Impact of initial moisture content levels,freezing rate and instant controlled pressure drop treatment (DIC) on dehydrofreezing process and quality attributes of quince fruits

Dehydrofreezing process involves water partial removal before freezing. This treatment has been proposed in order to reduce the negative impacts of conventional or even accelerated freezing, especially on the textural quality of high water content fruits and vegetables. Indeed, in such cases, freezing and thawing processes result in severe damage of the integrity of product’s cell structure due to the formation of ice crystals. For this purpose, quince fruits (7?g H₂O/g db) were subjected to convective air drying of 40?°C and 3m/s to reach different water content levels of 2, 1, and 0.3?g H₂O/g db. Freezing profiles obtained at various freezing rates (V₁, V₂, and V₃) for different water contents allowed the main freezing characteristics such as the Initial Freezing Temperature (IFT), the Practical Freezing time (PFt), and the Specific Freezing time (SFt) to be assessed. The impact of freezing rate was important on PFt and SFt, and more pronounced for high water contents (W between 7 and 2?g H₂O/g db (dry basis)). Furthermore, IFT decreased sharply when initial sample water content decreased. Indeed, it started at ?0.8?°C for W?=?7g H₂O/g db, while it reached a value of ?8.2?°C for samples of W?=?1g H₂O/g db. Since convective air drying normally triggers shrinkage which causes a detrimental deformation of fruit structures, instant controlled pressure drop (DIC) treatment was used to improve the texture and enhance the whole dehydrofreezing performance and the final frozen-thawed product quality. Moreover, DIC implied a slight increase of PFt compared to untreated ones. On the other hand, quality attributes were estimated through the assessment of thawed water exudate (TWE g H₂O/100?g db), color and texture (maximum puncture force as index of firmness): freezing rate and water content had great impacts on TWE. Hence, the lower the water content, the weaker the TWE. Furthermore, the TWE of the pre-dried quince (0.3?g H₂O/g db) had higher value for DIC-textured samples than for the un-treated ones. Indeed, DIC-texturing leads to a well-controlled structure expansion of the cell wall. These textural changes resulted in more lixiviation of residual water. Consequently, water becomes more available, hence more releasable after thawing. Finally, the partial removal of water by air drying before freezing remarkably reduced the negative impact of freezing/thawing processes on final quince color. Decisively, the firmness of quince fruit increased with the decrease of water content level.

Abbreviations: DMC: Dry Matter Concentration (%); DIC: Instant controlled pressure drop; W: Water content dry basis (g H₂O/g db); IFT: Initial Freezing Temperature (°C); PFt: Practical Freezing time (min); SFt: Specific Freezing time (min); TWE: Thawed Water Exudate (g H₂O/100?g db); L, a, and b: Color coordinates; (L): The degrees of lightness; (a) and (–a): The redness (a) or greenness (?a), respectively; (b) and (?b): The yellowness (b) or blueness (?b), respectively; ΔE*_ab: Total color difference; L₀, a₀, and b₀: Color coordinates of fresh or dried quince samples; SD: Standard Deviation; ANOVA: Analysis of variances; LSD: Least Significant Differences; cp: Specific Heat of the product depending on composition (dry material and water content)(KJ/kg K); cp_d: Specific Heat of the dry material (KJ/kg K); cp_W: Specific Heat of water (KJ/kg K); V₁: Freezing rate without insulation; V₂: Freezing rate with a food stretch film insulation with thickness e2?=?3?mm and thermal conductivity λ₂?=?0.17 W/m K; V₃: Freezing rate with a versatile flexible insulation (Armacell) with thickness e3?=?13mm and weak thermal conductivity λ₃?=?0.036 W/m K; v_d: Volume of dry material of quince sample (mm³); v_H2O: Volume of quince sample water (mm³); v_t: Total volume of quince sample (mm³); e₀: Quince sample thickness (mm); e₂: Insulation thickness in the case V2; = 3?mm; ; e₃: Insulation thickness in the case V3; = 13?mm; ; λ₀: Quince sample conductivity (W/m K); λ₂: Insulation conductivity in the case V2;?=?0.17 W/m K; ; λ₃: Insulation conductivity in the case V3;?=?0.036 W/m K; λ_d: Conductivity of quince sample dry material (W/m K); λ_H2O: Conductivity of water (W/m K); λ_equiv: Equivalent conductivity of quince sample versus water content (W/m K); m_i and m_f: Weights of the frozen and thawed samples, respectively     

