On scaling the IEEE 802.11 to facilitate scalable wireless networks

The IEEE 802.11 MAC protocol has gained widespread popularity and has been adopted as the de-facto layer 2 protocol for wireless local area networks (WLANs). However, it is well known that as the number of competing stations increases, the performance of the protocol degrades dramatically. Given the explosive growth in WLANs’ usage, the question of how to sustain each user’s perceived performance when a large number of competing stations are present, is an important and challenging open research problem.Motivated by this, in this paper we analyze the behavior of 802.11-based WLANs as the number of competing stations increases, and attempt to provide concrete answers to the following fundamental questions: (i) is there a set of system and protocol parameters that we can scale in order to sustain each individual user’s perceived performance, and (ii) what is the minimum scaling factor?Using theoretical analysis coupled with extensive simulations we show that such a set of parameters exists, and that the minimum scaling factor is equal to the factor by which the number of users increases. Our results reveal several important scaling properties that exist in today’s 802.11-based wireless networks, and set guidelines for designing future versions of such networks that can efficiently support a very large number of users.     

Development of [60] fullerene supported on silica catalysts for the photo-oxidation of alkenes

Simple or successive incipient wetness impregnation followed by heating at 180 °C is proved an efficient preparation method for dispersing effectively onto the silica surface various amounts of C₆₀ in the range 1–4% (w/w). BET, XRD, DRS, TGA, microelectrophoresis and photoluminescence have been used to characterize the photocatalysts prepared. A high dispersion was obtained for the quite stable supported C₆₀ phase, comprised mainly from relatively small or medium size C₆₀ clusters/aggregates. The photocatalytic activity was assessed in the singlet oxygen oxidation of alkenes by examining the photo-oxygenation of 2-methyl-2-heptene as a probe reaction. The catalytic tests were carried out at 0–5 °C in CH₃CN, under oxygen atmosphere and using a 300 W xenon lamp as the light source. The heterogeneous catalysts obtained were proved to be active in the photocatalytic oxidation of olefins via a ¹O₂ ene reaction. The catalysts exhibited significant conversion, turnover number and turnover frequency values, substantially higher than those achieved over the unsupported C₆₀. The conversion increases with the amount of the supported C₆₀ up to a value equal to 3% (w/w) and then it decreases whereas turnover number and turnover frequency decreases monotonically as the amount of the supported C₆₀ increases. The easy separation of these solid catalysts from the reaction mixture, the high activity and stability as well as the retained activity in subsequent catalytic cycles, make these supported catalysts suitable for a small-scale synthesis of fine chemicals.     

Decatungstate catalyst supported on silica and γ-alumina: Efficient photocatalytic oxidation of benzyl alcohols

Four supported catalysts with the same tungsten loading were prepared by depositing decatungstate species W₁₀O⁴⁻₃₂, through wet impregnation, on the surface of γ-alumina and silica at different pH values. The prepared samples were characterized using BET measurements as well as XRD, UV–vis DR, and XP spectroscopies. Higher dispersion of W(VI) oxo-species was obtained in the silica-supported catalysts compared with the corresponding alumina-supported ones. Within the same support, the dispersion was higher when the impregnation pH is lower than the point of zero charge (pzc) of the support. The decatungstate anions were present mainly on the silica surface without any modification, whereas these underwent a partial depolymerization on their deposition on the γ-alumina surface. The extent of depolymerization was less in the sample prepared at pH above pzc. These findings were explained in terms of the mode of deposition of the W(VI) species from the solution onto the support surface. The photocatalytic activity of the aforementioned catalysts, concerning the photooxidation of 1-phenylethanol, depends on the fraction of the W₁₀O⁴⁻₃₂ supported species rather than on the W(VI) dispersion. Thus, extremely high conversions have been obtained over the silica-based catalysts and also over the γ-alumina-based catalyst prepared at relatively high pH. These catalysts also are very effective in the photooxidation of a series of secondary and primary benzyl alcohols, in which benzyl ketones and benzoic acids were formed as the only or major products, respectively. The easy separation of the solid catalyst from the reaction mixture, the high activity, selectivity, and stability as well as the retained activity in subsequent catalytic cycles, make these supported catalysts suitable for a small-scale synthesis. Based on product analysis and kinetic data on the heterogeneous oxidation of benzyl alcohols, we suggest that a hydrogen abstraction transfer (HAT) mechanism predominates with respect to an electron transfer (ET) one in these reactions.     

