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排序方式: 共有1492条查询结果,搜索用时 15 毫秒
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Jagadeesh Babu Sriramoju Murthy Muniyappa Navya Rani Marilingaiah Chetana Sabbanahalli Manjunath Shetty Ravi Mudike Chitrabanu C.P Prasanna D. Shivaramu Nagaraju G Kanchugarakoppal S. Rangappa Ananda Kumar C.S Dinesh Rangappa 《Ceramics International》2021,47(7):10314-10321
Application of brown titanium dioxide (TiO2-x) and its modified composite forms in the photocatalytic decomposition of organic pollutants in the environment is a promising way to provide solutions for environmental redemption. Herein, we report the synthesis of effective and stable TiO2-x nanoparticles with g-C3N4, RGO, and multiwalled carbon nanotubes (CNTs) using a simple hydrothermal method. Among all the as-synthesized samples, excellent photocatalytic degradation activity was observed for RGO-TiO2-x nanocomposite with high rate constants of 0.075 min?1, 0.083 min?1 and 0.093 min?1 for methylene blue, rhodamine-B, and rosebengal dyes under UV–Visible light irradiation, respectively. The altered bandgap (1.8 eV) and the large surface area of RGO-TiO2-x nanocomposite impacts on both absorption of visible light and efficiency of photogenerated charge electron (e?)/hole (h+) pair separation. This resulted in enhanced photocatalytic property of carbon-based TiO2-x nanocomposites. A systematic study on the influence of different carbon nanostructures on the photocatalytic activity of brown TiO2-x is carried out. 相似文献
3.
Valence M. K. Ndesendo Yahya E. Choonara Leith C. R. Meyer Pradeep Kumar Lomas K. Tomar Charu Tyagi 《Drug development and industrial pharmacy》2015,41(8):1274-1287
Context and objective: The aim of this study was to develop, characterize and evaluate a mucoadhesive caplet resulting from a polymeric blend (polymeric caplet) for intravaginal anti-HIV-1 delivery.Materials and methods: Poly(lactic-co-glycolic) acid, ethylcellulose, poly(vinylalcohol), polyacrylic acid and modified polyamide 6, 10 polymers were blended and compressed to a caplet-shaped device, with and without two model drugs 3′-azido-3′-deoxythymidine (AZT) and polystyrene sulfonate (PSS). Thermal analysis, infrared spectroscopy and microscopic analysis were carried out on the caplets employing temperature-modulated DSC (TMDSC), Fourier transform infra-red (FTIR) spectrometer and scanning electron microscope, respectively. In vitro and in vivo drug release analyses as well as the histopathological toxicity studies were carried out on the drug-loaded caplets. Furthermore, molecular mechanics (MM) simulations were carried out on the drug-loaded caplets to corroborate the experimental findings.Results and discussion: There was a big deviation between the Tg of the polymeric caplet from the Tg's of the constituent polymers indicating a strong interaction between constituent polymers. FTIR spectroscopy confirmed the presence of specific ionic and non-ionic interactions within the caplet. A controlled near zero-order drug release was obtained for AZT (20 d) and PSS (28 d). In vivo results, i.e. the drug concentration in plasma ranged between 0.012–0.332?mg/mL and 0.009–0.256?mg/mL for AZT and PSS over 1–28 d.Conclusion: The obtained results, which were corroborated by MM simulations, attested that the developed system has the potential for effective delivery of anti-HIV-agents. 相似文献
4.
