全文获取类型
收费全文 | 415篇 |
免费 | 17篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 3篇 |
综合类 | 1篇 |
化学工业 | 205篇 |
金属工艺 | 18篇 |
机械仪表 | 7篇 |
建筑科学 | 7篇 |
矿业工程 | 1篇 |
能源动力 | 12篇 |
轻工业 | 22篇 |
水利工程 | 2篇 |
石油天然气 | 27篇 |
无线电 | 7篇 |
一般工业技术 | 66篇 |
冶金工业 | 31篇 |
原子能技术 | 1篇 |
自动化技术 | 23篇 |
出版年
2023年 | 3篇 |
2022年 | 34篇 |
2021年 | 35篇 |
2020年 | 10篇 |
2019年 | 16篇 |
2018年 | 12篇 |
2017年 | 11篇 |
2016年 | 14篇 |
2015年 | 11篇 |
2014年 | 16篇 |
2013年 | 21篇 |
2012年 | 21篇 |
2011年 | 27篇 |
2010年 | 9篇 |
2009年 | 14篇 |
2008年 | 16篇 |
2007年 | 12篇 |
2006年 | 11篇 |
2005年 | 14篇 |
2004年 | 18篇 |
2003年 | 9篇 |
2002年 | 12篇 |
2001年 | 9篇 |
2000年 | 3篇 |
1999年 | 4篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1991年 | 2篇 |
1989年 | 5篇 |
1988年 | 4篇 |
1986年 | 4篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 4篇 |
1980年 | 3篇 |
1979年 | 5篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 2篇 |
1970年 | 1篇 |
1969年 | 2篇 |
1967年 | 1篇 |
1966年 | 2篇 |
1965年 | 1篇 |
1926年 | 2篇 |
1925年 | 2篇 |
排序方式: 共有433条查询结果,搜索用时 15 毫秒
1.
2.
Valentina I. Simagina Pavel A. Storozhenko Olga V. Netskina Oksana V. Komova Galina V. Odegova Yury V. Larichev Arcady V. Ishchenko Anna M. Ozerova 《Catalysis Today》2008,138(3-4):253
Catalytic hydrolysis of NaBH4 and NH3BH3 has been studied. It was shown that the nature of the support and the active component of the catalyst affect the H2 generation rate. Despite similar sizes of rhodium particles formed on the surface of different supports (γ-Al2O3, TiO2, carbon), their reactivity is different. Rh/TiO2 with low rhodium concentration (1 wt.%) is the most active catalyst both in the hydrolysis of NaBH4 and NH3BH3. The obtained results show that the rhodium chloride interaction with titania determines the reactivity of rhodium particles formed under action of NaBH4 medium. TEM, DRS UV–vis and XPS were used to characterize the catalysts. 相似文献
3.
Tkachenko Yurii G. Britun Yurchenko Djema Z. Ochkas Larisa F. Bovkun Galina A. 《Powder Metallurgy and Metal Ceramics》2004,43(1-2):99-104
The influence which the composition of powder mixtures, the treatment conditions which the mixtures are subjected to, and the conditions under which the hot-pressed composite materials B4C – (5-10 mass%) calcium-silicon are fabricated exert on the structure, nature of failure, and mechanical properties of these materials is investigated. Optimum properties are possessed by material containing 10 mass% of addition. It is shown that the structure, morphology, and dispersivity, as well as the nature of the distribution of the components that are added to the composite material (secondary phase) vary as the temperature of hot pressing changes. Maximal mechanical characteristics of the composite material (σbend = 560 MPa, K 1c = 4.7 MPa·m1/2, HV = 37 GPa) are attained at hot-pressing temperatures in the range 2000-2100°C. 相似文献
4.
