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排序方式: 共有132条查询结果,搜索用时 15 毫秒
1.
2.
An experimental study has been carried out of debonding and fibre rupture in model composites. A single glass rod or fibre was embedded in the centre of a long transparent silicone rubber block. Strains in the rubber in close proximity to the rod or fibre were measured as the specimen was slowly stretched. Pull-out forces, strain distributions, and debonded lengths are compared with the predictions of a simple theory based on a fracture energy criterion for debonding, and taking into account friction at the debonded interface. Experiments were carried out with rods of different diameter, rubber blocks of varied cross-section, and with two levels of adhesion. By extrapolating the debonded length to zero, values of the debonding force in the absence of friction were obtained. They were in accord with fracture energies of about 50 J/m2 for weak bonding and about 200 J/m2 for strong bonding. Fibre fragmentation lengths were measured also. They were in reasonable agreement with the inferred fracture energies and the measured frictional properties of silicone rubber sliding on glass. In a separate study, it was found that the frictional stress between cast silicone rubber and glass was approximately constant, about 0.1 MPa, rather than proportional to pressure, for pressures exceeding about 0.02 MPa. This feature is attributed to a particularly smooth interface between the two materials. 相似文献
3.
The strength of adhesion of elastomers to rigid substrates generally increases with time of contact. This effect has been studied for samples of butyl and chlorobutyl rubber adhering to some rigid substrates. The peel strength increased continuously over long periods of contact until in some cases failure became cohesive within the elastomer layer. At higher temperatures the strength increased more rapidly, consistent with the WLF relation governing molecular motions. It is postulated that slow molecular rearrangements occur at the interface and increase the bond strength. A criterion for the observed transition from interfacial to cohesive failure is suggested. 相似文献
4.
A. N. Gent 《The Journal of Adhesion》1987,23(2):115-122
Three new methods are discussed for measuring the work Ga, required to detach unit area of an adhering material from a substrate. The first is a simple modification of the Outwater double-torsion test for long rectangular plates, bonded together. This method is suitable for evaluating aluminum-epoxy bonds, for example, or the transverse strength of fibrous composites. The second is a pull-off test for long strips adhering to a rigid surface. It seems suitable for adhesive tapes and laminates. The third is a reconsideration of the “blister” test for films and coatings, in which a circular debond at the interface is made to grow by internal pressure. The relation obtained between pull-off force F for a strip, or blow-off pressure P for a layer, takes the unusual form:
F4 (or P4) ∞ KG3a
where K is the tensile stiffness of the detaching layer. This dependence arises from the non-linear (cubic) relation between load or pressure and deflection in these configurations. Nevertheless, the product Fθ, where θ is the angle of detachment of a strip, or Py, where y is the height of a “blister”, give direct measures of the strength of adhesion Ga, independent of the stiffness of the adhering material and of the extent of detachment. 相似文献
F4 (or P4) ∞ KG3a
where K is the tensile stiffness of the detaching layer. This dependence arises from the non-linear (cubic) relation between load or pressure and deflection in these configurations. Nevertheless, the product Fθ, where θ is the angle of detachment of a strip, or Py, where y is the height of a “blister”, give direct measures of the strength of adhesion Ga, independent of the stiffness of the adhering material and of the extent of detachment. 相似文献
5.
Fracture mechanics and cavitation in rubber-like solids 总被引:2,自引:0,他引:2
Conditions for propagation of a pressurized crack within a rubber-like solid are derived in terms of the elastic properties of rubber, the fracture energyG
c and the initial radiusr
o of the crack. A previously proposed criterion, that the critical internal pressureP
c for crack growth is given by 5E/6, whereE is the tensile (Young) modulus of elasticity, is shown to be inadequate both for small cracks, when the stiffening of rubber at high strains must be taken into account, and for large cracks, when the critical degree of inflation is so small that the assumptions leading toP
c=5E/6 do not apply. However, this simple criterion is found to remain a useful guide for cracks having initial radii lying in an intermediate range, such thatr
o
E/G
c lies between about 0.0005 and 1. For representative rubber-like solids, this corresponds to the ranger
o=0.5 m to 1 mm. 相似文献
6.
