全文获取类型
收费全文 | 451篇 |
免费 | 9篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 6篇 |
化学工业 | 85篇 |
金属工艺 | 13篇 |
机械仪表 | 17篇 |
建筑科学 | 3篇 |
能源动力 | 5篇 |
轻工业 | 6篇 |
水利工程 | 7篇 |
石油天然气 | 61篇 |
无线电 | 47篇 |
一般工业技术 | 124篇 |
冶金工业 | 46篇 |
原子能技术 | 3篇 |
自动化技术 | 38篇 |
出版年
2022年 | 6篇 |
2021年 | 7篇 |
2020年 | 4篇 |
2019年 | 9篇 |
2018年 | 11篇 |
2017年 | 10篇 |
2016年 | 13篇 |
2015年 | 6篇 |
2014年 | 12篇 |
2013年 | 16篇 |
2012年 | 15篇 |
2011年 | 13篇 |
2010年 | 24篇 |
2009年 | 20篇 |
2008年 | 24篇 |
2007年 | 20篇 |
2006年 | 19篇 |
2005年 | 9篇 |
2004年 | 10篇 |
2003年 | 11篇 |
2002年 | 10篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 8篇 |
1998年 | 8篇 |
1997年 | 7篇 |
1996年 | 5篇 |
1995年 | 7篇 |
1994年 | 4篇 |
1993年 | 6篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 11篇 |
1989年 | 8篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 7篇 |
1983年 | 6篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 8篇 |
1977年 | 6篇 |
1976年 | 5篇 |
1975年 | 6篇 |
1973年 | 3篇 |
1972年 | 5篇 |
1971年 | 3篇 |
1970年 | 6篇 |
1969年 | 3篇 |
排序方式: 共有461条查询结果,搜索用时 93 毫秒
1.
It was found that vanadyl porphyrin complexes synthesized from petroleum metal porphyrin concentrates stimulated epoxidation during the olefin oxygenation process. The yields of obtained oxiranes turned out to be 38–75%, depending on the olefin structure. An epoxidation mechanism that suggests the formation of a protonated dioxygen adduct as an intermediate during oxygenation of olefins in the presence of vanadyl porphyrin complexes was proposed. An analogy is drawn between the epoxide formation reaction upon the catalytic oxygenation of olefins and the Prilezhaev reaction. 相似文献
2.
Solar cells based on SnO2/Cd0.4Zn0.6S/CdTe heterostructures are fabricated by electrochemical deposition, and the dependences of their electrical and photoelectric properties on the thermal annealing conditions are studied. It is shown that thermal annealing reduces the tunnel currents by almost two orders of magnitude. The best conditions of thermal annealing are determined (t = 300°C and τ = 9 min). These conditions provide the highest photosensitivity of the heterostructures under study (I sc ≈ 21.2 mA/cm2, U oc ≈ 813 mV, and η = 14.7%). 相似文献
3.
A fiber optic phase modulator is described in which the phase of a light wave traveling in an optical fiber is modulated by a composite electromechanical resonator with Q≌1000. The instantaneous frequency of the wave at the modulator output varies according to a harmonic law. The interval of tuning of the instantaneous light wave frequency achieved in the experiment is 20 GHz, which corresponds to a modulation index of ≌106. It is demonstrated that a maximum value of the frequency tuning range is determined by the elastic limit of the resonator material. 相似文献
4.
M. N. Mamedov 《Protection of Metals》2002,38(3):236-237
Plating conditions and some physicochemical properties of lead-tellurium coatings from a fluoboric acid bath are studied. The electroplates exhibit high microhardness, and a corrosion resistance in sulfuric acid media of 2–3 times that of pure electrolytic lead. 相似文献
5.
6.
Effect of titanium and silicon on the phase composition and properties of a high-chromium tool steel
1. | The presence of Ti (0.4–0.7%) and silicon (0.7–1.0%) in high-chromium die steels does not adversely affect the level of their manufacturing properties and leads to an increase in strength and wear resistance. |
2. | The mechanical properties of steel Kh12MST as a function of tempering temperature has two maximum which indicates that these steels can be used in die stamping equipment with high speed automated punching machines where the working sections can obtain temperatures as high as 400°C. |
3. | Steel Kh12MST is recommended for the manufacture of cold deformation dies which operate over a wide range of dynamic loading and also for the manufacture of the cutting parts of heavy-duty dies which operate under conditions of extreme wear. |
4. | The application of steel Kh12MST (ÉP952) in punching dies will increase their durability during the production of magnetic current plates made of electrotechnical steel by not less than 1.7 times. |
7.