Production and set-up control of a failure-prone manufacturing system

The present paper considers a stochastic optimal control problem for a one-machine two-parts manufacturing system, subject to random breakdowns and repairs. The machine under consideration is not completely flexible and hence requires set-up time and cost in order to switch the production from a part type to another. The objective is to find the production plan and sequence of set-ups that minimize the cost function that penalizes inventory/backlog and set-up costs. A continuous dynamic programming formulation of the problem is presented. A numerical scheme is then adopted to solve the obtained optimality conditions equations. The optimal set-up policy. is shown numerically, to be described by a modified hedging corridor strategy. A complete heuristic policy, based on the determination of the boundaries of the corridors that describe the optimal policy in positive and negative areas of the state variables, is developed. The usefulness of such a policy is iJlustrated through experimentation and sensitivity analysis. Extensions to more complex systems are also discussed.     

Synthesis,Thermal Properties and Electrical Conductivity of Na-Sialate Geopolymer

This work aims to study the thermal behavior of basic-geopolymers derived from metakaolin (clay). The geopolymers were characterized by different techniques: thermal analysis (DTA, TGA), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and impedance spectroscopy. Some physicochemical properties of the products were also determined: the phases obtained after geopolymer heat treatment and their electrical properties. The results obtained after drying and heat treatment showed that the products kept their initial shapes, but revealed variable colors depending on the temperatures at which they were treated. The products obtained are amorphous between 300 up to 600 °C with peaks relating to the presence of nanocrystallites of muscovites and zeolite, thus at 900 °C it is quite amorphous but only contains nanocrystallites of muscovites. From the temperature of 950 °C, we notice that the geopolymer has been transformed into a crystalline compound predominated by the Nepheline (NaAlSiO₄) with the presence of a crystalline phase by minor peaks of Muscovite, this crystalline character has been increased at 1100 °C to obtain a whole phase crystalline of a Nepheline. The treatment of this geopolymer for one hour at 1200 °C shows an amorphous phase again corresponding to corundum (α-Al₂O₃). This indicates that the dissolution of the grains by the liquid phase induces the conversion of the material structure from sialate [–Si–O–Al–O] to sialate siloxo [–Si–O–Al–O–Si–O–] and the formation of a new crystalline phase (α-Al₂O₃). This development of sialate to sialate-siloxo was confirmed by IR spectroscopy. As mentioned above, from 300 to 900 °C, Na-sialate geopolymer exhibits the same disorder structure of nepheline. The crystal structure of nepheline is characterized by layers of six-membered tetrahedral rings of exclusively oval conformation. The rings are built by Regularly alternating tetrahedral AlO₄ and SiO₄. Stacking the layer’s parallel to the c axis gives a three-dimensional network containing channels occupied by Na cations. This topology favors easy movement of Na⁺ ions throughout the structure. For this reason, ionic migration in nepheline is widely reported. The refinement of Na-Sialate geopolymer at room temperature gives bulk high ionic conductivity of about 5 × 10^?5 S cm^?1 and this is due to the probable joint contribution of H⁺ and Na⁺ ions. Above 200 °C, Na⁺ seems to remain the only charge carrier with a low activation energy of about Ea?=?0.26 eV. At higher temperatures, the characteristic frequencies become so close that it is impossible to distinguish the contributions. A total resistance comprising both grain and grain boundaries contribution is then determined.

     

Radiation pyrometry on semitransparent sheets. I: Gray media

Radiation pyrometry is often used in the measurement of temperature during polymer processing operations such as film blowing. Since polymers are semitransparent in the infrared, the temperature measured by the pyrometer will correspond to some average of the internal temperature distribution. In the present study, an expression is derived for this average when a sheet with a thermal gradient across its thickness is considered. This expression is used to study the effect of the absorption characteristics of the sheet on this average when the material is a gray medium.     

