Influence of n-alkanes on wettability and zeta potential of quartz

Contact angles were measured in the following systems: quartz/water droplet/saturated vapor of water + n-alkane and quartz/water droplet/saturated vapor of n-alkane. The alkanes tested were from hexane to pentadecane. In both systems non-smooth changes of contact angle as a function of the chain length were observed. These changes are similar to the zeta-potential changes measured previously for two different samples of quartz in the quartz/n-alkana/water system. On the basis of the results and calculations it is suggested that the observed non-smooth changes of contact angle are due to similar changes in film pressures of the water and n-alkanes.     

Predicting Acute Renal Failure after Cardiac Surgery: Validation and Re‐definition of a Risk‐Stratification Algorithm

Background:  Acute renal failure (ARF) after cardiac surgery is associated with significant morbidity and mortality, irrespective of the need for dialysis. Previous studies have attempted to identify predictors of ARF and develop risk stratification algorithms. This study aims to validate the algorithm in an independent cohort of patients that includes a significant proportion of female and black patients and compares two different definitions of renal outcome.
Methods:  A large single center cardiac surgery database was examined (n, 24,660; 1993–2000) which included 29.9% females and 3.7% black patients. Post‐operative ARF was defined as: a) ARF requiring dialysis, b) > 50% reduction in creatinine clearance relative to baseline or requiring dialysis. Clinical variables related to baseline renal function and cardiovascular disease were used in recursive partitioning analysis for both outcome definitions. Chi‐square goodness of fit analysis was performed to validate the algorithm.
Results:  The frequency of post‐operative ARF requiring dialysis ranged between 0.5 and 15.5% based on the risk categories with the area under the receiver operating characteristic (ROC) curve of 0.78. Using the more inclusive definition of ARF, the frequency was significantly higher ranging from 2.6 to 25%(P < 0.001) with an area under ROC curve of 0.65.
Conclusions:  The renal risk stratification algorithm is valid in predicting post‐operative ARF in an independent cohort of patients, well represented by differences in gender and race. Since the need for dialysis remains subjective, a more objective and inclusive definition of ARF may help in identifying a larger number of patients 'at‐risk'.     

OLAP and bibliographic databases

The application of online analytical processing (OLAP) technology to bibliographic databases is addressed. We show that OLAP tools can be used by librarians for periodic and ad hoc reporting, quality assurance, and data integrity checking, as well as by research policy makers for monitoring the development of science and evaluating or comparing disciplines, fields or research groups. It is argued that traditional relational database management systems, used mainly for day-to-day data storage and transactional processing, are not appropriate for performing such tasks on a regular basis. For the purpose, a fully functional OLAP solution has been implemented on Biomedicina Slovenica, a Slovenian national bibliographic database. We demonstrate the system's usefulness by extracting data for studying a selection of scientometric issues: changes in the number of published papers, citations and pure citations over time, their dependence on the number of co-operating authors and on the number of organisations the authors are affiliated to, and time-patterns of citations. Hardware, software and feasibility considerations are discussed and the phases of the process of developing bibliographic OLAP applications are outlined. This revised version was published online in June 2006 with corrections to the Cover Date.     

Verteilung der N?hrstoffe im Tabak

Ohne Zusammenfassung     

Determination of porous glass surface free energy components from contact angles

The contact angles of water drops and diiodomethane drops on pellets made of controlled porosity glasses have been measured. The surface of the glasses was modified by thermal treatment at 873 K which led to an increase in the surface concentration of boron atoms. Glass modified with Carbowax 20M (polyethylene glycol) and fully hydroxylated glass have also been studied. Using the measured contact angles and modified Young equation, the dispersion and nondispersion components of the glass surface free energy have been calculated. The values show that with increasing heating time (increasing surface density of boron atoms) an increase in the surface polarity takes place. However, the polarity of the same samples decreases after treatment with Carbowax, increasingly so with higher boron atom concentrations.