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1.
In this contribution we consider the absolute stability problem. We derive necessary and sufficient conditions for the existence of periodic motion using an operator approach. The results yield an efficient algorithm to approximate the maximum sector bounds for absolute stability numerically. 相似文献
2.
This study addresses the likelihood of false negative urine pregnancy test results, due to physiological urine dilution as described in some anecdotal reports. In this prospective study 320 pregnancy tests were performed on urine samples of varying concentrations obtained from 40 women, with suspected complications of early pregnancy, who had presented for ultrasound scans. Four different pregnancy tests were used and serum betahCG levels were measured quantitatively. Despite a mean fivefold increase in urine dilution, the pregnancy tests with low betahCG detection limits maintained maximal sensitivity. The detection of betahCG in dilute urine was adversely affected by using pregnancy tests with higher betahCG detection limits and these tests should be used with caution when assessing gynaecological emergencies. 相似文献
3.
The thermal and hydro‐thermal aging of a hot‐cured epoxy system (diglycidylether of bisphenol A (DGEBA) + dicyandiamide (DDA)) in the glassy state is revisited using DSC and IR attenuated total reflection spectroscopy. Because of the diffusion of DDA from the solid particles into the liquid DGEBA matrix, curing produces a highly crosslinked amorphous matrix that contains low crosslinked amorphous regions. After full curing, the network possesses a relatively low molecular mobility and no residual reactive groups. Thermal and hydro‐thermal loading is performed at 60°C, well below the principal glass transition temperature (Tg1 = 171°C). Both aging regimes cause significant chemical and structural changes to the glassy epoxy. It undergoes a phase separation of relatively mobile segments inside the low mobile matrix, providing a second glass transition that shifts from Tg2 = 86–114°C within 108 days of aging. This phase separation is reversible on heating into the viscoelastic state. Hydro‐thermal aging leads to a reversible and a nonreversible plasticizing effect as well. On thermal aging, no chemical changes are observed but hydro‐thermal aging causes significant chemical modifications in the epoxy system. These modifications are identified as a partial degradation of crosslinks produced by the cyano groups of the DDA and correspond to the nonreversible plasticitation. These changes in the cured epoxy should exert an influence on the mechanical properties of an adhesive bond. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006 相似文献
4.
Alkema WB Hensgens CM Snijder HJ Keizer E Dijkstra BW Janssen DB 《Protein engineering, design & selection : PEDS》2004,17(5):473-480
Penicillin acylase catalyses the condensation of Calpha-substituted phenylacetic acids with beta-lactam nucleophiles, producing semi-synthetic beta-lactam antibiotics. For efficient synthesis a low affinity for phenylacetic acid and a high affinity for Calpha-substituted phenylacetic acid derivatives is desirable. We made three active site mutants, alphaF146Y, betaF24A and alphaF146Y/betaF24A, which all had a 2- to 10-fold higher affinity for Calpha-substituted compounds than wild-type enzyme. In addition, betaF24A had a 20-fold reduced affinity for phenylacetic acid. The molecular basis of the improved properties was investigated by X-ray crystallography. These studies showed that the higher affinity of alphaF146Y for (R)-alpha-methylphenylacetic acid can be explained by van der Waals interactions between alphaY146:OH and the Calpha-substituent. The betaF24A mutation causes an opening of the phenylacetic acid binding site. Only (R)-alpha-methylphenylacetic acid, but not phenylacetic acid, induces a conformation with the ligand tightly bound, explaining the weak binding of phenylacetic acid. A comparison of the betaF24A structure with other open conformations of penicillin acylase showed that betaF24 has a fixed position, whereas alphaF146 acts as a flexible lid on the binding site and reorients its position to achieve optimal substrate binding. 相似文献
5.
Converting unconstrained video sequences into videos that loop seamlessly is an extremely challenging problem. In this work, we take the first steps towards automating this process by focusing on an important subclass of videos containing a single dominant foreground object. Our technique makes two novel contributions over previous work: first, we propose a correspondence‐based similarity metric to automatically identify a good transition point in the video where the appearance and dynamics of the foreground are most consistent. Second, we develop a technique that aligns both the foreground and background about this transition point using a combination of global camera path planning and patch‐based video morphing. We demonstrate that this allows us to create natural, compelling, loopy videos from a wide range of videos collected from the internet. 相似文献
6.
