some current challenges and opportunities in the domain.     

Analytical and graphical evaluation of local quasi-stable angular points during ion bombardment at oblique incidence

An implied analytical condition, connecting the incidence angles _o and _e between the two intersecting microfacet normals and the ion beam direction, has been inferred for the existence of local quasi-stable intersections (angular points) during ion erosion. This condition, which can also be deduced on the basis of the erosion slowness curve, leads to a higher degree algebraic equation with a parameter, applicable for any dependence S=S (), expressed as an algebraic polynomial expression in cos . A new graphical method for evaluation of orientations _e compatible with a given orientation _o, based on a known polar diagram cursor-type, has also been proposed.     

SEM investigations of iron surface ion erosion as a function of specimen temperature and incidence angle

Ion bombardment of iron surfaces produced an ion eroded surface microtopography strongly dependent on the incidence angle and specimen temperature. For bombardment temperatures exceeding the self-diffusion temperature, T _d, a microstructural smoothing process due to the thermally activated diffusion effects, assisted by ion bombardment, can be observed by SEM. The role of migrational processes which should be taken into account for a correct interpretation of the final surface topography formed by hot sputtering, was also considered.     

Synthesis and characterization of a titanium phosphate-tellurite glass for Faraday rotators

This work is focused on investigation of thermal, structural, optical, magnetic, and magneto-optical properties of novel titanium phosphate-tellurite glass applied as Faraday rotators. The glass belonging to the system 35Li₂O–10Al₂O₃–5TiO₂–45P₂O₅–5TeO₂ was prepared by a nonconventional wet route of raw materials processing, followed by melting-quenching-annealing steps. Some important physical properties of the investigated glass have been measured and calculated, providing knowledge related to glass compactness, electronic structure, glass forming capability, etc. XRD analysis evidenced an amorphous network structure of the investigated glass. The optical absorption in the Vis domain is mainly due to Ti³⁺ ions and Te₂ clusters formed during the glass melting process. A relatively low optical absorption is noticed over 600 nm that activates a significant Faraday magneto-optical effect. Photoluminescence bands in the blue, red, and infrared domains are observed, caused by Te₂ clusters formed during the glass melting process. The magnetization in dependency on applied magnetic field reveals a complex behavior of the glass, depending on temperature. Thus, it is found a ferromagnetic behavior up to 2000 Oe, a paramagnetic component up to 40 000 Oe, followed by a diamagnetic one over 40 000 Oe. Faraday rotation angle and Verdet constant values in the visible domain are correlated with the reduced TeO₂ content of the glass.     

Cellular and Molecular Targets for Non-Invasive,Non-Pharmacological Therapeutic/Rehabilitative Interventions in Acute Ischemic Stroke

BACKGROUND: Cerebral circulation delivers the blood flow to the brain through a dedicated network of sanguine vessels. A healthy human brain can regulate cerebral blood flow (CBF) according to any physiological or pathological challenges. The brain is protected by its self-regulatory mechanisms, which are dependent on neuronal and support cellular populations, including endothelial ones, as well as metabolic, and even myogenic factors. OBJECTIVES: Accumulating data suggest that “non-pharmacological” approaches might provide new opportunities for stroke therapy, such as electro-/acupuncture, hyperbaric oxygen therapy, hypothermia/cooling, photobiomodulation, therapeutic gases, transcranial direct current stimulations, or transcranial magnetic stimulations. We reviewed the recent data on the mechanisms and clinical implications of these non-pharmaceutical treatments. METHODS: To present the state-of-the-art for currently available non-invasive, non-pharmacological-related interventions in acute ischemic stroke, we accomplished this synthetic and systematic literature review based on the Preferred Reporting Items for Systematic Principles Reviews and Meta-Analyses (PRISMA). RESULTS: The initial number of obtained articles was 313. After fulfilling the five steps in the filtering/selection methodology, 54 fully eligible papers were selected for synthetic review. We enhanced our documentation with other bibliographic resources connected to our subject, identified in the literature within a non-standardized search, to fill the knowledge gaps. Fifteen clinical trials were also identified. DISCUSSION: Non-invasive, non-pharmacological therapeutic/rehabilitative interventions for acute ischemic stroke are mainly holistic therapies. Therefore, most of them are not yet routinely used in clinical practice, despite some possible beneficial effects, which have yet to be supplementarily proven in more related studies. Moreover, few of the identified clinical trials are already completed and most do not have final results. CONCLUSIONS: This review synthesizes the current findings on acute ischemic stroke therapeutic/rehabilitative interventions, described as non-invasive and non-pharmacological.     

Synthesis of MgAl2O4 Spinel Powder by Combination of Sol–Gel and Precipitation Processes

MgAl₂O₄ spinel precursor was prepared by a novel method combining a sol–gel process with the "traditional" precipitation process. The thermal decomposition and phase development of the precursor were analyzed, and the degree of agglomeration of the calcined powder was assessed by determining its particle size and crystal size. The optimum calcination temperature was determined based on the variation of specific surface areas, crystal size, and particle size. Completely crystallized ultrafine spinel powder ( d ₅₀=600 nm, specific surface area=105 m²/g) was obtained after calcination at 900°C.     

IGAA and XRF methods used in oil contamination research

The release of trace metals from oil industry in ecosystems represents a serious hazard for the Biosphere, because of their toxicity. The objective of the study is to identify the source and evaluate the effect of key contaminants and other toxic and non-toxic bioactive elements as well as to provide the basis for improved health for human population by the use of instrumental gamma-activation analysis in combination with the X-ray fluorescence technique.The analytical work consisted in measuring trace concentrations of specific oil industry pollutants in soil and river sediments from the region of oil refinery industry in Ploiesti city, Romania.A highly sensitive photon neutron activation method based on the (γ, n) reactions for determining the concentrations of trace heavy metals in the environmental samples is applied. Additionally, the replicate samples were investigated by the X-ray fluorescence analysis.Further the results were used to develop an approach based on the geostatistical modelling to update the estimates of heavy metal concentrations on the ground in order to quantify their extent in the region in relation with the emission sources.     

Synthesis,structural characterization,and photocatalytic properties of iron-doped TiO<Subscript>2</Subscript> aerogels

Fe(III)-doped TiO₂ aerogels are prepared by acid catalyzed sol–gel method followed by supercritical drying, and then heat treatment. Raman spectra together with X-ray diffraction (XRD) and selected area electron diffraction (SAED) patterns of the iron-doped TiO₂ aerogel samples revealed the existence of both anatase and brookite crystalline phases. It was found that the brookite phase formation is favored by the increase of the iron content in the dried samples. XRD measurements show that the lattice constant c of anatase phase decreases with the dopant addition, while the value of a remains essentially unchanged. The microstructure of the investigated samples is relatively compact with small mesopores as revealed from transmission electron microscopy (TEM). The most enhanced photocatalytic activity was exhibited by the TiO₂ aerogel sample with 1.8 at.% Fe(III) whose apparent rate constant of the salicylic acid photodegradation was found to be of almost six times higher than that of Degussa P25.