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排序方式: 共有107条查询结果,搜索用时 31 毫秒
1.
Raúl Quijada Juan Luis Guevara Mehrdad Yazdani-Pedram Griselda B. Galland Daniel Ribeiro 《Polymer Bulletin》2002,49(4):273-280
Summary
1-Octadecene (C18) was polymerized by using different metallocene catalysts. The rac-Et(Ind)2ZrC12/MAO (I) and rac-Me2Si(Ind)2ZrC12/MAO (III) presented the highest activity as compared with ra-Et(2-Me-Ind)2ZrCl2/MAO (II) and Ph2C(Flu)(Cp)ZrC12/MAO (IV) catalysts. Catalyst IV produced polymers with highest molecular weights. The microstructure of the polymers was
determined by 13C-NMR spectroscopy. Catalyst systems I, II and III produced isotactic polymers while catalyst IV produced polymers with mainly
syndiotactic structures but with large amount of stereoregular error.
Received: 21 June 2002/Revised version: 4 November 2002/ Accepted: 4 November 2002 相似文献
2.
Griselda A. Eimer Liliana B. Pierella Gustavo A. Monti Oscar A. Anunziata 《Catalysis Letters》2002,78(1-4):65-75
A novel route in the synthesis of Al-MCM-41 and Al-MCM-48, using tetraethoxysilane (TEOS) and sodium aluminate (NaAlO2) as Si and Al source has been obtained. The effect of surfactant nature and the synthesis conditions such as surfactant/Si ratio and hydrothermal treatment time on the formed mesostructure regularity has been studied. Different methods of template removal have also been evaluated. The samples were characterized by X-ray diffraction, nitrogen physisorption, FT-IR, and solid-state MAS NMR spectroscopy. 相似文献
3.
Li Cao Tae Song Kim Susan C. Mantell Dennis L. Polla 《Sensors and actuators. A, Physical》2000,80(3):273-279
Two piezoresistive (n-polysilicon) strain sensors on a thin Si3N4/SiO2 membrane with improved sensitivity were successfully fabricated by using MEMS technology. The primary difference between the two designs was the number of strips of the polysilicon patterns. For each design, a doped n-polysilicon sensing element was patterned over a thin 3 μm Si3N4/SiO2 membrane. A 1000×1000 μm2 window in the silicon wafer was etched to free the thin membrane from the silicon wafer. The intent of this design was to fabricate a flexible MEMS strain sensor similar in function to a commercial metal foil strain gage. A finite element model of this geometry indicates that strains in the membrane will be higher than strains in the surrounding silicon. The values of nominal resistance of the single strip sensor and the multi-strip sensor were 4.6 and 8.6 kΩ, respectively. To evaluate thermal stability and sensing characteristics, the temperature coefficient of resistance [TCR=(ΔR/R0)/ΔT] and the gage factor [GF=(ΔR/R0)/] for each design were evaluated. The sensors were heated on a hot plate to measure the TCR. The sensors were embedded in a vinyl ester epoxy plate to determine the sensor sensitivity. The TCR was 7.5×10−4 and 9.5×10−4/°C for the single strip and the multi-strip pattern sensors. The gage factor was as high as 15 (bending) and 13 (tension) for the single strip sensor, and 4 (bending) and 21 (tension) for the multi-strip sensor. The sensitivity of these MEMS sensors is much higher than the sensitivity of commercial metal foil strain gages and strain gage alloys. 相似文献
4.
Test management aims at organizing, documenting and executing test cases, and at generating execution reports. The adoption of a support tool and of a standard process for such activities is expected to improve the current practice. ITALO is a European project devoted to the evaluation of the benefits coming from test management automation. In this paper the experiences collected and the lessons learned during ITALO are summarized. A formal methodology was adopted for the selection of a support tool among those available from the market. A survey of the current practice in component testing was conducted to adapt the existing process model so as to obtain the greatest benefits from automation. An empirical study was then designed to measure the effects that are expected to be produced by the new test process complemented with the introduction of the support tool. Three pilot projects were conducted to measure the benefits obtained from tool usage and process modification. Results are presented and discussed in this paper. 相似文献
5.
