全文获取类型
收费全文 | 391篇 |
免费 | 22篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 1篇 |
综合类 | 1篇 |
化学工业 | 196篇 |
金属工艺 | 16篇 |
机械仪表 | 7篇 |
建筑科学 | 7篇 |
矿业工程 | 1篇 |
能源动力 | 15篇 |
轻工业 | 23篇 |
水利工程 | 2篇 |
石油天然气 | 9篇 |
无线电 | 7篇 |
一般工业技术 | 75篇 |
冶金工业 | 31篇 |
原子能技术 | 1篇 |
自动化技术 | 22篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 34篇 |
2021年 | 36篇 |
2020年 | 10篇 |
2019年 | 16篇 |
2018年 | 14篇 |
2017年 | 13篇 |
2016年 | 12篇 |
2015年 | 13篇 |
2014年 | 19篇 |
2013年 | 23篇 |
2012年 | 22篇 |
2011年 | 27篇 |
2010年 | 8篇 |
2009年 | 15篇 |
2008年 | 17篇 |
2007年 | 13篇 |
2006年 | 13篇 |
2005年 | 14篇 |
2004年 | 18篇 |
2003年 | 9篇 |
2002年 | 11篇 |
2001年 | 8篇 |
2000年 | 3篇 |
1999年 | 4篇 |
1998年 | 2篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1969年 | 1篇 |
1965年 | 1篇 |
1926年 | 2篇 |
1925年 | 2篇 |
排序方式: 共有414条查询结果,搜索用时 16 毫秒
1.
2.
Valentina I. Simagina Pavel A. Storozhenko Olga V. Netskina Oksana V. Komova Galina V. Odegova Yury V. Larichev Arcady V. Ishchenko Anna M. Ozerova 《Catalysis Today》2008,138(3-4):253
Catalytic hydrolysis of NaBH4 and NH3BH3 has been studied. It was shown that the nature of the support and the active component of the catalyst affect the H2 generation rate. Despite similar sizes of rhodium particles formed on the surface of different supports (γ-Al2O3, TiO2, carbon), their reactivity is different. Rh/TiO2 with low rhodium concentration (1 wt.%) is the most active catalyst both in the hydrolysis of NaBH4 and NH3BH3. The obtained results show that the rhodium chloride interaction with titania determines the reactivity of rhodium particles formed under action of NaBH4 medium. TEM, DRS UV–vis and XPS were used to characterize the catalysts. 相似文献
3.
Tkachenko Yurii G. Britun Yurchenko Djema Z. Ochkas Larisa F. Bovkun Galina A. 《Powder Metallurgy and Metal Ceramics》2004,43(1-2):99-104
The influence which the composition of powder mixtures, the treatment conditions which the mixtures are subjected to, and the conditions under which the hot-pressed composite materials B4C – (5-10 mass%) calcium-silicon are fabricated exert on the structure, nature of failure, and mechanical properties of these materials is investigated. Optimum properties are possessed by material containing 10 mass% of addition. It is shown that the structure, morphology, and dispersivity, as well as the nature of the distribution of the components that are added to the composite material (secondary phase) vary as the temperature of hot pressing changes. Maximal mechanical characteristics of the composite material (σbend = 560 MPa, K 1c = 4.7 MPa·m1/2, HV = 37 GPa) are attained at hot-pressing temperatures in the range 2000-2100°C. 相似文献
4.
Factors influencing vitamin C stability in powder mixtures for beverages were studied and the main ways of its decomposition in products preserved in glass containers or paper packages covered with polymeric film were established. The phenomenon of vitamin C self-stabilization has been observed. 相似文献
5.
6.
Galina M. Viryasova Ekaterina A. Golenkina Tibor Hianik Nataliya V. Soshnikova Nina G. Dolinnaya Tatjana V. Gaponova Yulia M. Romanova Galina F. Sudina 《International journal of molecular sciences》2021,22(5)
Neutrophil-mediated innate host defense mechanisms include pathogen elimination through bacterial phagocytosis, which activates the 5-lipoxygenase (5-LOX) product synthesis. Here, we studied the effect of synthetic oligodeoxyribonucleotides (ODNs), which mimic the receptor-recognized sites of bacterial (CpG-ODNs) and genomic (G-rich ODNs) DNAs released from the inflammatory area, on the neutrophil functions after cell stimulation with Salmonella typhimurium. A possible mechanism for ODN recognition by Toll-like receptor 9 (TLR9) and RAGE receptor has been proposed. We found for the first time that the combination of the magic peptide LRR11 from the leucine-rich repeat (LRR) of TLR9 with the CpG-ODNs modulates the uptake and signaling from ODNs, in particular, dramatically stimulates 5-LOX pathway. Using thickness shear mode acoustic method, we confirmed the specific binding of CpG-ODNs, but not G-rich ODN, to LRR11. The RAGE receptor has been shown to play an important role in promoting ODN uptake. Thus, FPS-ZM1, a high-affinity RAGE inhibitor, suppresses the synthesis of 5-LOX products and reduces the uptake of ODNs by neutrophils; the inhibitor effect being abolished by the addition of LRR11. The results obtained revealed that the studied peptide-ODN complexes possess high biological activity and can be promising for the development of effective vaccine adjuvants and antimicrobial therapeutics. 相似文献
7.
Olga Shilova Elena Shramova Galina Proshkina Sergey Deyev 《International journal of molecular sciences》2021,22(9)
Cancer cells frequently overexpress specific surface receptors providing tumor growth and survival which can be used for precise therapy. Targeting cancer cell receptors with protein toxins is an attractive approach widely used in contemporary experimental oncology and preclinical studies. Methods of targeted delivery of toxins to cancer cells, different drug carriers based on nanosized materials (liposomes, nanoparticles, polymers), the most promising designed light-activated toxins, as well as mechanisms of the cytotoxic action of the main natural toxins used in modern experimental oncology, are discussed in this review. The prospects of the combined therapy of tumors based on multimodal nanostructures are also discussed. 相似文献
8.
9.
A new method of preparation of carboxyl cation exchangers directly from methacrylic acid and divinylbenzene is described. A suspension technique with a concentrated aqueous calcium chloride solution as the water phase was used. n-Octane and toluene were inert diluents of the monomers. The copolymers obtained have high ion-exchange capacity (9.6–10.6 mequ./g) and porous structure. 相似文献
10.
E. A. Filonova A. N. Demina E. A. Kleibaum L. Ya. Gavrilova A. N. Petrov 《Inorganic Materials》2006,42(4):443-447
We have revealed the formation of a continuous series of orthorhombic LaMn1 ? y FeyO3 solid solutions (0<y<1); La1 ? x SrxFeO3 solid solutions in the composition range 0 < x ≤ 0.8, with an orthorhombic structure at 0 < x ≤ 0.6 and a cubic structure at 0.6 < x ≤ 0.8; and a tetragonal SrMn1 ? y FeyO3 phase in the range 0.6 ≤ y ≤ 1. The composition stability limits of the perovskite phase La1 ? x SrxMn1 ? y FeyO3 have been determined, and the 1100°C isotherm of the La2O3-SrO-Mn3O4-Fe2O3 system in air has been constructed. 相似文献