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排序方式: 共有324条查询结果,搜索用时 15 毫秒
1.
Dhirendra Kumar Mishra Gopal Pugazhenthi Tamal Banerjee 《International Journal of Hydrogen Energy》2021,46(29):15773-15779
The current work explores the usage of novel synthesized Deep Eutectic Solvent (DES) as a catalyst cum solvent media for the thermal dehydrogenation of chemical hydrides, namely Ammonia Borane (AB) and Ethylene diamine bisborane (EDAB). In the first instance, the quantum chemistry based COSMO-SAC (COnductor like Screening MOdel Segment Activity Coefficient) model was used for the selection of the pertinent solvent. 1-Butyl-3-methylimidazolium methanesulfonate: Imidazole ([BMIM][MeSO3]:[Im]) turned out to be an ideal eutectic mixture with the highest predicted solubility with amine boranes. The DES was synthesized by combining the Hydrogen Bond Acceptor (HBA), namely 1-Butyl-3-methylimidazolium methanesulfonate and Imidazole as Hydrogen Bond Donor (HBD) at a molar ratio of 1:2 and T = 70 °C. The formation of DES was confirmed by recording the NMR spectra. Further, the thermal dehydrogenation study was performed at a vacuum of 4 × 10?2 mbar (gauge pressure) of AB/DES and EDAB/DES systems at 105 °C, where a hydrogen equivalent of 1.40 and 2.55 was produced, respectively. The residual samples were further analyzed through 1H NMR analysis for the reaction mechanism and to confirm the role of Ionic Liquid-based DES as catalyst cum solvent media. 相似文献
2.
Tek Bahadur Gurung Ram Prasad Dhakal Jay Dev Bista 《Lakes & Reservoirs: Research and Management》2006,11(3):141-148
The seasonal patterns of phytoplankton primary production, chlorophyll‐a concentration, cell number and several other limnological variables in Lake Phewa, located in the active monsoon zone in Central Himalaya, Nepal, were studied for a year beginning in April 2001. During the study period, the gross primary production and chlorophyll‐a concentrations were relatively low during the monsoon season. The phytoplankton cell number, represented by 24 genera, also fluctuated seasonally, but tended to increase in the pre‐ and post‐monsoon period. These results suggest that the monsoon plays a crucial role in the primary production and phytoplankton dynamics for Lake Phewa. Among the phytoplankton species, Microcystis aeruginosa, a representative species for eutrophic lakes, was the dominant phytoplankton. At the same time, however, it is clear that the lake is not yet heavily eutrophic. The present study suggests that the exchange of lake water during the monsoon season contributes to maintaining the health of the lake against further degradation. Nevertheless, the silt carried in the monsoon rain run‐off from the lake's catchment area suggests increasingly serious degradation problems for this small mountainous lake. 相似文献
3.
Ferrite particles coated with biocompatible phases can be used for hyperthermia treatment of cancer. We have synthesized substituted
calcium hexaferrite, which is not stable on its own but is stabilized with small substitution of La. Hexaferrite of chemical
composition (CaO)0.75(La203)0.20(Fe2O3)6 was prepared using citrate gel method. Hydroxyapatite was prepared by precipitating it from aqueous solution of Ca(NO3)2 and (NH4)2HPO4 maintaining pH above 11. Four different methods were used for coating of hydroxyapatite on ferrite particles. SEM with EDX
and X-ray diffraction analysis shows clear evidence of coating of hydroxyapatite on ferrite particles. These coated ferrite
particles exhibited coercive field up to 2 kOe, which could be made useful for hysteresis heating in hyperthermia. Studies
by culturing BHK-21 cells and WBC over the samples show evidence of biocompatibility. SEM micrographs and cell counts give
clear indication of cell growth on the surface of the sample. Finally coated ferrite particle was implanted in Kasaulli mouse
to test its biocompatibility. The magnetic properties and biocompatibility studies show that these hydroxyapatite coated ferrites
could be useful for hyperthermia. 相似文献
4.