Jean-Fran?ois Blais Nathalie Meunier Guy Mercier Patrick Drogui Rajeshwar Dayal Tyagi 《Canadian Metallurgical Quarterly》2004,130(5):516-525
This research is related to a preindustrial pilot scale study of the performance of the simultaneous sewage sludge digestion and metal leaching (SSDML) process for decontamination and stabilization of sewage sludge. Ten batch tests were carried out in two 4?m3 bioreactors under various conditions of operation. Results indicated that the addition of 1.0 to 1.5?g?S0/L, which is the equivalent of approximately 30 to 50?kg?S0 per tons dry sludge, is sufficient to obtain conditions of acidity (pH<2.5) and oxido-reduction potential greater than 500 mV necessary for an effective solubilization of toxic metals. The final average of metal solubilization in the output sludge during the SSDML process varied in the following ranges: 25–78% Cd, 9–32% Cr, 48–100% Cu, 77–99% Mn, 15–53% Ni, 12–47% Pb, and 66–100% Zn. The N, P, and K contents were also preserved in the decontaminated sludge. Moreover, the use of low concentrations of elemental sulfur makes it possible to obtain decontaminated sludge with a low total sulfur content (1.4–1.5% S) compatible with agricultural use. The suspended solids removal calculated for the SSDML process was slightly lower, (2.5±0.4)% volatile suspended solids per day, than those reached using standard aerobic digestion. Finally, the SSDML process was found to be effective in removing bad odors and in the destruction (99–100%) of indicator bacteria. 相似文献
5.
The nature of pairing mechanism as well as transition temperature of yttrium cuprates is discussed using the strong coupling
theory. An interaction potential has been developed for the layered structure with two conducting CuO2(a–b) layers in a unit cell. The interaction potential properly takes care of electron-electron, electron-phonon and electron-plasmon
interactions. Furthermore, the electron-phonon coupling parameter (λ), the modified Coulomb repulsive parameter (μ*) and the 2D acoustic phonon (plasmon) energy as a function of oxygen deficiency is worked out. Finally, the superconducting
transition temperature (T
c) is then evaluated by using these coupling parameters and obtainedT
c = 95(92)K for Y(Yb)Ba2Cu3O7−δ
superconductors withδ = 0·0. The model parameters estimated from the layered structure approach are consistent with the strong coupling theory.
The result deduced on the variation ofT
c withδ are in fair agreement with the earlier reported data on yttrium cuprates. The analysis of the above results are discussed. 相似文献
6.
7.
R. Dinesh T. Fujiwara T. Watanabe K. Byrappa M. Yoshimura 《Journal of Materials Science》2006,41(5):1541-1546
A well-crystallized AMO4 (A=Ba, Ca, Sr; M=W, Mo) films have been prepared at room temperature through a simple solution reaction in respective alkaline
solution at higher pH ranging from 12–14. Adopting the corrosion principle for oxidation of metal substrate, these double
oxide films were carried out in presence of chemical driving force without any special apparatus or devices. Hydrogen peroxide
was used to enhance the dissolution rate of metal substrates. The driving force for the film formation and growth were high
concentration of A2+, MO42− ions with high pH conditions. Average grain sizes of 8–10 μm with bipyramidal shaped particle were grown to the thickness
of about 10–14 μm after 3–6 hours treatment. The crystallization of AMO4 was characterized by three-dimensional nucleation. This work demonstrates the possibility of fabrication of functional ceramic
films directly from the aqueous solution in a single step by solution reactions. 相似文献
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10.
A quantitative analysis of the effectiveness of laparascopy and endoscopy virtual reality simulators
Shankar Srinivasan Author Vitae Dinesh P. Mital Author VitaeAuthor Vitae 《Computers & Electrical Engineering》2006,32(4):283-298
The increasing use of virtual reality (VR) simulators in surgical training makes it imperative that definitive studies be performed to assess their training effectiveness. Indeed in this paper we report the meta-analysis of the efficacy of virtual reality simulators in (1) the transference of skills from the simulator training environment to the operating room and (2) their ability to discriminate between the experience levels of its users. The task completion time and the error score were the two study outcomes collated and analyzed in this meta-analysis. Sixteen studies were identified from a computer-based literature search (1996-2004). The meta-analysis of the random-effects model (because of the heterogeneity of the data) revealed that training on virtual reality simulators did lessen the time taken to complete a given surgical task as also clearly differentiate between the experienced and the novice trainees. Meta-analytic studies such as the one reported here would be very helpful in the planning and setting up of surgical training programs and for the establishment of reference ‘learning curves’ for a specific simulator and surgical task. If any such programs already exist they can then indicate the improvements to be made in the simulator used such as providing for more variety in their case scenarios based on the state and/or rate of learning of the trainee. 相似文献