D Vieira-van Bruggen I Kalkman T van Gent A van Tol H Jansen 《Canadian Metallurgical Quarterly》1998,273(48):32038-32041
Hepatic lipase (HL) and scavenger receptor type B class I (SR-BI) have both been implicated in high density lipoprotein (HDL)-cholesteryl ester uptake in cholesterol-utilizing tissues. Inactivation of HL by gene-directed targeting in mice results in up-regulation of SR-BI expression in adrenal gland (Wang, N., Weng, W., Breslow, J. L., and Tall, A. R. (1996) J. Biol. Chem. 271, 21001-21004). The net effect on HDL-cholesteryl ester uptake is not known. We determined the impact of acute in vivo inhibition of rat adrenal HL activity by antibodies on SR-BI expression and on human and rat HDL-[3H]cholesteryl ether (CEth) uptake in the adrenal gland. Rat HDL was isolated from rats in which HL activity had been inhibited for 1 h. The rats were studied under basal conditions (not ACTH-treated) and after previous treatment with ACTH for 6 days (ACTH-treated). Intravenous injection of anti-HL resulted in 70% lowering of adrenal HL activity in both conditions which were maintained for at least 8 h. In not ACTH-treated rats, inhibition of adrenal HL increased adrenal SR-BI mRNA (5.2-fold) and mass (1. 6-fold) within 4 h. HL inhibition resulted in 41% and 14% more adrenal accumulation of human HDL-[3H]CEth during 4 and 24 h, respectively. The adrenal uptake of rat HDL-[3H]CEth increased by 68%, 4 h after the antibody injection. ACTH treatment increased total adrenal HL activity from 3.7 +/- 0.5 milliunits to 34.0 +/- 17. 2 milliunits, as well as adrenal SR-BI mRNA from 2.9 +/- 0.7 arbitrary units (A.U.) to 86.8 +/- 41.1 A.U. and SR-BI mass from 7.7 +/- 1.8 A.U. to 63.16 +/- 46.7 A.U. The human HDL-[3H]CEth uptake by adrenals was also significantly increased from 0.58 +/- 0.11% of injected dose to 7.24 +/- 1.58% of injected dose. Inhibition of adrenal HL activity did not result in further induction of SR-BI expression and did not affect human HDL-[3H]CEth uptake. These findings indicate that SR-BI expression may be influenced by changes in HL activity. HL activity is not needed for the SR-BI-mediated HDL-cholesteryl ester uptake by rat adrenal glands. 相似文献
7.
Draw ratios have been measured for samples of polyethylene and trons-polyisoprene, crystallized at various temperatures and at various degrees of orientation. The values obtained range from unity, i. e., no drawing is observed, up to values of about 15X for materials crystallized in the oriented state and then drawn in a perpendicular direction. The results are in rough accord with a simple molecular network model in which network strands are incorporated into crystallites with a number of reversals of direction (folds), and the remainder of a strand between network junctions is randomly arranged. The reduction in draw ratio with increasing temperature of crystallization and with increasing orientation at the time of crystallization is then accounted for in terms of a reduction in the number of reversals (folds) per molecular strand. Differences in natural draw ratio for different polymers are attributed to variations in characteristic sequence length within a crystallite and in the number of folds per network strand. 相似文献
8.
Markys G. Cain Rebecca L. Cain Michael H. Lewis John Gent 《Journal of the American Ceramic Society》1997,80(7):1873-1876
A novel in situ reaction between a ceria-doped zirconia interphase coating on Saphikon fibers and an outer alumina coating has resulted in the formation of oriented hexaaluminate platelets which can act as a low fracture energy interface barrier for crack deflection in oxide-oxide ceramic-matrix composites (CMCs). The reaction proceeds only in reducing environments where the reduction of the cerium and zirconium ions to their 3+ valent state causes a destabilization phenomenon consistent with previously reported findings. The diffusion of the cerium from the zirconia into solid solution with the alumina can stabilize the layered hexaaluminate structure. Preferred orientational growth of the hexaaluminate parallel to the coating interface was observed which is the required orientation for enhanced debonding at the fiber/matrix interface in long-fiber-reinforced CMCs. 相似文献
9.
Finite element methods have been used to calculate the rate of release of strain energy caused by growth of an internal crack in some model elastic composites under tension. A layer of a linearly elastic material was considered, bonded between two flat or two spherical rigid surfaces. The reduction in strain energy caused by a small circular crack at the interface was found to be only about one-half of that due to a similar crack in the centre of the layer, in accord with the conjecture of Andrews and King. Cracks in the centre of a thin layer bonded between flat surfaces caused about the same release of energy as a crack in the centre of a thick specimen under the same tensile stress. On the other hand, a crack in a thin layer bonded between two spherical surfaces caused a much larger rate of energy release, depending on the radius of the layer relative to its minimum thickness. Growth of an initial crack would thus occur at a small applied stress. For thin layers between both flat and spherical surfaces, the rate of release of energy decreased as the crack grew, indicating that the crack would stabilize at a finite size. These conclusions are in accord with some observations of cracks in thin elastic layers. 相似文献
10.
J. W. Blankenship C. M. Van Gent L. B. Sandberg P. J. Roos J. A. Scharffenberg 《Lipids》1991,26(5):381-384
The incorporation of dietary cholestan-3β, 5α, 6β-triol (triol) into rat thoracic aortic tissue and changes in amino acid
composition of the elastin were investigated to identify the cytotoxic properties of the triol. Weanling male Sprague-Dawley
rats were fed the following diets for three months: (i) normal chow, (ii) normal chow with 1% (w/w) cholesterol added, or
(iii) normal chow with 0.9% (w/w) cholesterol and 0.1% (w/w) triol added. Triol levels in the blood and in the thoracic aortic
tissue were measured. Compositional changes of elastin were also determined. After three months on the triol-containing diet,
triol was found in the thoracic aorta but was not detected in the blood. Amino acid analyses of the aortic tissue elastin
revealed that the proline levels in the triol-fed animals were significantly greater than in the other two diet groups, while
the elastin levels of leucine, aspartate, arginine, and phenylalanine decreased significantly. The mechanism for these observed
changes induced by triol may reflect alternate splicing of elastin messenger ribonucleic acid (mRNA) resulting in structural
changes in the elastin molecule. Dietary triol does contribute to tissue triol content and is associated with aortic elastin
compositional changes. How these changes may contribute to the development of cardiovascular disease is not known. 相似文献