Griselda Castruita-de León Claudia Y. Yeverino-Miranda Angel de J. Montes-Luna Hector Iván Meléndez-Ortiz German Alvarado-Tenorio Luis Alfonso García-Cerda 《应用聚合物科学杂志》2020,137(3):48286
Flat mixed matrix membranes (MMMs) comprising polysulfone and clinoptilolite-type natural zeolite were prepared by casting. Zeolite was modified with three alkylamines: ethanolamine (EA), bis(2-hydroxypropyl)amine (BHPA), and polyethylenimine (PEI) by the impregnation method. Impregnated zeolite samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and N2 adsorption–desorption. The alkylamine loading extent determined by thermogravimetric analysis was 5.2, 4.8, and 8.5% for EA, BHPA, and PEI, respectively. Analyses of MMMs showed that the incorporation of impregnated zeolite affected the glass-transition temperature (Tg) and mixed-gas transport properties. In this regard, a decreasing trend of the Tg values from 185.5 °C for the polymeric membrane up to 176.6 °C for Clino-EA-based MMM was recorded. In addition, the gas separation performance was evaluated at two different feed pressures. At 50 psi, MMMs showed an enhancement up to 30% on the CO2 permeability (22.79 Barrer) and 55% on the CO2/CH4 selectivity (45.78) in comparison with the polymeric membrane (CO2 permeability 17.34 Barrer; CO2/CH4 selectivity 29.38). These values varied depending on the alkylamine, BHPA being the most selective. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48286. 相似文献
6.
Physicochemical Characterization of a Heat Treated Calcium Alginate Dry Film Prepared with Chicken Stock
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Germán D. Báez Gisela N. Piccirilli Griselda A. Ballerini Agustín Frattini Pablo A. Busti Roxana A. Verdini Néstor J. Delorenzi 《Journal of food science》2017,82(4):945-951
Solid sodium alginate was dissolved into chicken stock in order to give a final alginate concentration of 0.9 percent (w/v). Calcium ions present in chicken stock were enough to induce ionic gelation. After drying, Fourier transform infrared spectroscopy, thickness and mechanical properties of films obtained were determined. Calcium alginate‐chicken stock films were heated at 130 °C for different times between 0 and 15 min. Mechanical and optical studies, differential scanning calorimetry, visual aspect and scanning electron microscopy were carried out to describe physicochemical properties of heat treated films. Heating developed a maroon ochre color and increased the brittleness (crispness) of the films related to the intensity of the treatment. Differential scanning thermometry and study on appearance of the films suggested that Maillard reactions may be responsible for the observed changes. Maillard reactions mainly occurred between reducing sugar monomers and free amino groups of gelatin peptides present in the chicken stock, and between alginate and gelatin peptides to a lesser extent. In addition, the plasticizing effect of fat added with chicken stock was also studied. These studies suggest a potential use of heat treated chicken stock films as a substitute of roasted chicken skin. 相似文献
7.
Griselda Deelstra Ahmed Ezzine Dries Heyman Michèle Vanmaele 《Computational Economics》2007,29(2):139-149
This paper studies a strategy that minimizes the Value-at-Risk (VaR) of a position in a zero-coupon bond by buying a percentage
of a put option, subject to a fixed budget available for hedging. We elaborate a formula for determining the optimal strike
price for this put option in case of a Vasicek stochastic interest rate model. We demonstrate the relevance of searching the
optimal strike price, since moving away from the optimum implies a loss, either due to an increased VaR or due to an increased
hedging expenditure. In this way, we extend the results of [Ahn, Boudoukh, Richardson, and Whitelaw (1999). Journal of Finance, 54, 359–375] who minimize VaR for a position in a share. In addition, we look at the alternative risk measure Tail Value-at-Risk. 相似文献
8.
