Technologies for ballast water treatment: a review

Invasive aquatic species discharged through ballast water is one of the most serious problems posed nowadays in the marine environment. This review paper summarizes the available technologies applied for ballast water treatment. These technologies can be either port‐based or ship‐based, with the latter being easier to implement. Special emphasis was given to onboard treatment methods, which can be categorized as physical separation, mechanical or chemical methods. The efficiency of the methods, as well as the capacity of application and the target microorganisms were compiled and are presented in this review. Copyright © 2009 Society of Chemical Industry     

Solar hydrogen

The intermittance and the geographical distribution of solar energy require means of storing and transporting it to the user's place. An ideal means of doing this is to split water in order to obtain hydrogen.Hydrogen is a carbon-free fuel which oxidizes to water as combustion product. The generated water becomes, together with renewable primary energy for splitting it, a source of clean and abundant energy in a carbon-free, natural cycle.Hydrogen is a fuel which can be transported over long distances and stored so that solar energy can be transported from energy rich countries over long distances in ships to Europe, stored underground or in containers and used in gaseous or liquid form in industry, households, power stations, motor cars and aviation.Solar energy as primary energy is discussed. A special form of it, the cheapest and by now largely available hydropower, is stressed.Techniques of hydrogen production, vectorisation and end use are discussed as well as safety aspects, costs and strategy for its implementation.     

Exact and efficient construction of Minkowski sums of convex polyhedra with applications

We present an exact implementation of an efficient algorithm that computes Minkowski sums of convex polyhedra in R³. Our implementation is complete in the sense that it does not assume general position. Namely, it can handle degenerate input, and it produces exact results. We also present applications of the Minkowski-sum computation to answer collision and proximity queries about the relative placement of two convex polyhedra in R³. The algorithms use a dual representation of convex polyhedra, and their implementation is mainly based on the Arrangement package of Cgal, the Computational Geometry Algorithm Library. We compare our Minkowski-sum construction with the only three other methods that produce exact results we are aware of. One is a simple approach that computes the convex hull of the pairwise sums of vertices of two convex polyhedra. The second is based on Nef polyhedra embedded on the sphere, and the third is an output-sensitive approach based on linear programming. Our method is significantly faster. The results of experimentation with a broad family of convex polyhedra are reported. The relevant programs, source code, data sets, and documentation are available at http://www.cs.tau.ac.il/~efif/CD and a short movie [Fogel E, Halperin D. Video: Exact Minkowski sums of convex polyhedra. In: Proceedings of 21st annual ACM symposium on computational geometry. 2005. p. 382-3] that describes some of the concepts portrayed in this paper can be downloaded from http://www.cs.tau.ac.il/~efif/CD/Mink3d.avi.     

Modeling users on the World Wide Web based on cognitive factors,navigation behavior and clustering techniques

This paper focuses on modeling users’ cognitive styles based on a set of Web usage mining techniques on user navigation patterns and clickstream data. Main aim is to investigate whether specific clustering techniques can group users of particular cognitive style using measures obtained from psychometric tests and content navigation behavior. Three navigation metrics are proposed and utilized to find identifiable groups of users that have similar navigation patterns in relation to their cognitive style. The proposed work has been evaluated with two user studies which entail a psychometric-based survey for extracting the users’ cognitive styles, combined with a real usage scenario of users navigating in a controlled Web 2.0 environment. A total of 106 participants of age between 17 and 25 participated in the study providing interesting insights with respect to cognitive styles and navigation behavior of users. Studies like the reported one can be useful for modeling users and assist adaptive Web 2.0 environments to organize and present information and functionalities in an adaptive format to diverse user groups.     

Renal osmotic stress-induced cotransporter: expression in the newborn, adult and post-ischemic rat kidney

The renal osmotic stress-induced cotransporter (ROSIT), a new putative member of a family of organic solute transporters, is highly expressed in the kidney. Our in situ hybridization data now reveal that large amounts of ROSIT mRNA can be found in the S3 segment of the proximal tubule. In the developing kidney, ROSIT mRNA is expressed after the S-shaped body stage. Because the S3 segment is the major site of damage in the post-ischemic kidney, we evaluated alterations in ROSIT mRNA expression after ischemic acute tubular necrosis. Renal osmotic stress-induced cotransporter mRNA levels were already decreased eight hours post-ischemia. At seven days post-ischemia, ROSIT mRNA reappeared in a mosaic pattern in the regenerating S3 segment, being fully expressed three weeks after the insult except for focal areas. The exact localization of this putative osmolyte transporter in the kidney, together with that of other known osmolyte transporter will contribute to a better understanding of the mechanism of medullary osmolyte accumulation and its vectorial transport.     