Deep Affect Prediction in-the-Wild: Aff-Wild Database and Challenge,Deep Architectures,and Beyond

International Journal of Computer Vision - Automatic understanding of human affect using visual signals is of great importance in everyday human–machine interactions. Appraising human...     

A Statistical Metadata Model for Simultaneous Manipulation of both Data and Metadata

There is a growing demand for more cost-efficient production processes in Statistical Institutes. One way to address this need is to equip Statistical Information Systems (SIS) with the ability to automatically produce statistical data and metadata of high quality and deliver them to the user via the Internet. Current approaches, although provide for the storage of appropriate metadata, do not use process metadata for guiding the production process. In this paper we present an approach on creating SISs that permits metadata-guided statistical processing based on an object-based, statistical metadata model. The model is not domain specific and can accommodate both microdata and macrodata. We have equipped the model with a set of transformations that can be used to automatically manipulate data and metadata. We show the applicability of transformations with some examples using actual statistical data for R&D expenditures. Finally, we demonstrate how the presented framework can be exploited for the construction of a web site that offers ad hoc query capabilities to the users of statistical data.     

Performance analysis of BitTorrent-like systems with heterogeneous users

Among all peer-to-peer (P2P) systems, BitTorrent seems to be the most prevalent one. This success has drawn a great deal of research interest on the system. In particular, there have been many lines of research studying its scalability, performance, efficiency, and fairness. However, despite the large body of work, there has been no attempt mathematically to model, in a heterogeneous (and hence realistic) environment, what is perhaps the most important performance metric from an end user’s point of view: the average file download delay.

In this paper we propose a mathematical model that accurately predicts the average file download delay in a heterogeneous BitTorrent-like system. Our model is quite general, has been derived with minimal assumptions, and requires minimal system information. Then, we propose a flexible token-based scheme for BitTorrent-like systems that can be used to tradeoff between overall system performance and fairness to high bandwidth users, by properly setting its parameters. We extend our mathematical model to predict the average file download delays in the token- based system, and demonstrate how this model can be used to decide on the scheme’s parameters that achieve a target performance/fairness.     

Mapping objects

We present a technique that is based on volatile mapping objects and enables wrappers-based mediation architectures to describe bi-directional (read–write) interschema mappings of multiple, disparate data sources. We describe the structure of these mapping objects, explain how they work, and compare them to other traditional techniques used for describing schema mappings in data-mediation systems.     

A tetrachromatic model for colorimetric use in mesopic vision

In this article, a tetrachromatic colorimetric model is proposed. Four monochromatic stimuli are used as primaries instead of three to achieve colorimetric matches in mesopic vision. Tetrachromatic colorimetric matches are assumed in such a way so as to hold in both the photopic and the scotopic levels of adaptation. The fourth primary helps to balance the rod contribution in mesopic vision. The proposed model is based on the experimental observations that (a) trichromatic matches can be achieved in any light level and (b) once a tetrachromatic match is made, it holds at all radiances. The main outcome is that (a) only three channels in human vision system are important for color matching at mesopic and photopic levels and (b) additivity can be preserved at all levels once rod input is taken into account. © 2010 Wiley Periodicals, Inc. Col Res Appl, 2011     

CO2 solubility in aqueous N-methylcyclohexylamine (MCA) and N-cyclohexyl-1,3-propanediamine (CHAP) solutions

N-methylcyclohexylamine (MCA) and N-cyclohexyl-1,3-propanediamine (CHAP) have been suggested, in mixtures with lipophilic amines, as potential phase change solvents for CO₂ capture applications, and subsequently studied as promising alternatives to monoethanolamine (MEA) for minimizing the desorber's energy requirements. In this study, new high pressure experimental data were obtained for the solubility of CO₂ in aqueous solutions containing MCA or CHAP at 313 and 333 K. The obtained data were used to parameterize the modified Kent–Eisenberg model. In this direction, CHAP was modeled assuming a “principle of independent reactivity,” that is, that the reactivity of each amine group does not depend on the potential reaction of the other one. It was shown that through this approach the model can be successfully applied to diamines using the relevant equations of amine mixtures.