全文获取类型
收费全文 | 453篇 |
免费 | 36篇 |
国内免费 | 1篇 |
专业分类
电工技术 | 2篇 |
化学工业 | 131篇 |
金属工艺 | 9篇 |
机械仪表 | 11篇 |
建筑科学 | 14篇 |
矿业工程 | 1篇 |
能源动力 | 28篇 |
轻工业 | 101篇 |
水利工程 | 1篇 |
无线电 | 30篇 |
一般工业技术 | 53篇 |
冶金工业 | 10篇 |
原子能技术 | 4篇 |
自动化技术 | 95篇 |
出版年
2024年 | 5篇 |
2023年 | 8篇 |
2022年 | 11篇 |
2021年 | 24篇 |
2020年 | 21篇 |
2019年 | 24篇 |
2018年 | 31篇 |
2017年 | 25篇 |
2016年 | 17篇 |
2015年 | 14篇 |
2014年 | 11篇 |
2013年 | 40篇 |
2012年 | 40篇 |
2011年 | 38篇 |
2010年 | 31篇 |
2009年 | 38篇 |
2008年 | 25篇 |
2007年 | 24篇 |
2006年 | 22篇 |
2005年 | 9篇 |
2004年 | 11篇 |
2003年 | 3篇 |
2002年 | 2篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1995年 | 2篇 |
1992年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1985年 | 2篇 |
1984年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有490条查询结果,搜索用时 15 毫秒
1.
Uzun İlhan Orak İkram Yağmur Hatice Karaer Karakaplan Mehmet Yalman Murat 《SILICON》2021,13(12):4703-4713
Silicon - 5-(2,4-dichlorophenyl)-2-furoic acid and anthraquinone-2-carboxylic acid were reacted separately with chitin. The synthesized products were characterized by various spectroscopic methods... 相似文献
2.
3.
Ming Li Shunbo Li Jinbo Wu Weijia Wen Weihua Li Gursel Alici 《Microfluidics and nanofluidics》2012,12(5):751-760
We report a simple and cost-effective method for fabricating integrated electronic-microfluidic devices with multilayer configurations.
A CO2 laser plotter was employed to directly write patterns on a transferred polydimethylsiloxane (PDMS) layer, which served as
both a bonding and a working layer. The integration of electronics in microfluidic devices was achieved by an alignment bonding
of top and bottom electrode-patterned substrates fabricated with conventional lithography, sputtering and lift-off techniques.
Processes of the developed fabrication method were illustrated. Major issues associated with this method as PDMS surface treatment
and characterization, thickness-control of the transferred PDMS layer, and laser parameters optimization were discussed, along
with the examination and testing of bonding with two representative materials (glass and silicon). The capability of this
method was further demonstrated by fabricating a microfluidic chip with sputter-coated electrodes on the top and bottom substrates.
The device functioning as a microparticle focusing and trapping chip was experimentally verified. It is confirmed that the
proposed method has many advantages, including simple and fast fabrication process, low cost, easy integration of electronics,
strong bonding strength, chemical and biological compatibility, etc. 相似文献
4.
In the present study, the effects of charge‐transfer complex formation and intramolecular fragmentation (side‐chain lactonization) in radical copolymerization of tert‐butyl vinyl ether (t‐BVE) with anhydrides of maleic (MA) and citraconic (CA) acids and the structure–thermal behavior relationships of the resulting copolymers were examined using the 1H‐NMR, FTIR, DSC, and TGA analysis methods. It was shown that copolymerization under the chosen conditions proceeded through intramolecular fragmentation with the formation of γ‐lactone units. Side‐chain fragmentation of t‐BVE–MA and t‐BVE–CA copolymers also was confirmed by TGA and DSC analysis. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2455–2463, 2006 2006 相似文献
5.