Disruption and phenotypic analysis of seven ORFs from the left arm of chromosome XV of Saccharomyces cerevisiae

We have disrupted seven open reading frames (ORFs) located in the left arm of chromosome XV of the yeast Saccharomyces cerevisiae. These ORFs, previously discovered by our laboratory during the programme of systematic sequencing of the yeast genome, are YOL152w, YOL151w, YOL149w, YOL130w, YOL128c, YOL125w and YOL124c. In most cases, the short flanking homology (SFH) replacement technique has been used. The mutants were analysed for different phenotypic tests. Disruption of YOL130w (also known as ALR1) produced a lethal phenotype, despite the presence of a highly similar gene in the yeast genome (ALR2/YFL050C). Disruption of YOL149w (also known as DCP1, and encoding an mRNA decapping enzyme) results in lethality in the FY1679 background, although it allows slow growth in the CEN.PK141 background. Disruption of the remaining ORFs did not result in readily detectable phenotypic changes.     

A new DC model of HBT's including self-heating effect suitable forcircuit simulators

This paper presents a new empirical DC model which includes self-heating effects. The expression of the collector current does not explicitly incorporate the junction temperature of the device to aid convergence process and to simplify the equations involved. A comparison of simulated and experimental DC-IV characteristics over the ohmic and active regions demonstrates the accuracy of the model. This model is suitable for optimization purposes and has been implemented in nonlinear circuit simulators, HSPICE and HP-MDS     

Two La0.5Ag0.1Ca0.4MnO3 Manganite Nanoparticles Synthesized via Sol–Gel and Solid-State Methods–Structural,Magnetic, and Magnetocaloric Properties

Journal of Superconductivity and Novel Magnetism - La0.5Ag0.1Ca0.4MnO3 manganite nanoparticles are synthesized via two different ways, namely, a solid-state reaction (S1) and the sol–gel...     

Silica-filled poly(HEMA) from hema/grafted SiO2 nanoparticles: Polymerization kinetics and rheological changes

The chemio-rheological behavior during the radical polymerization of the HEMA/grafted silica nanoparticles was found to be very dependent on the weight fraction of the silica particles. In the case of the neat HEMA reactive system, the macrogelation occurs at the same time as the Trommosdorf effect. The reactive groups on the silica nanoparticles, which have a lower reactivity compared to that of the HEMA monomer, slow down the mean radical polymerization rate of the filled reactive system. The reactions between the grafted groups of the neighboring silica particles lead to the percolation, i.e., macrogelation, of the reactive system at low conversion degree, even if the reactive system is kinetically at the stationary state. The reactive medium of the HEMA/grafted silica nanoparticles systems could be divided to two parts: the percolating nanoparticles part for which the polymerization rate is very slow, and the bulk HEMA medium in which the radical polymerization rate is the same order of magnitude than for the neat HEMA. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 2701–2713, 1999     

An Environmental Hedging Point Policy to control production rate and emissions in unreliable manufacturing systems

This paper proposes a new Hedging Point Policy (HPP) which integrates environmental concerns into the optimal control of unreliable manufacturing systems. The considered system is composed of a production facility subjects to random failures and producing a product family intended for a given market with stable demand. The manufacturing facility’s operations cause harmful emissions to the environment, and may incur sanctions in the form of an environmental tax imposed by the relevant authorities. Given the significant compromise that must take place between inventory, backlog and taxes costs, the main objective of this paper is to propose a feedback adaptive control policy which provides a better control of the production rate and the emissions generated. Under the HPP category, a new structure called the Environmental Hedging Point Policy (EHPP) is proposed. To illustrate the effectiveness of the proposal, an experimental approach based on simulation modelling, variance analysis and response surface methodology (RSM) is applied. The results show a significant gain in terms of incurred costs compared to those incurred when the system is governed by a classical HPP. An improved version of EHPP is also proposed for systems with high emission rates. Several sensitivity analyses are conducted to illustrate the robustness and effectiveness of the proposed policies.