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1.
MASARU MIYAYAMA SHINICHI KATSUTA YOSHIHIRO SUENAGA HIROAKI YANAGIDA 《Journal of the American Ceramic Society》1983,66(8):585-588
Electrical conduction in tetragonal β-Bi2 O3 doped with Sb2 O3 was investigated by measuring electrical conductivity, ionic transference number, and Seebeck coefficient. The β-Bi2 O3 doped with 1 to 10 mol% Sb2 O3 was stable up to 600°C and showed an oxygen ionic and electronic mixed conduction, where the electron conduction was predominant at low oxygen pressures. The oxygen-ion conductivity showed a maximum at 4 mol% Sb2 O3 , whereas the activation energy for the ionic conduction remained unchanged for 4 to 10 mol% Sb2 O3 -doped specimens. These results were interpreted in terms of the oxygen vacancy concentration and the distortion of the tetragonal structure. The electron conductivity and its oxygen pressure dependence decreased with increasing Sb2 O3 content. The fact that Sb5+ is partially reduced by excess electrons in heavily doped β specimens at low oxygen pressures is explained. 相似文献
2.
KUNIHITO KOUMOTO KEIKO YAMAYOSHI HIROAKI YANAGIDA 《Journal of the American Ceramic Society》1983,66(1):42-45
Electrical conductivity and thermoelectric power were measured on Co1-χ Mgχ O (0.16χ 0.87) at 900° to 1200°C. Electrical conductivity σ decreased and the activation energy increased with increasing MgO content. Seebeck coefficient α appeared to be positive for all χ. The difference in temperature dependence of σ and α was 0.2 to 0.5 eV and the hole mobility decreased with increasing MgO content. The results were interpreted as showing that electron holes were localized to cation clusters and their thermally activated hopping conduction was operative in the solid solution. The dominant lattice defect changed from singly to doubly ionized cobalt vacancy with increasing MgO content. 相似文献
3.
Gas Sensing Characteristics of Porous ZnO and Pt/ZnO Ceramics 总被引:2,自引:0,他引:2
SHINICHIRO SAITO MASARU MIYAYAMA KUNIHITO KOUMOTO HIROAKI YANAGIDA 《Journal of the American Ceramic Society》1985,68(1):40-43
Changes in resistivity and chemical changes in reducing gases were measured for porous zinc oxide ceramics with and without a platinum catalyst at 300° and 400°C to examine the gas sensing mechanism and the effect of platinum additions. Reducing gases were oxidized to CO2 and Hz2 on the sensor surfaces. Platinum addition promoted the oxidation of reducing gases but did not lead to an increase in the resistivity change at 400°C. The reaction sequences for the gas sensing process are proposed, taking into account partially oxidized intermediates of hydrocarbons and oxidation on platinum without an electron transfer process. 相似文献
4.
The Influence Analysis that a Phase Characteristic of the High‐Level Earthquake Gives to Vibration Response Characteristic of the 550‐kV Disconnectors 下载免费PDF全文
KIYOSHI NAGATA TOMOYUKI OHYAMA HIROAKI SATO TOMOAKI ITO ATSUSHI ETO TAKAYUKI KOBAYASHI 《Electrical Engineering in Japan》2016,196(4):32-39
We developed the 550‐kV disconnectors that strengthened earthquake proofing by the addition of the damper unit and weight reduction of conductive part based on the damage of the 550‐kV disconnectors by the Great East Japan earthquake (March 11, 2011) and inspected the earthquake proofing performance by shake table test. In shake table test, we performed the test by the artificial seismic wave that varied in phase characteristic in addition to the test by resonance method. And, in a high‐level earthquake area, we analyzed it about the influence that a phase characteristic of the artificial seismic wave gave to stress to occur in disconnectors. As a result, it is thought that the stress to occur in disconnectors is decided by a primary natural frequency basically because a bending strain to occur to the disconnectors in the time when the resonance frequency ingredient becomes the big acceleration response value grows big. But, on a particular phase condition, it was confirmed that the bending strain to occur in disconnectors might grow big conspicuously. As for this, the possibility is thought about by influence of higher natural frequency doing superposition. 相似文献
5.
