Effects of surface roughness and the chemical structure of materials of construction on wall slip behavior of linear low density polyethylene in capillary flow

The presence of wall slip during the flow of polymeric melts has significant ramifications on the melts' processability. In this study, the effects of materials of construction and surface roughness on the wall slip behavior of a linear low density polyethylene were investigated, using capillary flow. Capillaries, constructed from copper, stainless steel, aluminum, and glass, were used. The inner surface roughness of the capillaries were characterized by the employment of a profilometer and scanning electron microscopy. The roughness profiles of copper capillaries were also altered by the employment of chemical etching. Using Mooney's analysis, the wall slip velocity values were determined to be in the range of 0.09 to 1.34 mm/s. The wall slip velocity values were the highest for stainless steel and were negligible for aluminum. The relative work of adhesion values of polyethylene were the smallest for stainless steel and copper and the highest for glass. Overall, the wall slip velocity values increased with decreasing surface roughness of the capillaries and with decreasing work of adhesion. © 1993 John Wiley & Sons, Inc.     

Fractional wavelet transform for the quantitative spectral resolution of the composite signals of the active compounds in a two-component mixture

Fractional calculus is a powerful tool that has been applied successfully for the analysis of the complex systems. One interesting example of a complex mixture is given by the multicomponent pharmaceutical samples having constant matrix content. The main aim of this study is to develop a new approach based on the combined use of the fractional wavelet transform (FWT) and the continuous wavelet transform (CWT) in order to quantify atorvastatin (ATO) and amlodipine (AML) in their mixtures without requiring a chemical pretreatment. In the first step, the absorption spectra of the compounds and their samples were processed by the FWT method. In the next step, the CWT approach was applied to the fractional wavelet spectra obtained in the above step. The aim of the application of FWT is data reduction corresponding to the spectra of compounds and their commercial samples. In the following step, the CWT was used for the quantitative resolution of the composite signals of the analyzed compounds. After method validation, the proposed signal processing methods based on the combined use of the FWT and the CWT were successfully applied to the resolution of the composite spectra for the quantitation of atorvastatin (ATO) and amlodipine (AML) in tablets.     

Wavelet ridges for musical instrument classification

The time-varying frequency structure of musical signals have been analyzed using wavelets by either extracting the instantaneous frequency of signals or building features from the energies of sub-band coefficients. We propose to benefit from a combination of these two approaches and use the time-frequency domain energy localization curves, called as wavelet ridges, in order to build features for classification of musical instrument sounds. We evaluated the representative capability of our feature in different musical instrument classification problems using support vector machine classifiers. The comparison with the features based on parameterizing the wavelet sub-band energies confirmed the effectiveness of the proposed feature.     

Three‐dimensional high‐conductivity trees for volumetric cooling

Here, we show how the cooling performance of a volumetrically heated solid can be increased by embedding high‐conductivity tree‐shaped designs in it. The volume fraction occupied by the high‐conductivity material is fixed. Embedding the high‐conductivity material as trees in the solid decreases the maximum temperature more than three times compared with distributing the high‐conductivity material uniformly throughout the solid. The maximum temperature decreases as the number of the bifurcation levels and the volume fraction of the highly conductive material increase. The thermal resistance of the cube is the lowest when the diameter ratio of the mother and daughter branches at each pairing junction is 2. Changing from T‐shaped to Y‐shaped designs and from two‐dimensional to three‐dimensional designs decrease the maximum and the volume averaged temperatures. The peak temperature is the lowest in three‐dimensional and Y‐shaped designs. This paper shows that the peak temperature of the heated solid can be decreased by only varying the shape of the high‐conductivity tree embedded in it. Copyright © 2014 John Wiley & Sons, Ltd.     