Gilles Thibault Gilles Paintaud Hsueh Cheng Sung Laurie Lajoie Edouard Louis the GETAID Celine Desvignes Herv Watier Valrie Gouilleux-Gruart David Ternant 《International journal of molecular sciences》2021,22(11)
The FcγRIIA/CD32A is mainly expressed on platelets, myeloid and several endothelial cells. Its affinity is considered insufficient for allowing significant binding of monomeric IgG, while its H131R polymorphism (histidine > arginine at position 131) influences affinity for multimeric IgG2. Platelet FcγRIIA has been reported to contribute to IgG-containing immune-complexe clearance. Given our finding that platelet FcγRIIA actually binds monomeric IgG, we investigated the role of platelets and FcγRIIA in IgG antibody elimination. We used pharmacokinetics analysis of infliximab (IgG1) in individuals with controlled Crohn’s disease. The influence of platelet count and FcγRIIA polymorphism was quantified by multivariate linear modelling. The infliximab half-life increased with R allele number (13.2, 14.4 and 15.6 days for HH, HR and RR patients, respectively). It decreased with increasing platelet count in R carriers: from ≈20 days (RR) and ≈17 days (HR) at 150 × 109/L, respectively, to ≈13 days (both HR and RR) at 350 × 109/L. Moreover, a flow cytometry assay showed that infliximab and monomeric IgG1 bound efficiently to platelet FcγRIIA H and R allotypes, whereas panitumumab and IgG2 bound poorly to the latter. We propose that infliximab (and presumably any IgG1 antibody) elimination is partly due to an unappreciated mechanism dependent on binding to platelet FcγRIIA, which is probably tuned by its affinity for IgG2. 相似文献
8.
Synthesis, structure and catalytic properties of Fe-substituted barium hexaaluminates 总被引:7,自引:0,他引:7
Daoud Naoufal Jean-Marc Millet Edouard Garbowski Yes Brullé Michel Primet 《Catalysis Letters》1998,54(3):141-148
A sol–gel method using Ba and Al isopropylates and iron nitrate has been used to synthesise barium hexaaluminate partially substituted with iron. After calcination under oxygen at 1200°C the -alumina structure was obtained. Formation of the mixed BaFexAl12-xO19 phase occurred for x=1–4. XRD measurements showed a good crystallinity of the structure and expansion of unit cell parameters due to the presence of larger Fe3+ ions substituting Al3+ ones in octahedral sites only. Mössbauer spectroscopy revealed that Fe3+ ions are present in four different octahedral sites slightly distorted. Catalytic activity in methane combustion showed that an optimum was obtained for solid containing 2 Fe ions per unit cell: the increase of the amount of introduced iron was counterbalanced by the decrease of specific surface area. Intrinsic activities have been calculated for the four solids in both the fresh and aged states. It is observed that increasing iron content increases relative activities in the same ratio as the populations of iron located in two sites as deduced from Mössbauer spectroscopy. It is then tentatively assumed that activity is attributed to octahedrally coordinated Fe3+ ions in some specific sites. 相似文献
9.
We have studied the possibility of producing powders from gray cast-iron chips formed during the production of home air conditioners. The particle morphology, structure, physicotechnical, mechanical, and antifriction properties of the cast iron powder are studied and compared to those of powdered iron. It is shown that the sample obtained from the cast-iron powder have worse mechanical properties than the samples prepared from iron but they have better antifriction properties than the latter.Bakkonditsioner Scientific-Industrial Complex. Translated from Poroshkovaya Metallurgiya, No. 2(362), pp. 93–98, February, 1993. 相似文献
10.
A. M. Mamedov 《Journal of Engineering Physics and Thermophysics》1978,34(3):312-315
Using experimental and data, equations are developed for six aromatic hydrocarbons which describe within the limits of experimental accuracy over the temperature range 298–573°K at pressures up to 500 bar.Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 34, No. 3, pp. 465–469, March, 1978. 相似文献