Ibrahim M. J. Mohialdeen Sardar S. Fatah Rzger A. Abdula Mohammed H. Hakimi Wan H. Abdullah Polla A. Khanaqa Grenville A. Lunn 《Journal of Petroleum Geology》2022,45(1):29-56
The Upper Triassic Baluti Formation has been identified and mapped based on its log response in selected wells from the Zagros foldbelt in the Kurdistan Region of northern Iraq. A preliminary evaluation of the formation's source rock potential was made by Rock-Eval screening analysis in four wells along a NW-SE profile (Atrush-1, Shaikan-5B, Taq Taq-22 and Miran-2) with maturity determined from reflectance measurements in samples from well Taq Taq-22. The Baluti Formation consists of thinly interbedded shales, carbonates and anhydrite ranging in thickness from 48 m in well Atrush-1 to 118 m in well Miran-2. The Rock-Eval screening was conducted primarily on bulk cuttings samples plus selected picked cuttings. The TOC content is low to moderate (0.23 to 1.14 wt%). However, the shale content in many of the analysed bulk samples was relatively low, making assessment of the source potential problematic. The highest TOCs are recorded from the thickest analysed sections from wells Miran-2 and Taq Taq-22, where high-gamma bituminous shales are present. Rock-Eval Tmax values ranging from 295 to 438°C are not consistent with estimates of pre-Zagros burial to depths of between 4600 m (Atrush-1) and 6900 m (Miran-2). The relatively low Tmax values suggest that the S2 response does not reflect kerogen pyrolysis in these samples and may be due to the presence of solid bitumen, which is observed in the Baluti Formation in at least three of the study wells (Taq Taq-22, Miran-2 and Shaikan-5B). Little pyrolysable organic matter remains in the formation due to the interpreted deep pre-Zagros burial and the consequent high maturity in Taq Taq-22 (VR = 1.51%Ro) and Miran-2 (estimated VR >2%Ro), and the poor source character in Atrush-1 and Shaikan-5B. Organic petrography suggests the presence of vestiges of Types I and II kerogen in Taq Taq-22, with bitumen observed as stains in the matrix of the shales and also in the pores and fractures of interbedded dolostones. However, bitumen reflectance determinations for Taq Taq-22 indicate an equivalent vitrinite reflectance maturity of no more than 0.93%Ro, which is significantly less than that of the indigenous vitrinite, implying the solid bitumen in this well is derived primarily from migrated hydrocarbons. Further detailed analysis is required, but the results suggest that the Baluti Formation may have sourced hydrocarbons in its depocentre which is identified in this study as covering a NW-SE trending area between Bekhme and Sangaw. 相似文献
9.
Y. S. Yoon J. H. Kim A. M. Schimidt D. L. Polla Q. Wang W. L. Gladfelter Y. H. Shin 《Journal of Materials Science: Materials in Electronics》1998,9(6):465-471
RuO2/Ru conducting films were deposited on low stress Si3N4/Si substrates by reactive r.f. sputtering deposition at a substrate temperature of 400°C to introduce a new bottom electrode for microelectromechanical system devices based on a Pb(Zr1-xTix)O3 film and a surface micromachining technique with high temperature processes. X-ray diffraction and scanning electron microscopy measurements after heat treatment at 700°C were conducted to investigate structural stability of the RuO2/Ru films, which showed no silicide and silicon oxide formations by the heat treatment. Interfacial structures of the film with the heat treatment were similar to those of the as-deposited films. The surface of the film with the heat treatment consisted of larger grains than those of the as-deposited film. Rutherford backscattering spectrometry and Auger electron spectroscopy showed no interfacial reactions between the RuO2/Ru and the Si3N4. In order to investigate the feasibility of the RuO2/Ru as a bottom electrode, Pb(Zr0.53Ti0.47)O3 films were deposited by metalorganic decomposition. After deposition of a Pb(Zr0.53Ti0.47)O3 film at 700°C for 30 min, the interface structure between the RuO2/Ru and the Pb(Zr0.53Ti0.47)O3 film showed no interface reactions. The electrical properties of the PZT film on the RuO2/Ru were not changed before and after an HF etching to make an air gap, even though the piezoelectric coefficients on the RuO2/Ru were lower than on the Pt/Ti. Therefore, the RuO2/Ru conducting film could be used for a bottom electrode on the Si3N4/Si for a microelectromechanical system device based on a Pb(Zr1-xTix)O3 film and a surface micromachining technique with high temperature processes. 相似文献
10.
Heat shock (HS)/stress proteins (HSP) provide protection from a variety of stresses other than HS, including oxidative stress and mitochondria have been implicated as the target of HS-related protection in stressed cultured cells. Here we investigated whether mitochondria also are targets for the HS-mediated protection in vivo. Sprague Dawley rats were exposed, or not, to HS (41 degrees C, 15 min). After a 21 h recovery period, hearts were excised and perfused with or without H2O2 (0.15 mM). Myocardial mitochondria were then isolated, and their oxygen consumption was analyzed. HS prevented H2O2-induced alterations in state 3 respiration while increasing the expression of Hsp70 and heme oxygenase (HO). Thus, in vivo HS protects rat myocardial mitochondrial respiration against the deleterious effects of oxidative injury, a protection relating to Hsp70 and/or HO and targeting state 3 respiration. 相似文献