Hatice Kaplan Can A. Lale Doan Zakir M. O. Rzaev Ayegül Hasegeli Uner Ali Güner 《应用聚合物科学杂志》2006,100(5):3425-3432
The ternary copolymerization of maleic anhydride (MA), vinyl acetate (VA), and acrylic acid (AA) [P(MA‐co‐VA‐co‐AA)], which is considered to be an acceptor–donor–acceptor system, was carried out in 1,4‐dioxane with benzoyl peroxide as an initiator at 70°C under a nitrogen atmosphere. Constants of complex formation for the monomer systems in the study were determined by UV–visible (hydrogen‐bonding complex) and 1H‐NMR (charge transfer complex) methods, respectively. The results show that polymerization of the P(MA‐co‐VA‐co‐AA) system proceeds by an alternating terpolymerization mechanism. It is shown that the synthesized copolymers have typical polyelectrolyte behavior, ability for reversible hydrolysis–anhydrization reactions, and semicrystalline structures. In these cases, including radical polymerization, and formation of semicrystalline structures, the hydrogen‐bonding effect plays a significant role. The in vitro cytotoxicities of the synthesized terpolymer and alternating copolymer were evaluated using Raji cells (human Burkitt lymphoma cell line). The antitumor activities of prepared anion‐active copolymers were studied using methyl–thiazol–tetrazolium colorimetric assay and 50% of the cytotoxic dose of each copolymer and terpolymer were calculated. Hydrolyzed P(MA‐co‐VA‐co‐AA) and P(MA‐alt‐AA) copolymers have sufficiently high antitumor activity, which depends on the amount of hydrogen‐bonding carboxylic groups and their regular distribution in the side chain of functional macromolecules. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3425–3432, 2006 相似文献
6.
Hamed Salimkhani Emre Erdem Selmiye Alkan Gursel Alp Yurum 《Journal of the American Ceramic Society》2021,104(8):4257-4271
Recently, lanthanides have been employed by researchers to examine their impact on the structure and properties of Li7La3Zr2O12 (LLZO) garnets. In this regard, we developed Europium oxide (Eu2O3) doped LLZO (Li7+δEuxLa3−δZr2−δO12−δ) solid electrolyte which demonstrates a cubic phase with the symmetry of Iad (No.230) at room temperature. In this investigation, different concentrations of Eu ranging from 0.1 to 0.6 atoms per formula unit (pfu) were doped into Li7La3Zr2O12 to evaluate the impact of Eu on the stability of the cubic phase and thereby the ionic conductivity. The results unveiled that upon doping Eu3+ ions, the Eu2+ state is also formed and is then self-doped into the structure in which Rietveld refinement coupled with XPS, EPR, and solid-state NMR suggests that Eu3+ ions most probably partially occupy Zr4+ (16a) site, the Eu2+ ions occupy La3+ (24d) site, and the Li+ ions occupy two different sites (24d and 96h). It was further found that such a site preference induces distortion at LaO8 polyhedrons opening up the neck for Li-ions diffusion, thereby enhancing the ionic conductivity. Moreover, it was revealed that Li-ions probably hop from 96h to 24d and then to 96h site to generate the Li-ion movement. Overall, by introducing Eu ions into the LLZO structure, an enhanced bulk ionic conductivity of 0.30 × 10−3 S/cm at 298 K with a minimum electronic conductivity of 2.547 × 10−9 S/cm at 298 K was achieved. 相似文献
7.