Increased epithelial cell proliferation and abnormal extracellular matrix in rat polycystic kidney disease

Proliferation of renal tubular epithelial cells is considered a major factor leading to cyst formation in human polycystic kidney disease (PKD). The Han:SPRD rat model for inherited PKD permits a close scrutiny, especially for early stages of the disease, and shows numerous similarities to human autosomal dominant PKD (ADPKD). In this study, the exact in vivo proliferation rate in Han:SPRD rat kidneys was evaluated in a cell type-specific manner, using immunohistochemistry with antibody to proliferating cell nuclear antigen (PCNA). The proliferation index (PI; percentage of PCNA-positive cell nuclei) was determined in normal and cystically altered tissue, and a relationship between proliferative activity and alterations in extracellular matrix expression was established using in situ hybridization for collagen I and IV mRNA. Heterozygously affected rats (cy/+) showed strong increases of PI values in cystically altered nephron portions that were mostly derived from proximal tubule. Cell proliferation obviously preceded cyst formation, because early in the progression of the disease, the normal-appearing tubules from PKD kidneys had markedly increased PI values compared with healthy controls (14.1-fold in 3-mo-old rats and 11.9-fold in 12-mo-old rats; P < 0.05), whereas later stages revealed a more generalized cystic degeneration of the nephron, with increases in PI between 14- and 82-fold, depending on the respective category of cystic epithelia. In cysts with a distal phenotype, changes were less pronounced. No significant differences were encountered between the two age groups. Proliferation was also present in interstitial cells, whereas glomeruli were unchanged. Increases in epithelial and interstitial proliferation coincided with an overexpression of matrix compounds. For comparison, changes in homozygously affected rats (cy/cy) showed up to several hundred-fold elevated PI values. These results indicate that in the Han:SPRD model for ADPKD, cystic malformation of the nephron is preceded by and coincides with enhanced epithelial and interstitial cell proliferation. Altered cell-matrix interactions seem to be directly involved in the disruption of epithelial differentiation.     

A Low Temperature Route toward Hierarchically Structured Titania Films for Thin Hybrid Solar Cells

The requirement of high‐temperature calcination for titanium dioxide in (solid‐state) dye‐sensitized solar cells (DSSCs) implies challenges with respect to reduced energy consumption and the potential for flexible photovoltaic devices. Moreover, the use of dye molecules increases production costs and leads to problems related with dye bleaching. Therefore, fabrication of dye‐free hybrid solar cells at low temperature is a promising alternative for current DSSC technology. In this work the authors fabricate hierarchically structured titania thin films by combining a polystyrene‐block‐polyethylene oxide template assisted sol–gel synthesis with nano‐imprint lithography at low temperatures. The achieved films are filled with poly(3‐hexylthiophene) to form the active layer of hybrid solar cells. The surface morphology is probed via scanning electron microscopy and atomic force microscopy, and the bulk film morphology is examined with grazing incidence X‐ray scattering. Good light absorption by the active layer is proven by UV–vis spectroscopy. An enhancement in light absorption is observed and ascribed to light scattering in mesoporous titania films with imprinted superstructures. Accordingly a better photovoltaic performance is found for nano‐imprinted solar cells at various angles of light incidence.     

Fast randomized algorithm for 2-hops clustering in vehicular ad-hoc networks

Vehicular Ad-Hoc Networks (VANETs) enable inter vehicle wireless communication as well as communication with road side equipment. Warning messages can be exchanged among nearby vehicles, helping to predict dangerous situations, and thus improving road safety. Such safety messages require fast delivery and minimal delay to local areas, in order for them to be effective. Therefore, a fast and efficient channel access scheme is required. A feasible solution, derived from the Mobile Ad-Hoc Networks (MANETs) field, groups nodes into smaller manageable sections called clusters. Such an approach can be beneficial for locally delivering messages under strict time constraints. In this paper, a Hierarchical Clustering Algorithm (HCA) is presented. HCA is a distributed randomized algorithm, which manages channel access by forming three hierarchy clusters. The proposed channel access scheme enables delay bounded reliable communication. Unlike other common clustering algorithm for VANETs, HCA does not require the knowledge of the vehicles’ locations. This feature guarantees accurate operation even when localization systems such as GPS are not available. The running time and message complexity were analyzed and simulated. Simulation results show that the algorithm behaves well especially under realistic mobility patterns; therefore, it is a suitable solution for channel access scheme for VANETs.     

Geometric Frustration in Molecular Crystals

Unlike Lego bricks that perfectly assemble next to one another, solid assemblies of organic compounds often include some inevitable misfit between constituents, giving rise to geometric frustration. In order to fit into the assembly the molecular building blocks must distort, at some finite energetic cost. In cases where this distortion at the ground state is uniform across all the units in the assembly, the associated geometric frustration is said to be locally resolved. Such locally resolved frustration carries little implications on the morphology and response properties of the assembled structure. However, in many cases, for small enough assemblies there are non-local compromises that are more energetically favorable. These conformations are associated with non-uniform distortions and highly cooperative response between the molecular constituents. The cooperative nature of frustrated assemblies may result in growth arrest, tendency to form filaments, exotic response properties and large morphological variations during the growth of the assembly. Almost a century ago German mineralogist Ferdinand Bernauer discovered that a large fraction of small organic compounds could form twisted molecular crystals. These are straight and narrow needle-like structures with mesoscopic pitch, a crystalographically impossible structure. Recent revived interest in twisted molecular crystals discovered even more compounds that form these exotic assemblies and led to their study by modern means. Electron microscopy revealed straight faceted structures with sharp diffraction peaks in selected area electron diffraction, much like regular crystals. Moreover, the pitch of the molecular crystals varied with size, with thicker crystals exhibiting less twist. In this work we review twisted molecular crystals as frustrated assemblies. In this approach twist emerges from the preferred morphology at the constituent scale, and gets attenuated with size by the incompatibility of twist and large-scale crystalline order. We discuss two distinct mechanisms that produce twisted molecular crystals, and provide a prediction for the twist decay as a function of the crystals’ spatial dimensions.