Effect of dispersion states (electrostatic/electrosteric stabilization) on particles arrangement in the yttria-stabilized zirconia sediments

In the present work, particle arrangement and their packing in the sediment layer of zirconia suspension were studied. To evaluate the particle settling, aqueous suspensions of zirconia nanoparticles were prepared in different dispersion states. In one state, Dolapix CE64 was used as a dispersant to provide electrosteric mechanism. In another state, pH of the suspension was adjusted at 4 to provide electrostatic mechanism. The other state was the combination of dispersant and pH adjustment which resulted in the most stable suspension. First of all, the stability of all dispersion states was evaluated by zeta potential, sediment volume (SV) and height, viscosity, and packing density (PD). Then, the sediment layers of all suspensions were characterized. Incorporation of electrostatic mechanism was resulted in a main decrease in viscosity with high surface charges, while electrosteric mechanism caused lower sedimentation of particles. Fall velocities of particles/agglomerates were estimated, and the influences of dispersion states on the particles fall velocities were characterized. The microstructural observation revealed homogeneous packing of particles in the sediment layer of the stable suspension demonstrating the proper dispersion of particles. Dolapix CE64 and pH adjustment resulted in a uniform arrangement of particles without agglomeration and spherical and regular granules with a uniform shape.     

A greedy MLPG method for identifying a control parameter in 2D parabolic PDEs

In this paper, we consider coefficient inverse problems, which are associated with the identification of unknown time dependent control parameter and unknown solution of two-dimensional parabolic inverse problem with overspecialization at a point in the spatial domain. After suitable finite difference approximation of time variable, an MLPG method is used for spatial discretization. To improve the efficiency of the MLPG method, a greedy algorithm is used. In fact, using the greedy algorithm, we avoid using more points from the data site than absolutely necessary and therefore, the method becomes more efficient. Comparison of the different kind of point selection and the effect of noisy data are performed for four test problems while our last test problem considers a problem with unknown solution. The results reveal that the method is efficient.     

Effect of cerium ion addition on corrosion and wear characteristics of plasma electrolytic oxidation coating of CP-Ti

Cerium containing coatings are interested because of corrosion and wear resistance characteristics, in another point valve metals have the ability to be treated with plasma electrolytic oxidation (PEO). Different cerium sources, from base metal, pretreatment, post treatment and electrolyte are implemented for Mg alloys. In this research Ti substrates was treated via PEO in less studied, cerium chloride containing electrolytes. Effect of cerium ion concentration was studied on morphology, corrosion and wear properties using SEM, FTIR, polarization, EIS, pin on disk experiments. It was observed that cerium participates in coatings slightly and there is an optimum content for cerium ions in electrolytes which results in improved corrosion and wear properties, mostly from modifying coating roughness and morphology. Addition of cerium ions to electrolyte, first decreases and then increases coating roughness and coefficient of friction.     

Amine-functionalized and non-functionalized mesoporous silica nanoparticles as the delivery system for tertiary butylhydroquinone (TBHQ)

Journal of Porous Materials - The aim of this study was to encapsulate 2-tert-butylhydroquinone (TBHQ), as a common synthetic antioxidant in food industries, by mesoporous silica nanoparticles...     

In situ emulsion polymerization and characterization of PVAc nanocomposites including colloidal silica nanoparticles for wood specimens bonding

Polyvinyl acetate (PVAc) nanocomposites for wood adhesives containing different amounts of colloidal silica nanoparticles (CSNs) were synthesized via in situ one-step emulsion polymerization. The adhesion strength of wood specimens bonded by PVAc nanocomposites was investigated by the tensile test. Thermal properties of PVAc nanocomposites were also characterized by differential scanning calorimetry and thermogravimetric analysis. Rheological and morphological properties of the PVAc nanocomposites were investigated using rheometric mechanical spectrometry and field emission scanning electron microscopy (FESEM), respectively. The obtaining results showed that the shear strength of PVAc nanocomposite including 1 wt. % CSNs has the highest shear and tensile strength about 4.7 and 3.2 MPa, respectively. A small increment of T_g (~3 °C) and considerable increment of the ash content proved the enhancement of PVAc thermal characterization in the presence of CSNs. FESEM results showed uniform dispersion of nanoparticles throughout the PVAc matrix due to using the in situ emulsion polymerization process. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48570.