Tek Bahadur Gurung 《Lakes & Reservoirs: Research and Management》2007,12(4):237-246
Lake Rupa is a small, subtropical, shallow lake with a surface area of 100 ha situated 600 m a.s.l. in Central Himalaya, Nepal. This degraded lake was studied between 2000 and 2006, with the goal of determining whether or not it could be restored by a community‐based cooperative of local people living in its catchment. Main threats to the lake, its aquatic life and its very existence include encroachment by excessive aquatic vegetation, sedimentation, and low in‐lake concentrations of dissolved oxygen (DO). Small lakes (≤ 500 ha) are relatively prone to the process of ‘succession and climax’, although they also can be of social, environmental and ecological importance. Thus, their disappearance could spark social chaos and disorder in areas already having to cope with other rapid environmental changes. This means that credible mechanisms for revitalizing or protecting small lakes are an important goal. Accordingly, a lake cooperative of 329 households living in close vicinity to Lake Rupa was formed in 2002, by prioritizing traditional fishers, women and other deprived community members with the goals of respecting the citizenry and equity. Following the cooperative's campaigns directed at weed removal and fish stocking, encroachment of vegetation on the lake margins was halted, its aquatic weeds became under control, and its fisheries improved. In addition to the cooperative's restoration activities, several water quality parameters, including water transparency and DO and chlorophyll‐a concentrations, were monitored on a monthly basis. The measured water transparency was inconsistent, exhibiting large variations between 2000 and 2003. Relatively low, but consistent, values, however, were measured after 2004. The results imply that the removal of weeds, and sufficient nutrients and solar radiation are subsequently available to the lake's phytoplankton communities. Supporting this notion is that the chlorophyll‐a concentration spiked to 205 µg L−1 in November 2006, the water transparency became consistent, and the DO concentration increased to >3.8 mg L−1 during the critical months (March–May) after 2004. These water quality indicators indicated improvement in the degraded Lake Rupa, suggesting that the establishment of cooperatives such as that highlighted in this study could be a powerful and sustainable mechanism for restoring degraded lakes in similar socioeconomic settings by maintaining equity, by connecting communities with their resources, and by facilitating integrity, equity, citizenry and social justice. 相似文献
5.
Several parameters and their limitations to prepare monodisperse polystyrene particles were discussed. Polystyrene latexes B, C and D of diameter 129.8, 142.8 and 264.5 nm, respectively, were synthesized by emulsion polymerization method. The latex D is almost monodisperse with very low polydispersity of 0.005 while B and C are having polydispersity of 0.1837 and 0.1601. The particle size and particle size distribution of the latexes were determined by a TEM and Brookhaven particle size analyzer. It was observed that the particle size of the latexes decreased with increasing initiator (ammonium persulfate) or surfactant (SDS) concentrations. The surface area of the latexes were calculated by using BET equation on the basis of the amount of nitrogen gas adsorbed at the surface of the particles to form a monolayer. It was observed that the surface area of latex D is less than B and C because of the bigger size of the particles. The average molecular weights, zeta potentials and densities of the latexes were also presented. 相似文献
6.
Intermetallic phases in Al-Mn alloys 总被引:3,自引:0,他引:3
Aruna Bahadur 《Journal of Materials Science》1988,23(1):48-54
The intermetallic phases present in high-purity and commercial purity Al-Mn alloys (up to 2% Mn) in as-cast and heat-treated conditions were extracted electrolytically in 10% HCl in methanol solution and identified by X-ray diffraction. As iron is known to increase the coarse cast-intermetallic particles and to cause refinement of the grain size after recrystallization, different amounts of iron (up to 0.5%) were added and the resulting intermetallic phases were extracted and identified with and without heat treatment. The unidentified phase -Al (Mn, Fe)Si, reported by Sperry and others, was recognized as corresponding for ASTM card number 6-0669 and the conditions favourable for its formation were determined. This phase may be responsible for refining the grain size after recrystallization in commercial purity alloys as compared to high-purity Al-Mn alloys and may therefore be tried as an inoculant (by adding powdered compound to liquid alloys) for grain refining. 相似文献
7.
