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Erigene Bakangura Yubin He Xiaolin Ge Yuan Zhu Liang Wu Jin Ran Congliang Cheng Kamana Emmanuel Zhengjin Yang Tongwen Xu 《Frontiers of Chemical Science and Engineering》2018,12(2):306-310
Poly(2,6-dimethyl-1,4-phenylene oxide) was tethered with a 1,5-disubstituted tetrazole through a quaternary ammonium linkage. The formation of a tetrazole-ion network in the resulting polymers was found to promote the hydroxide ion transport through the Grotthus-type mechanism. 相似文献
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Liang Wu Chuanrun Li Zhen Tao Hao Wang Jin Ran Erigene Bakangura Zhenghui Zhang Tongwen Xu 《International Journal of Hydrogen Energy》2014
Fluorous copolymers are synthesized by grafting quaternary ammonium-functionalized 4-vinylbenzyl chloride (QVBC) and N-Isopropyl acrylamide (NIPAAM) from poly(vinylidene fluoride) (PVDF) via atom transfer radical polymerization (ATRP). Ionic PQVBC and thermo-responsive PNIPAAM grafts are characterized by proton nuclear magnetic resonance (1H NMR) spectroscopy. Polarity difference between flexible grafts and rigid fluorous backbones allows convenient formation of ionic clusters, which impart resultant membranes excellent hydroxide conductivities in the range of 21–52 mS cm−1 at 20 °C, and up to 98 mS cm−1 at 70 °C. Moreover, amide–amide interactions between thermo-responsive grafts at high temperature can mitigate water swelling of hydrophilic clusters. This study suggests that the fluorous copolymer bearing both ionic and thermo-responsive grafts holds a promising selectivity as novel materials for anion exchange membrane with enhanced hydroxide conductivity and controlled water swelling. 相似文献
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