High energy storage and ultrafast discharge in NaNbO3-based lead-free dielectric capacitors via a relaxor strategy

Dielectric capacitors with decent energy storage and fast charge-discharge performances are essential in advanced pulsed power systems. In this study, novel ceramics (1-x)NaNbO₃-xBi(Ni_2/3Nb_1/3)O₃(xBNN, x = 0.05, 0.1, 0.15 and 0.20) with high energy storage capability, large power density and ultrafast discharge speed were designed and prepared. The impedance analysis proves that the introducing an appropriate amount of Bi(Ni_0·5Nb_0.5)O₃ boosts the insulation ability, thus obtaining a high breakdown strength (E_b) of 440 kV/cm in xBNN ceramics. A high energy storage density (W_total) of 4.09 J/cm³, recoverable energy storage density (W_rec) of 3.31 J/cm³, and efficiency (η) of 80.9% were attained in the 0.15BNN ceramics. Furthermore, frequency and temperature stability (fluctuations of W_rec ≤ 0.4% over 5–100 Hz and W_rec ≤ 12.3% over 20–120 °C) were also observed. The 0.15BNN ceramics exhibited a large power density (19 MW/cm³) and ultrafast discharge time (~37 ns) over the range of ambient temperature to 120 °C. These enhanced performances may be attributed to the improved breakdown strength and relaxor behavior through the incorporation of BNN. In conclusion, these findings indicate that 0.15BNN ceramics may serve as promising materials for pulsed power systems.     

一种5 重real-time PCR筛查转基因水稻方法的建立

以转基因水稻中最常用的CaMV35S启动子、NOS终止子、Cry1Ab/Ac基因、HPT基因及SPS水稻内标基因为研究对象，利用5 种不同的荧光信号（FAM、HEX、Taxas Red、Cy5、Cy5.5）进行多重实时聚合酶链式反应（real-time polymerase chain reaction，real-time PCR）检测方法的研究。通过引物组合筛选、反应体系优化、特异性测试、灵敏度测试、适用性测试等一系列实验，建立了5 重real-time PCR方法，灵敏度可达0.032%。此方法具有灵敏度高、结果准确、通量大等优点，可实现水稻中转基因成分的快速、高效检测。     

裂纹对石墨烯拉伸力学性能影响的数值仿真

为研究裂纹对石墨烯力学性能的影响,以锯齿型石墨烯为研究对象,基于分子动力学方法,采用Tersoff势函数分析裂纹长度对石墨烯拉伸力学性能的影响以及含有裂纹的石墨烯在不同应变率下的拉伸变形破坏过程.结果表明,裂纹长度的增加大大减小石墨烯的抗拉强度和抗拉应变,对弹性模量有一定影响;裂纹降低石墨烯的抗拉应变对应变率的敏感性,但对于含有裂纹的石墨烯,仍可以增大加载速率来提高石墨烯的抗拉性能.     

Preparation and Bioactivity of Iridium(III) Phenanthroline Complexes with Halide Ions and Pyridine Leaving Groups

A series of half-sandwich structural iridium(III) phenanthroline (Phen) complexes with halide ions (Cl⁻, Br⁻, I⁻) and pyridine leaving groups ([(η⁵-Cp^X)Ir(Phen)Z](PF₆)_n, Cp^x: electron-rich cyclopentadienyl group, Z: leaving group) have been prepared. Target complexes, especially the Cp^xbiph (biphenyl-substituted cyclopentadienyl)-based one, showed favourable anticancer activity against human lung cancer (A549) cells; the best one ( Ir8 ) was almost five times that of cisplatin under the same conditions. Compared with complexes involving halide ion leaving groups, the pyridine-based one did not display hydrolysis but effectively caused lysosomal damage, leading to accumulation in the cytosol, inducing an increase in the level of intracellular reactive oxygen species and apoptosis; this indicated an anticancer mechanism of oxidation. Additionally, these complexes could bind to serum albumin through a static quenching mechanism. The data highlight the potential value of half-sandwich iridium(III) phenanthroline complexes as anticancer drugs.     

