Al2O3/Yttria‐Stabilized Zirconia Hollow‐Fiber Membrane Incorporated with Iron Oxide for Pb(II) Removal

Removal by absorptive ceramic membranes can simultaneously absorb and separate metal ions from water. Alumina/yttria‐stabilized zirconia (Al₂O₃/YSZ) hollow‐fiber membranes, fabricated using phase inversion and sintering process, were deposited with iron oxide by an in‐situ hydrothermal process. The results showed that α‐Fe₂O₃ was produced and incorporated across the membranes. A reduction in flux was recorded with the deposition of α‐Fe₂O_3. However, it improved the adsorption capacity for heavy metal adsorption. The adsorption‐separation test demonstrated that the optimized membrane is able to completely remove Pb(II) ions after two hours.     

Transesterification of Palm-based Methyl Palmitate into Esteramine Catalyzed by Calcium Oxide Catalyst

The technology for transesterification reactions between methyl esters and alcohols is well established by using classical homogeneous alkaline catalysts, which provide high conversion of methyl esters to specialty or nonindigenous esters. However, in certain products where the purity of the esters is of concern, the removal of homogeneous catalysts after the completion of the reaction is a challenge in terms of production cost and water footprint. Therefore, a study to investigate the potential of heterogeneous catalysts was conducted on reactions between methyl palmitate and triethanolamine. The degree of basicity and active surface area of calcium oxide (CaO), zinc oxide (ZnO), and magnesium oxide (MgO) were first characterized by using temperature-programmed desorption (TPD-CO₂) and Brunauere–Emmett–Teller (BET), respectively. Among the metal oxides investigated, the CaO catalyst showed the best catalytic activity toward the transesterification process as it gave the highest conversion of methyl palmitate and yielded fatty esteramine compositions similar to the conventional homogeneous catalyst. The optimum transesterification condition by using the CaO catalyst utilized a lower vacuum system of approximately 200 mbar, which could minimize a considerable amount of energy consumption. Furthermore, low CaO dosage of 0.1% was able to give a conversion of 94.5% methyl ester and formed esteramine at 170 °C for 2 h. Therefore, the production of esterquats from esteramine may become more economically feasible through the methyl ester route by using the CaO catalyst, which can be recycled three times.     

Performance evaluation of directory protocols on an optical broadcast-based distributed shared memory multiprocessor

Recent advances in the development of optical technologies suggest the possible emergence of broadcast-based optical interconnects within cache-coherent distributed shared memory (DSM) multiprocessor architectures. It is well known that the cache-coherence protocol is a critical issue in designing such architectures because it directly affects memory latencies. In this paper, we evaluate via simulation the performance of three directory-based cache-coherence protocols; strict request-response, intervention forwarding and reply forwarding on the Simultaneous Optical Multiprocessor Exchange Bus (SOME-Bus), which is a low-latency and high-bandwidth broadcast-based fiber-optic interconnection network supporting DSM. The simulated system contains 64 nodes, each of which has a processor, a cache controller, a directory controller and an output channel. Simulations have been conducted for each protocol to measure average processor utilization, average network latency and average number of packets transferred over the network for varying values of the important DSM parameters such as the ratio of the mean channel service time to mean thread run time (T/R), probability of a cache block being in modified state {P(M)}, the fraction of write misses {P(W)} and home node contention rate. The results reveal that for all cases, except for low values of P(M), intervention forwarding gives the worst performance (lowest processor utilization and highest latency). The performance of strict request-response and reply forwarding is comparable for several values of the DSM parameters and contention rate. For a contention rate of 0%, the increase of P(M) makes reply forwarding perform better than strict request-response. The performance of all protocols decreases with the increase of P(W) and contention rate. However, the performance of strict request-response is the least affected among other protocols due to the negative impact of the increase of P(W) and contention rate. Therefore, for the full contention case (i.e. contention rate of 100%); for low values of P(M), or for mid values of P(M) and high values of P(W), strict request-response performs better than reply forwarding. These results are significant in the sense that they provide an insight to multiprocessor architecture designers for comparing the performance of different directory-based cache-coherence protocols on a broadcast-based interconnection network for different values of the DSM parameters and varying rates of contention.     

Implementation of genetic algorithm in an embedded microcontroller-based polarization control system

Implementation of genetic algorithm in a PIC32MX microcontroller-based polarization control system is proposed and demonstrated. The controller measures the signal intensity that is used to estimate the genetic value. This process is controlled by the genetic algorithm rather than referring to the Look-Up-Table as implemented in existing solutions. To reach optimum performance, the code is optimized by using the best genetic parameters so that the fastest execution time can be achieved. An ability of genetic algorithm to work efficiently in polarization control system possesses many advantages including easy code construction, low memory consumption and fast control speed. Genetic algorithm is intelligent enough to be used for endless polarization stabilization and in the worst case, able to stabilize the polarization changes in 300 μs. In the best case the response time can reach 17 μs.     