DAISUKE HIRAMATSU KAZUMA TSUJIKAWA TAKASHI UEDA MASAFUMI FUJITA HIROAKI ISHIZUKA MASASHI OKUBO HIDEYUKI HACHIYA JUNJI MORI DAI NOZAKI DAISUKE IWASHITA TADASHI TOKUMASU 《Electrical Engineering in Japan》2017,198(2):39-49
Fractional‐slot windings are widely used in rotating machines in order to improve the output voltage waveform, increase the design flexibility, and gain many other advantages. However, fractional‐slot windings are known to produce different harmonic components such as an even order and/or fractional number of space flux harmonics compared to integral‐slot windings. These harmonics may increase stray losses and cause stator core vibration. This paper describes an analysis of space flux harmonics and proposes new winding methods such as “novel interspersed windings” to reduce these harmonic components. The proposed winding methods were verified by numerical analysis and model tests. 相似文献
6.
YUYING WU HIROAKI IKEDA HIROFUMI YOSHIDA SHIGENOBU SHINOHARA 《International Journal of Communication Systems》1996,9(1):5-11
This paper describes two types of bidirectional addressed audio signal transmission systems where the square-wave frequency modulation (SWFM) and intensity modulation (IM) are used to obtain the optical SWFM signals generated from LEDs at 850 nm. The first one is an addressed audio signal transmission network of tree structure. The sender and auxiliary receiver in the centre are connected to four terminals, each consisting of a receiver and an auxiliary sender, through pairs of optical fibres and an optical splitter used as an optical signal distributor. The second one is a new type of full-duplex one-to-one communication system. The sender and auxiliary receiver in one terminal are connected to the receiver and auxiliary sender in the other terminal through an optical fibre and a pair of directional couplers. Although LEDs in the second system deliver optical SWFM signals at the same wavelength of 850 nm at the same time, the communications are satisfactory because there is no interference from one LED to the other. In both the first and second experimental systems, the audio signal, address, and SWFM carrier occupy 10 Hz to 20 kHz, 65 kHz to 710 kHz, and 6 MHz, respectively. The SNR and distortion were 62 dB and 0.4 per cent, respectively. 相似文献
7.
The dependence of grain-boundary resistivity and resistance per square centimeter of grain-boundary surface on grain-boundary density (D) in yttria-stabilized zirconia was investigated using reported data. The grain-boundary resistivity increased with increasing D in the high-D region but was independent of D in the low-D region. These results were interpreted in terms of intrinsic effects such as lattice irregularity and extrinsic effects such as impurity segregation. 相似文献
8.
Electrical conductivity and thermoelectric power measurements on pure and Li-substituted Co3 O4 were performed at 200° to 900°C. Impurity-induced p-type semiconduction was observed at low temperatures and intrinsic behavior at high temperatures. A hopping scheme for electron hole conduction was confirmed, and site exchange of cations in the spinel structure was proposed to explain the electrical conduction at high temperatures. 相似文献
9.
Mechanism and Kinetics for the Formation of Uranium Mononitride by the Reaction of Uranium Dioxide with Carbon and Nitrogen 总被引:1,自引:0,他引:1
The mechanism and kinetics of UN formation by reaction of a pellet of mixed UO2 and C with N2 were studied for temperatures of 1420° to 1750°C. The reaction followed the first-order rate equation; the activation energy was 83 kcal/mol. Only UN1−x C x was produced. The lattice parameter variation of UN1−x C x had a minimum and a maximum during reaction; at the maximum, UN1−x C x + C + N2 were in equilibrium. The overall reaction was divided into four stages: (1) formation of UN1−x C x from UO2 , (2) decarburization of UN1−x C x , (3) formation of UN1−x C x with the equilibrium composition, and (4) pure UN formation. The lowest reaction rate was in stage (4). 相似文献
10.
Reaction of Strontium Carbonate with Anatase and Rutile 总被引:2,自引:0,他引:2
The kinetics of the solid-state reaction of strontium carbonate with anatase and rutile in air and carbon dioxide were studied by use of a thermobalance. The product was single-phase SrTiO3 in all cases. The relation between fraction reacted and time was fitted to the Jander equation and to the Carter equation for both anatase and rutile. For anatase the rate constant in carbon dioxide did not differ from that in air. The reaction rates for rutile in air and in carbon dioxide were ⅓ and ⅛ that for anatase, respectively. The In k vs 1/ T relation for anatase gave two straight lines with different slopes having a break point at ∼820°C in both air and carbon dioxide. The Jander activation energies for anatase in the higher and lower temperature regions were ∼340 and ∼290 kj · mol−1 , respectively, and those for rutile in air and carbon dioxide were 340 and 390 KJ · mol−1 , respectively. 相似文献