Faisal Bahadur Arif Iqbal Umar Insaf Ullah Fahad Algarni Muhammad Asghar Khan 《计算机系统科学与工程》2022,42(2):589-604
Scalability is one of the most important quality attribute of software-intensive systems, because it maintains an effective performance parallel to the large fluctuating and sometimes unpredictable workload. In order to achieve scalability, thread pool system (TPS) (which is also known as executor service) has been used extensively as a middleware service in software-intensive systems. TPS optimization is a challenging problem that determines the optimal size of thread pool dynamically on runtime. In case of distributed-TPS (DTPS), another issue is the load balancing b/w available set of TPSs running at backend servers. Existing DTPSs are overloaded either due to an inappropriate TPS optimization strategy at backend servers or improper load balancing scheme that cannot quickly recover an overload. Consequently, the performance of software-intensive system is suffered. Thus, in this paper, we propose a new DTPS that follows the collaborative round robin load balancing that has the effect of a double-edge sword. On the one hand, it effectively performs the load balancing (in case of overload situation) among available TPSs by a fast overload recovery procedure that decelerates the load on the overloaded TPSs up to their capacities and shifts the remaining load towards other gracefully running TPSs. And on the other hand, its robust load deceleration technique which is applied to an overloaded TPS sets an appropriate upper bound of thread pool size, because the pool size in each TPS is kept equal to the request rate on it, hence dynamically optimizes TPS. We evaluated the results of the proposed system against state of the art DTPSs by a client-server based simulator and found that our system outperformed by sustaining smaller response times. 相似文献
8.
Urban growth modeling of Kathmandu metropolitan region, Nepal 总被引:6,自引:0,他引:6
The complexity of urban system requires integrated tools and techniques to understand the spatial process of urban development and project the future scenarios. This research aims to simulate urban growth patterns in Kathmandu metropolitan region in Nepal. The region, surrounded by complex mountainous terrain, has very limited land resources for new developments. As similar to many cities of the developing world, it has been facing rapid population growth and daunting environmental problems. Three time series land use maps in a fine-scale (30 m resolution), derived from satellite remote sensing, for the last three decades of the 20th century were used to clarify the spatial process of urbanization. Based on the historical experiences of the land use transitions, we adopted weight of evidence method integrated in cellular automata framework for predicting the future spatial patterns of urban growth. We extrapolated urban development patterns to 2010 and 2020 under the current scenario across the metropolitan region. Depending on local characteristics and land cover transition rates, this model produced noticeable spatial pattern of changes in the region. Based on the extrapolated spatial patterns, the urban development in the Kathmandu valley will continue through both in-filling in existing urban areas and outward rapid expansion toward the east and south directions. Overall development will be greatly affected by the existing urban space, transportation network, and topographic complexity. 相似文献
9.
Harish Bahadur S. B. Samanta A. K. Srivastava K. N. Sood R. Kishore R. K. Sharma A. Basu Rashmi M. Kar Prem Pal Vivekanand Bhatt Sudhir Chandra 《Journal of Materials Science》2006,41(22):7562-7570
Zinc oxide thin films grown by sol–gel and RF sputtering methods have been characterized. The characterization techniques used involve ellipsometry, optical absorption, scanning tunneling microscopy, scanning and transmission electron microscopy. The films grown by sol–gel spin method which followed zinc acetate route exhibited a smoother texture than the films, which were deposited by using zinc nitrate route. The later type of films showed a dendritic character. Nano-structured fine grains of size ranging from 20 to 60 nm were observed with zinc nitrate precursor film. Individual grains show a sharp contrast with different facets and boundaries. Crystal planes and lattice parameters calculated by electron diffraction and X-ray diffraction are quite close and in agreement with the reported values in literature. Scanning tunneling microscopy has been used for measuring the average roughness of the surface and estimating the lattice constants. The STM studies of RF sputtered films, although showing a ZnO structure, exhibited a disturbed lattice. This was presumably due to the fact that after deposition the films were not annealed. Nanographs of 2D and 3D view of atomic positions of ZnO have been presented by using scanning tunneling microscopy. 相似文献
10.
Mahendra Nath Roy Bhoj Bahadur Gurung Vikas Kumar Dakua 《International Journal of Thermophysics》2006,27(5):1539-1550
Electrolytic conductivities of potassium halides, KX (X = Cl−, Br−, I−) have been investigated in 10, 20, and 30 mass% glycerol + H2O mixtures at 298.0, 308.0, and 318.0 K. The conductance data have been analyzed by the Fuoss-conductance–concentration equation in terms of the limiting molar conductance (Λ0), the association constant (K
A
), and the distance of closest approach of ion (R). The association constant (K
A
) tends to increase in the order: 10 mass% < 20 mass% < 30 mass% glycerol + water mixtures, while it decreases with temperature. Thermodynamic parameters ΔH
0, ΔG
0, and ΔS
0 are obtained and discussed. Also, Walden products (Λ0η) are reported. The results have been interpreted in terms of ion–solvent interactions and structural changes in the mixed solvents. 相似文献