Multiple Kernel Learning (MKL) is a popular generalization of kernel methods which allows the practitioner to optimize over convex combinations of kernels. We observe that many recent MKL solutions can be cast in the framework of oracle based optimization, and show that they vary in terms of query point generation. The popularity of such methods is because the oracle can fortuitously be implemented as a support vector machine. Motivated by the success of centering approaches in interior point methods, we propose a new approach to optimize the MKL objective based on the analytic center cutting plane method (accpm). Our experimental results show that accpm outperforms state of the art in terms of rate of convergence and robustness. Further analysis sheds some light as to why MKL may not always improve classification accuracy over naive solutions. 相似文献
7.
Sina Jafarzadeh Anders Christian Wulff Kurt Engelbrecht Christian Robert Haffenden Bahl 《Advanced Engineering Materials》2023,25(11):2201790
Obtaining a highly homogeneous magnetic field is desired for field-controlled applications. For example, the resolution of magnetic analysis methods can be improved by generating a stronger and more homogeneous field over the region of interest (ROI). A set of 3D-printed passive shims is fabricated using additive manufacturing to improve the magnetic field homogeneity of a Halbach magnet assembly. The feedstock is a custom acrylonitrile butadiene styrene (ABS)-hard magnet composite filament filled with 60% wt. isotropic NdFeB. Additionally, a method for investigating the remanence is developed and validated. The result reveals a good agreement between the new method and existing measurement techniques for the remanence of permanent magnets. It is also shown that the additive manufacturing procedure has negligible effects on the magnetic properties. Performing a parametric study over a rectangular ROI, an optimized shim configuration is achieved. In the optimized and 3D-printed configuration, the average norm of the magnetic flux density, Bnorm, is increased by 13% and, more importantly, a 43% increase in the magnetic uniformity is obtained. These results highlight the great potential of freeform manufacturing, namely, additive manufacturing, to tailor the properties of magnet structures. 相似文献
8.
ABSTRACTIn this paper, a Lyapunov-based control concept is presented that combines variable structure and adaptive control. The considered system class consists of nonlinear single input systems which are affected by matched structured and unstructured uncertainties. Resorting to the certainty equivalence principle, the controller exploits advantages of both the sliding-mode and the adaptive control methodology. It is demonstrated that the gains of the discontinuous control action may be reduced remarkably when compared with pure sliding-mode-based approaches. The efficiency of the presented concept is demonstrated in detail, using results of numerical simulations. 相似文献
9.
The focus of this work is a novel application of configurational forces to tendon layout optimisation problems in prestressed concrete beams. To this end, the application of the method of the configurational forces is extended to two-dimensional plane stress analysis. The optimum tendon position is obtained by iteratively arriving at vanishing configurational forces. The performance of the optimisation algorithm is illustrated by means of numerical examples. 相似文献
10.
Harm op den Akker Valerie M. Jones Hermie J. Hermens 《User Modeling and User-Adapted Interaction》2014,24(5):351-392
Technology mediated healthcare services designed to stimulate patients’ self-efficacy are widely regarded as a promising paradigm to reduce the burden on the healthcare system. The promotion of healthy, active living is a topic of growing interest in research and business. Recent advances in wireless sensor technology and the widespread availability of smartphones have made it possible to monitor and coach users continuously during daily life activities. Physical activity monitoring systems are frequently designed for use over long periods of time placing usability, acceptance and effectiveness in terms of compliance high on the list of design priorities to achieve sustainable behavioral change. Tailoring, or the process of adjusting the system’s behavior to individuals in a specific context, is an emerging topic of interest within the field. In this article we report a survey of tailoring techniques currently employed in state of the art real time physical activity coaching systems. We present a survey of state of the art activity coaching systems as well as a conceptual framework which identifies seven important tailoring concepts that are currently in use and how they relate to each other. A detailed analysis of current use of tailoring techniques in real time physical activity coaching applications is presented. According to the literature, tailoring is currently used only sparsely in this field. We underline the need to increase adoption of tailoring methods that are based on available theories, and call for innovative evaluation methods to demonstrate the effectiveness of individual tailoring approaches. 相似文献