Analytical solution of micro-/nanoscale convective liquid flows in tubes and slits

Analytical solutions examining heat transport in micro-/nanoscale liquid flows were developed. Using the energy equation coupled with fully developed velocity, we solved developing temperature profiles with axial conduction and viscous dissipation terms. A comprehensive literature review provided the published range of velocity slip and temperature jump conditions. While molecular simulations and experiments present constant slip and jump values for a specific liquid/surface couple independent of confinement size, non-dimensional forms of these boundary conditions were found appropriate to calculate non-equilibrium as a function of flow height. Although slip and jump conditions are specific for each liquid/surface couple and hard to obtain, we proposed modeling of the slip and jump as a function of the surface wetting, in order to create a general, easy to measure methodology. We further developed possible correlations to calculate jump using the slip value of the corresponding surface and tested in the results. Fully developed Nu showed strong dependence on slip and jump. Heat transfer stopped when slip and jump coefficients became higher than a certain value. Strong variation of Nu in the thermal development length was observed for low slip and jump cases, while an almost constant Nu in the flow direction was found for high slip and jump coefficients. Variation of temperature profiles was found to dominate the heat transfer through the constant temperature surface while surface and liquid temperatures became equal at heat transfer lengths comparable with confinement sizes for no-dissipation cases. In case of non-negligible heat dissipation, viscous heating dominated the Nu value by enhancing the heating while decreasing the heat removal in cooling cases. Implementation of proposed procedure on a micro-channel convection problem from a micro-fluidics application showed the dominant effect of the model defining the slip and jump relationship. Direct use of kinetic gas theory resulted in an increase of Nu by an increase in non-equilibrium, while models developed from published liquid slip and jump values produced an opposite behavior.     

Improving the Sensitivity of Superconductor-Based DC Magnetometer

In this study we report on some critical factors affecting the sensitivity of a magnetic field sensor whose working principle is based on a linear DC field dependence of the second harmonic of the AC response in polycrystalline type-II superconductors. DC-fields down to 2?nT in magnitude could be detected by finding optimal conditions. The optimal sensor design was determined by studying superconductor cores having different geometries and coil configurations. The optimal AC-field frequency, which is required for excitation of the specimen, was found to be 50?kHz. The second harmonic signal changes quite linearly with the DC-field up to 0.1?Oe.     

The effects of nutritional habits on leucite-based ceramic repaired with nanohybrid composites

The purpose of the present in vitro study was to evaluate the effects of nutritional habits (various liquids) on the color change and early repair bond strength of a leucite-based ceramic repaired with different contents of nanohybrid composite resins currently used by the clinicians. Ninety-six IPS-Empress CAD ceramic samples were obtained with low-speed diamond saw. For all samples same repair method was performed. Samples were divided into groups according to four nanohybrid composite resins used as a repair material: Tetric-N-Ceram Bulk Fill, Filtek Z550, Clearfil-Majesty Esthetic, Bisco-Aelite Aesthetic Enamel (n?=?24). Composite resins were applied on ceramic surface and polymerized (40?sec). After waiting for 24?h, samples were divided into three subgroups according to liquid types: pomegranate-flavored mineral water, salad dressing, and distilled water (n?=?8). Before and after immersion the samples in the various liquids, color measurements were calculated (24?h). Then, shear bond strength was tested with an universal testing machine.For the statistical analyses two-way ANOVA, Tukey HSD, Spearman's correlation tests were used at a significance of p?≤?0.05. Nanohybrid composites, liquids (p?≤?0.001); correlation between nanohybrid composites and liquids (p?≤?0.006) had statistically significant impacts on the color change values. Nanohybrid composites (p?≤?0.017) and correlation between nanohybrid composites and liquids (p?≤?0.004) had statistically significant impacts on the shear bond strength values. There was not any statistically significant correlation between color change and shear bond strength (p?>?0.05). When a composite resin is selected as a repair material, nutritional habits of the patient should be taken into consideration. Although hydrophilic monomer type of a composite material is a more predominant factor associated with color change, filler weight has the same predominant effect on shear-bond strength.     

The Role of Weak Links and Zn-Doping on Magnetic Parameters of High-T c Superconductors

The second harmonic signal, which is generated by co-application of AC and DC fields to polycrystalline type-II superconductors, were analyzed in terms of the weak links and the critical current density. With this aim the YBa₂Cu_3?x Zn _x O_7?y (x=0, 0.01, 0.02, 0.03, 0.05, and 0.1) samples were synthesized in order to adjust intergranular couplings and thus the strength of weak links. The mechanical and magnetic measurements are in good agreement on that Zn doping reduces strength of the links between grains; however, contrary to the common expectations, it has no direct contribution to the 2nd harmonic signal strength.     

Synthesis of biodegradable polyurethanes chain‐extended with (2S)‐bis(2‐hydroxypropyl) 2‐aminopentane dioate

Polyurethanes (PUs) are the most widely used polymers because of their biocompatibility, tunable mechanical properties, and chemical versatility. In this study, a two‐step condensation polymerization of polycaprolactone diol and hexamethylene diisocyanate was carried out, and a glutamic acid ester derivative, (2S)‐bis(2‐hydroxypropyl) 2‐aminopentane dioate (HPAP), was used as a new chain extender to accelerate the biodegradation properties of PU. HPAP was synthesized by the Fischer esterification of l ‐glutamic acid. The chemical structure of HPAP was confirmed by high‐resolution mass spectroscopy and m/z (EI) was found to be 264.1447 [calculated value = 264.1443 for C₁₁H₂₁NO₆ (M⁺)]. The Berry plot of static light‐scattering measurements showed that PU–HPAP had a weight‐average molecular weight and radius of gyration of 33,100 g/mol and 1420 nm, respectively. The presence of HPAP in the PU structure facilitated hydrogen bonding between the polymer chains and increased the glass‐transition temperature from ?56 °C (PU) to ?50 °C (PU–HPAP). PU–HPAP showed the highest hydrophilicity and surface free energy among all of samples, and this accelerated the in vitro biodegradation period via surface erosion. In addition, PU–HPAP did not show any cytotoxic effects on the L929 cells. A new biodegradable and biocompatible PU–HPAP was obtained as candidate for tissue engineering applications. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45764.     

Measuring DC Fields as Low as 0.5 nT by Using Bi-2223 Polycrystalline Superconductors

In this study a novel type of magnetometer capable of direct measurement of DC fields as low as 0.5 nT was described. The second harmonic voltage generated by polycrystalline superconductors inserted in AC and DC fields was used as sensor signal. The experiments have shown that a 0.5 nT DC field can be detectable by using Bi-2223 superconductors as the core material. The Bi-2223 reveals better sensitivity compared to the other high-T _c cuprates. Besides, the sensor works in a wide dynamical range (10⁵ orders in magnitude), which increases its potential application areas.