一种基于改进遗传算法的粗糙集属性约简算法磁

为解决传统遗传算法在属性约简时会出现迭代次数多,收敛较慢的问题,论文提出了一种改进的遗传算法。该方法在适应函数上加入属性重要度因子,同时在交叉操作中有选择地保留子代个体,确保算法能够快速收敛。实验结果证明,改进之后的算法在保证属性约简的基础上,能够实现比传统遗传算法更快的迭代和收敛。     

2000年以来黄河宁蒙河段开河期冰凌洪水特点分析

黄河宁蒙河段开河期冰凌洪水主要集中在3月中下旬,一般由融冰洪水与冰坝洪水组成,其特点主要表现在:凌峰、洪量年际变化大,沿程增加明显,头道拐站易形成多峰,峰型系数较夏汛小,洪水历时较夏汛短,水位表现较夏汛同流量水位高,流速在涨水段慢于落水段。这些特点主要与宁蒙河道形态、水利工程、封河期上游来水及开河期气温、开河形势、封冻期形成的槽蓄水增量大小、沿程分布及其释放程度有关。     

粗纱工艺参数的优化配置研究

对粗纱工序影响成纱质量的工艺参数进行了全方位的分析,发现影响粗纱成纱质量的工艺参数主要有锭翼速度、前区隔距、主牵伸区隔距、后区隔距、后区牵伸倍数、上下销钳口隔距和捻系数等.针对这些工艺参数在粗纱机上进行正交试验,纺制普梳纯棉18.2 tex纱线,对产生的数据进行极差和方差分析,优选出能够获得最佳粗纱成纱质量的工艺参数.对得到的工艺参数上机试验并纺制成细纱测试其质量,其成纱质量数值在乌斯特2007年公报5%水平以内,说明优选的工艺参数可以应用于生产实践,对生产企业探索其他品种的工艺参数配置具有理论和实践指导意义.     

Catechol-containing waterborne polyurethane adhesive inspired by mussel proteins

A series of waterborne polyurethane (PDMAPU) containing catechol group were prepared by double-bond random copolymerization of terminated double bond polyurethane prepolymer with modified acrylamido dopamine under thermal initiation. This kind of mussel-like waterborne polyurethane adhesive is inspired by marine mussel, as well as it is environment-friendly and used in bonding of leather. FTIR and ¹H NMR proved the successful introduction of catechol group into polyurethane matrix. Oxidative cross-linking between catechol unit and molecular chain in PDMAPU structure, the thermal stability and crystallization ability of PDMAPU was significantly improved. The increase of the particle size of PDMAPU emulsion showed that the introduction of catechol group changed the microstructure of polyurethane and enhanced the cross-linking degree. The water resistance of polyurethane emulsion was further improved. Compared with PU without catechol group, the peel strength of leather substrate adhered by PDMAPU emulsion increased from 0.42 to 1.93 MPa, which indicated that PDMAPU has better bonding properties with leather. The bidentate hydrogen bond formed with catechol group as the reaction sites is considered to be the key reason for the adhesion of mussel-like polyurethane adhesive to hydrophilic substrates. This work provides an alternative to prepare environment-friendly high performance adhesive for hydrophilic substrates.     

融合梯度信息与HVS滤波器的无参考清晰度评价

目的 目前无参考图像质量评价算法的性能存在较大的提升空间,为了提高清晰度评价技术,提出了一种基于梯度信息与HVS滤波器的无参考清晰度评价算法(GI-F)。方法 该算法首先利用梯度算子计算各像素点的梯度信息,再通过HVS滤波器得到加权和作为图像的清晰度指标。结果 在公开数据库LIVE、TID2008和CSIQ上进行的实验,GI-F与S3(Spectral and Spatial Sharpness)、CPBD(Cumulative Probability of Blur Detection)和LPC-SI(Local Phase Coherence-based Sharpness Index)相比,性能指标RMSE(Root Mean Squared Error)、PLCC(Pearson Linear Correlation Coefficient)和SROCC(Spearman Rank-Order Correlation Coefficient)分别提升了20.66%、4.61%和3.33%;同时GI-F还具有更低的计算复杂度,即使与目前最好的BRISQUE(Blind/Referenceless Image Spatial QUality Evaluator)算法相比,耗时也降低了79.72%。结论 该算法只需耗费更少的时间即可计算出与人眼感知更加接近的客观清晰度指标,可广泛用于无参考图像情况下的清晰度指标计算场合,同时还可以通过并行计算进一步降低其计算时间。