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排序方式: 共有1468条查询结果,搜索用时 15 毫秒
1.
Nicolas Larché Benoit Emo Audrey Allion Elisabeth Johansson Dominique Thierry 《工业材料与腐蚀》2021,72(8):1338-1349
With lower alloying cost and higher mechanical properties, lean duplex stainless steels can be an alternative to the more commonly used austenitic stainless steels. However, these alloys are still not the preferred choice, probably due to a lack of field experience. A study was thus initiated in view of defining the limits of use of selected (lean) duplexes for urban wastewater treatment units. The present paper shows the localized corrosion performance of selected lean duplexes in chloride contaminated solutions. The results are compared with austenitic S30403 and S31603 and with the more standard duplexes S82441 and S32205. The effect of welding was also investigated. Exposures in field municipal wastewater plants were conducted for 1 year in low and high chloride content units. The results show that lean duplexes S32101 and S32202 can be used as alternatives to S30403 and S31603 in low chloride electrolytes. At 500 ppm of chloride content, duplex stainless steel S32304 showed better corrosion resistance than S30403 and S31603. For higher chloride contents (1000 ppm and above) the standard duplexes S82441 and S32205 shall be preferred. 相似文献
2.
Erwan Diler Vanessa Leblanc Hervé Gueuné Nicolas Larché Valerie Deydier Yannick Linard Didier Crusset Dominique Thierry 《工业材料与腐蚀》2021,72(1-2):218-234
In the context of the high-level radioactive waste disposal CIGEO, the corrosion rate due to microbially influenced corrosion (MIC) has to be evaluated. In France, it is envisaged to dispose of high- and intermediate-level long-lived radioactive waste at a depth of 500 m in a deep geological disposal, drilled in the Callovo-Oxfordian claystone (Cox) formation. To do so, a carbon steel casing will be inserted inside disposal cells, which are horizontal tunnels drilled in the Cox. A specific cement grout will be injected between the carbon steel casing and the claystone. A study was conducted to evaluate the possibility of MIC on carbon steel in the foreseeable high radioactive waste disposal. The corrosiveness of various environments was investigated at 50°C and 80°C with or without microorganisms enriched from samples of Andra's underground research laboratory. The monitoring of corrosion during the experiments was ensured using gravimetric method and real-time corrosion monitoring using sensors based on the measurements of the electrical resistance. The corrosion data were completed with microbiological analyses including cultural and molecular characterizations. 相似文献
3.
There are many potential causes of corrosion in animal buildings. Animals exhale large quantities of moisture into the air creating high relative humidity in the building if the moisture is not properly vented. High humidity increases the potential for condensation. In addition, ammonia may be found in large quantities in animal buildings. Ammonia is released from manure and urine. In addition, ammonium chloride is used as a nitrogen source in fertilisers. In this study, the atmospheric corrosion of hot-dip-galvanised steel and zinc alloy-coated steel such as zinc–aluminium and zinc–aluminium–magnesium has been studied in atmospheres containing different levels of ammonia. Investigations have also been conducted at different levels of ammonium chloride. The results are discussed in view of the mechanisms of corrosion of zinc and zinc alloy-coated steel in ammonia and ammonium chloride-containing environments. 相似文献
4.
Maria A. Ospina Monica Pizarro Thierry Tran Julien Ricci John Belalcazar Jorge L. Luna Luis F. Londoño Sandra Salazar Hernan Ceballos Dominique Dufour Luis A. Becerra Lopez-Lavalle 《International Journal of Food Science & Technology》2021,56(3):1343-1353
The objective of this study was to characterise the nutritional potential of leaves and identify a diversity centre with low cyanide and high nutrient content among 178 Latin American cassava genotypes. This field-based collection represents the seven diversity centres, held at The International Center for Tropical Agriculture (CIAT Palmira, Colombia) by the Cassava Program. The cyanide, all-trans-β-carotene and lutein concentrations in cassava leaves ranged from 346 to 7484 ppm dry basis (db), from 174–547 μg g−1 db and 15–181 μg g−1 db, respectively. Cassava leaves also showed significant levels of essential amino acids leucine, lysine, phenylalanine, valine and threonine, and average total protein content of 26.24 g 100 g−1 db. Among seven diversity centres, South American rainforest group showed low cyanide and high carotene content in leaves. In addition, VEN77 and PAN51 genotypes stood out for having low cyanide in leaves and roots and high carotene in leaves. This genetic diversity can be used to select high potential progenitors for breeding purposes. 相似文献
5.