V. I. Kodolov S. G. Shuklin A. P. Kuznetsov L. G. Makarova S. G. Bystrov O. V. Demicheva T. A. Rudakova 《应用聚合物科学杂志》2002,85(7):1477-1483
Results are reported of research on intumescent composites based on epoxy resin cross‐linked with polyethylene polyamine and containing ammonium polyphosphate and such modifying additives as calcium borate, manganese dioxide, nickel, and chromium, containing tubulenes as gas‐formers and carbonization stimulators. The changes in composition and physicochemical properties of modified compositions under conditions of heat and fire were investigated by X‐ray photo‐electron spectroscopy, atomic force microscopy, and local force spectroscopy. Ammonium polyphosphate mainly stimulates carbonization processes on the inner surface of a bubble being formed during foam coke formation. The introduction of metal‐containing tubulenes leads to the formation of fire‐retardant and low flammability‐compositions with high coke and carbon structures content. The use of calcium borate in the compositions considerably increases the strength of foam coke being formed. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1477–1483, 2002 相似文献
5.
6.
Olga Shilova Elena Shramova Galina Proshkina Sergey Deyev 《International journal of molecular sciences》2021,22(9)
Cancer cells frequently overexpress specific surface receptors providing tumor growth and survival which can be used for precise therapy. Targeting cancer cell receptors with protein toxins is an attractive approach widely used in contemporary experimental oncology and preclinical studies. Methods of targeted delivery of toxins to cancer cells, different drug carriers based on nanosized materials (liposomes, nanoparticles, polymers), the most promising designed light-activated toxins, as well as mechanisms of the cytotoxic action of the main natural toxins used in modern experimental oncology, are discussed in this review. The prospects of the combined therapy of tumors based on multimodal nanostructures are also discussed. 相似文献
7.
8.
A new method of preparation of carboxyl cation exchangers directly from methacrylic acid and divinylbenzene is described. A suspension technique with a concentrated aqueous calcium chloride solution as the water phase was used. n-Octane and toluene were inert diluents of the monomers. The copolymers obtained have high ion-exchange capacity (9.6–10.6 mequ./g) and porous structure. 相似文献
9.
Yurii G. Tkachenko Viktor F. Britun Emmanuil V. Prilutskii Dzhemma Z. Yurchenko Galina A. Bovkun 《Powder Metallurgy and Metal Ceramics》2005,44(3-4):196-201
We have investigated how the composition, grain morphology, and method of preparing the starting mixture affect the processes that form the structure and phase composition of B4C - SiC composites during hot pressing. We found that, depending on the composition of the initial powder mixtures, which is responsible for different mechanisms of consolidation of ceramic materials during hot pressing, the grain size of the main B4C phase and its defect content as well as the nature of the SiC phase distribution within the material differ significantly. When B4C - SiC composites with a low SiC content are made from initial B4C - B4Si - B - C powder mixtures those composites have a high cracking resistance because of their fine grain structure.__________Translated from Poroshkovaya Metallurgiya, Nos. 3–4(442), pp. 112–119, March–April, 2005. 相似文献
10.
Mikhail G. Akimov Alina M. Gamisonia Polina V. Dudina Natalia M. Gretskaya Anastasia A. Gaydaryova Andrey S. Kuznetsov Galina N. Zinchenko Vladimir V. Bezuglov 《International journal of molecular sciences》2021,22(2)
GPR55 is a GPCR of the non-CB1/CB2 cannabinoid receptor family, which is activated by lysophosphatidylinositol (LPI) and stimulates the proliferation of cancer cells. Anandamide, a bioactive lipid endocannabinoid, acts as a biased agonist of GPR55 and induces cancer cell death, but is unstable and psychoactive. We hypothesized that other endocannabinoids and structurally similar compounds, which are more hydrolytically stable, could also induce cancer cell death via GPR55 activation. We chemically synthesized and tested a set of fatty acid amides and esters for cell death induction via GPR55 activation. The most active compounds appeared to be N-acyl dopamines, especially N-docosahexaenoyl dopamine (DHA-DA). Using a panel of cancer cell lines and a set of receptor and intracellular signal transduction machinery inhibitors together with cell viability, Ca2+, NO, ROS (reactive oxygen species) and gene expression measurement, we showed for the first time that for these compounds, the mechanism of cell death induction differed from that published for anandamide and included neuronal nitric oxide synthase (nNOS) overstimulation with concomitant oxidative stress induction. The combination of DHA-DA with LPI, which normally stimulates cancer proliferation and is increased in cancer setting, had an increased cytotoxicity for the cancer cells indicating a therapeutic potential. 相似文献