Hardware-software co-synthesis of hard real-time systems with reconfigurable FPGAs

Real-time systems cover a wide application domain. This paper presents an efficient heuristic algorithm for enforcing the schedulability of aperiodic hard real-time tasks arriving simultaneously with precedence constraints and individual deadlines. The proposed co-synthesis algorithm integrates partitioning and non-preemptive scheduling. Reconfigurable FPGAs are incrementally added when schedulability suffers in a uniprocessor system. Initially, a schedule that minimizes the maximum lateness and satisfies the precedence constraints is made. If individual timing constraints are not met in this schedule, some tasks are selected and transferred to dynamically reconfigured FPGAs. The proposed algorithm was implemented and tested with a large number of task graphs with task size as high as 700 nodes. The algorithm could not only achieve schedulability but also could reduce the total completion time of the task graph. Moreover, incremental addition of reconfigurable FPGAs yielded a cost effective solution.     

Memory and the Reporting of Remittance in a Sample of Elderly Persons in Thailand

Accurate reporting of sources of income is needed in studies of intergenerational transfers and welfare of the elderly. The objective of this paper is to investigate how memory in the elderly is related to the reporting of remittances received from their children in Thailand. Using data from a longitudinal study of 1036 persons age 60 to 93 in a province in Thailand, the influence of a word recall (verbal learning and recall), and nickname recall (verbal learning and recall) on reporting of remittance was assessed. Initially, both measures were positively and significantly related to the reporting of remittance. The results remained significant only for the nickname task after controlling for education, wealth, living arrangements and disability. The results highlight the importance of cognitive issues in the quality of data and the need for attention to memory in questionnaire design.     

Antioxidant and α-glucosidase inhibitory activities of eight neglected fruit extracts and UHPLC-MS/MS profile of the active extracts

The 70% ethanolic extracts from eight neglected fruits; Muntingia calabura, Leucaena leucocephala, Spondias dulcis, Syzygium jambos, Mangifera caesia, Ardisia elliptica, Cynometra cauliflora and Ficus auriculata were evaluated for their 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical scavenging, α-glucosidase inhibitory activities as well as total phenolic content. The results of this study revealed that M. caesia fruit extract demonstrated the most potent radical scavenging activity. Among the fruits examined for α-glucosidase inhibitory activity, M. calabura and F. auriculata exhibited strong activity with no significant difference. The Pearson correlation indicated that the activities of M. caesia and F. auriculata contributed by phenolic compounds. A total of 65 metabolites were tentatively identified by using ultra-high-performance liquid chromatography tandem mass spectrometry (UHLPC-MS/MS). These findings suggested that the possible application of M. caesia and F. auriculata as a functional food with antioxidant and α-glucosidase inhibitory properties.     

Efficient synthesis of enwrapped CuO@rGO nanowire arrays to improve supercapacitor electrode performance

Journal of Applied Electrochemistry - There has been a growing interest in the performance of supercapacitors (SCs) based on Transition Metal Oxides (TMOs). It has recently been included in...     

NODIC: a novel distributed clustering routing protocol in WSNs by using a time-sharing approach for CH election

Wireless Networks - Due to the battery limitations, energy-efficient routing is one of the most important issues in WSNs. In this paper, a novel distributed clustering routing protocol (NODIC) is...     

An efficient extraction and clean‐up procedure for pesticide determination in olive oil

This work reports a simple, rapid, and effective extraction method based on liquid–liquid extraction (LLE) followed by matrix solid‐phase dispersion‐sonication for detection, identification and quantification of multiclass pesticides in virgin olive oil using liquid chromatography mass spectrometry (LC‐QTOF‐MS). LLE to extract pesticide residues in virgin olive oil was performed in order to study the centrifugation efficiency to obtain high recovery yield and low co‐extract fat residue in the final extract. Different suitable parameters of MSPD procedure were evaluated, such as nature of dispersing phase, clean‐up adsorbent, and volume of eluting solvent (acetonitrile) in different extraction conditions, with or without sonication. The best results were obtained using 5 g of virgin olive oil, 2 g of PSA as dispersant sorbent, 2 g of Florisil/GCB (70:30 w/w) as clean‐up sorbent, and 15 mL of acetonitrile as eluting solvent under conditions of 15 min ultrasonic bath at RT. Method validation was performed in order to study sensitivity, linearity, precision, and accuracy. Average recoveries ranged between 73.7 and 104.2% with relative SDs 5.3–13.4% at three concentration levels (25, 50, and 100 µg/kg). Detection and quantification limits ranged from 1.5 to 5 µg/kg and 3 to 9 µg/kg, respectively.