X-ray microtomography: Application to microstructure analysis of a cementitious material during leaching process 总被引:4,自引:0,他引:4
Leaching of cementitious materials leads to an increase in porosity, which has important consequences on transport and mechanical properties. The present study outlines the characterization of microstructural evolution in a mortar subjected to a chemical attack, by means of a powerful non-intrusive experimental method, namely synchrotron X-ray computed microtomography. This innovative method is used to measure the variation of porosity in a leached mortar. Having described the effects of leaching in mortar (influences on microstructure and on mechanical properties), we present the accelerated leaching process and the microtomographic analysis that have been used to monitor it. We then investigate the capacity of this method to quantify the evolution of porosity during the leaching process. The method is validated by comparison of the results obtained with data available in the literature. 相似文献
6.
Véronique Baroghel-Bouny Patrick Belin Matthias Maultzsch Dominique Henry 《Materials and Structures》2007,40(8):759-781
Within the framework of the evaluation and the prediction of chloride-induced corrosion risks, simple and rapid AgNO3 spray tests can be proposed for various issues. This paper forms the first part of a series. In this first part, the Maultzsch
procedure (spraying of 0.1-N AgNO3 solution + K2CrO4) as well as the procedure based on the use of a sole AgNO3 solution have been investigated on a broad range of concretes. These procedures have also been compared to the Collepardi
procedure (spraying of 0.1-N AgNO3 + fluoresceine). The feasibility of these colorimetric techniques on saturated specimens cast in laboratory, after non-steady-state
diffusion tests carried out in various conditions, is discussed. In addition, the results obtained from applying such spray
tests in field conditions on cores drilled out from various RC test specimens exposed to a marine environment (tidal zone)
and to a road and cold environment (freezing-thawing cycles and spraying of deicing salts) are presented. Colorimetric methods
have in particular been applied here to the assessment of the average chloride penetration depth and of its evolution versus
time (kinetics). Moreover, the detection threshold of these techniques has been investigated in various environments. The
possible sources of discrepancy on the results have been analysed. 相似文献
7.
Dominique PinoitRobert E Prud'homme 《Polymer》2002,43(8):2321-2328
The phase behavior of ternary blends made of poly(epichlorohydrin) (PECH), poly(vinyl acetate) (PVAc) and poly(methyl methacrylate) (PMMA) has been investigated by differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA). DMTA measurements have been shown to be more sensitive than DSC for the detection of a second phase, for the determination of the composition of each phase, and the distribution of PECH in each of them. About 70% PECH was required to obtain a single narrow Tg in the ternary system, which suggests a single homogeneous phase in the limit of sensitivity of DMTA. This study also emphasizes the importance of the composition of the immiscible polymer pair (i.e. the PVAc/PMMA pair in the PECH/PVAc/PMMA system), in addition to the thermodynamic interaction parameters, for controling the phase behavior of ternary systems. 相似文献
8.
9.
Crack onset at a v-notch. Influence of the notch tip radius 总被引:1,自引:0,他引:1
A criterion to predict crack onset at a sharp notch in homogeneous brittle materials has been presented in a previous paper of one of the authors. It is reviewed and improved herein. It fulfils both the energy and the strength criteria and takes an Irwin-like form involving the generalized intensity factor of the singularity governing the elastic behaviour in the vicinity of a notch tip. The prediction agrees fairly well with the experiments although it slightly underestimates the experimental measures. A cause of this discrepancy can be that a small notch tip radius blunts the sharp corner. It is analysed in this paper by means of matched asymptotics involving 2 small parameters: a micro-crack increment length and the notch tip radius. A correction is brought to the initial prediction and a better agreement is obtained with experiments on PMMA notched specimens. Experiments performed on a stiffer material (Alumina/Zirconia) show that it is less sensitive to small notch tip radii. A remaining small discrepancy between experiments and predictions can be due to some non linear behaviour of the materials near the notch tip. In addition, without new developments, the method allows to determine the stress intensity factor at the tip of a short crack emanating from a sharp or a rounded v-notch. 相似文献
10.
The authors present the design and the development of integrated microwave filters using suspended substrate microstrip, a technology that provides many advantages. Through quasi-static approximation the propagation structure has been treated using integral equations solved with the method of moments. Thanks to this tool of analysis and to an accurate synthesis method, a series of bandpass filters have been designed and manufactured. The results presented validate the accuracy of our design method. 相似文献