Casting properties of ASTM A128 Gr. E1 steel modified with Mn-alloying and titanium ladle treatment

This work aims to produce a high manganese steel with more refined austenite grains and better wear resistance without sacrificing the toughness and tensile properties by Mn alloying and Ti ladle treatment in comparision to ASTM A128 Gr. E1 steel (1.0C-13Mn) that is mostly used in the mining industry. The 1.0C-17Mn-xTi alloys (x=0, 0.05 and 0.1, in wt.%) were prepared. A relationship was established between the microstructures and mechanical properties of the as-cast and solution annealed alloys. Increasing Ti content increases the stable Ti(CN) phase on and beside the grain boundaries and decreases up to 37% the austenite grain size of the as-cast alloy with 0.10wt.% Ti. Correspondingly, after solution annealed, optimized titanium content (0.05wt.%) results in significant improvements in wear resistance, hardness, elongation, yield and tensile strengths by 44%, 31%, 30%, 8% and 12%, respectively, except 9% decrease in impact toughness compared to ASTM A 128 Gr. E1 steel without modification. These results show that 1.0C-17Mn-0.05Ti alloy can be used for parts exposed to high load wear and applied in conditions where relatively high tensile properties with sufficent ductility is needed.

     

Allochthonous blocks misidentified as the basement: Implication for petroleum exploration in the SW Thrace Basin (Turkey)

The sedimentary sequence of the SW Thrace Basin (NW Turkey) comprises of three major sedimentary packages: a) Cretaceous (Meastrichtien)–Early Eocene package formed as pelagic carbonate, turbidite, shelf and nearshore-fluvial deposits, b) Middle Eocene–Early Oligocene package formed as shallow marine, slope apron and turbidite sediments, c) Middle Miocene–Early Pliocene package formed as alluvial fan-fluvial and nearshore deposits. This basin is structurally complex and its southern margin is represented by a fold-thrust zone. The Westward Propagation of the North Anatolian Fault (WPNAF) intersects the Thrace Basin along its southwestern flank. In the SW Thrace Basin, there are ophiolite and limestone blocks in the sedimentary succession, which previously were interpreted as suture of the Intra-Pontide Ocean, Cretaceous aged Yeniköy Mélange or Olistostromal Unit in the Eocene sediments. In this study these rocks have been defined as allochthonous blocks facies of the Gaziköy Formation aged Middle–Late Eocene.In previous studies the Karaağaç Formation (Early Eocene) was considered to be within oil window and have an average potential for oil and gas generation. According to our data the Karaağaç Formation has a moderate TOC content, is mature and overmature. In the study area, there are potential stratigraphic traps (submarine fans and channels of the Karaağaç and Keşan Formations, fluvial channels of the Fıçıtepe Formation and reefs of the Soğucak Formation), potential fractured tuffs (the Gaziköy Formation) and, potential structural traps related to the folds, thrusts and the WPNAF. Although 17 exploration wells have been drilled in the study area and vicinity, no discovery has yet been made. The cause of this may be that the wells were terminated at depths shallower than potential targets or possibly drilling may have been terminated at the allochthonous block facies of the Gaziköy Formation, which is especially derived from ophiolite mélange and was misidentified as basement.     

The influence of cultural factors on scientific production

A classification of countries is made according to respective ranks in the scales of publications per million persons and GDP per capita (ppp). The result is a clustering of countries which share a common cultural attitude toward scientific research.     

SENDROM: Sensor networks for disaster relief operations management

SENDROM is a new sensor network architecture to manage the rescue operations after large scale disasters. This architecture mainly consists of sensor nodes deployed prior to a disaster and central nodes that can query sensor nodes. Central nodes are stored nearby the emergency operation centers and airports before a disaster. Following a disaster rescue teams are assigned one mobile central node and guided to a region based on the data in the SENDROM database. This paper explains the SENDROM architecture as well as our new task and data dissemination, localization of a detected person, and end-to-end reliable event transfer schemes introduced for SENDROM. Then it evaluates the performance of these schemes analytically and through simulation.