Bilal Demirel Nihat B. İnaner Derya U. Gezer Fugen Daver Ali Yaras Fatih Akkurt 《Polymer Engineering and Science》2021,61(7):2043-2054
Polyethylene terephthalate (PET)/nano-hydroxyapatite (nHAp) composite granules were obtained using twin-screw extruder. Preforms were prepared by injection molding and then PET/nHAp bottles were produced by blow molding. For PET bottles with nHAp, the migration amounts of carboxylic acid (COOH), acetaldehyde (AA), diethylene glycol (DEG), and isophthalic acid (IPA); glass transition temperature (Tg); melting temperature (Tm); and the maximum crystallization temperature (Tcry) were measured. The load-carrying capacity, burst strength, stress cracking, and regional material distribution tests were carried out on the bottles. X-ray diffraction, scanning electron microscopy, Fourier transform infrared spectroscopy, differential scanning calorimetry, and ultraviolet transmittance analyses were conducted to explain the changes in mechanical, chemical, physical properties, and light transmission of bottles. It was found out that the COOH amount increased and the AA content decreased with increasing nHAp amount. On the other hand, no change was observed in the amounts of DEG and IPA. Although the mechanical properties such as load-carrying capacity and burst strength of the bottles have improved, it has been determined that the standard environmental stress crack resistance test procedure cannot be applied to such a composite. Experimental findings indicate that nHAp disrupts the chemical structure of PET and it isolates harmful chemicals such as AA by forming intermolecular bonds. Moreover, with the addition of up to 0.8% nHAp, PET bottles block the light transmission approximately 80% within 400–700 nm wave length zone. The study demonstrates that the PET/nHAp composite bottles can be used in the food industry, particularly in the packaging of milk and milk products which are vulnerable to light exposure. 相似文献
8.
Ming Li Shunbo Li Wenbin Cao Weihua Li Weijia Wen Gursel Alici 《Microfluidics and nanofluidics》2013,14(3-4):527-539
This article presents a dielectrophoresis (DEP)-based microfluidic device with the three-dimensional (3D) microelectrode configuration for concentrating and separating particles in a continuous throughflow. The 3D electrode structure, where microelectrode array are patterned on both the top and bottom surfaces of the microchannel, is composed of three units: focusing, aligning and trapping. As particles flowing through the microfluidic channel, they are firstly focused and aligned by the funnel-shaped and parallel electrode array, respectively, before being captured at the trapping unit due to negative DEP force. For a mixture of two particle populations of different sizes or dielectric properties, with a careful selection of suspending medium and applied field, the population exhibits stronger negative DEP manipulated by the microelectrode array and, therefore, separated from the other population which is easily carried away toward the outlet due to hydrodynamic force. The functionality of the proposed microdevice was verified by concentrating different-sized polystyrene (PS) microparticles and yeast cells dynamically flowing in the microchannel. Moreover, separation based on size and dielectric properties was achieved by sorting PS microparticles, and isolating 5 μm PS particles from yeast cells, respectively. The performance of the proposed micro-concentrator and separator was also studied, including the threshold voltage at which particles begin to be trapped, variation of cell-trapping efficiency with respect to the applied voltage and flow rate, and the efficiency of separation experiments. The proposed microdevice has various advantages, including multi-functionality, improved manipulation efficiency and throughput, easy fabrication and operation, etc., which shows a great potential for biological, chemical and medical applications. 相似文献
9.
Elif Derya Übeyli 《Expert Systems》2008,25(5):431-443
Abstract: Features are used to represent patterns with minimal loss of important information. The feature vector, which is composed of the set of all features used to describe a pattern, is a reduced‐dimensional representation of that pattern. Medical diagnostic accuracies can be improved when the pattern is simplified through representation by important features. By identifying a set of salient features, the noise in a classification model can be reduced, resulting in more accurate classification. In this study, a signal‐to‐noise ratio saliency measure was employed to determine the saliency of input features of recurrent neural networks (RNNs) used in classification of ophthalmic arterial Doppler signals. Eigenvector methods were used to extract features representing the ophthalmic arterial Doppler signals. The RNNs used in the ophthalmic arterial Doppler signal classification were trained for the signal‐to‐noise ratio screening method. The application results of the signal‐to‐noise ratio screening method to the ophthalmic arterial Doppler signals demonstrated that classification accuracies of RNNs with salient input features are higher than those of RNNs with salient and non‐salient input features. 相似文献
10.
Elif Derya Übeyli 《Expert Systems》2008,25(4):367-379
Abstract: In this study, Doppler signals recorded from the internal carotid artery (ICA) of 97 subjects were processed by personal computer using classical and model-based methods. Fast Fourier transform (classical method) and autoregressive (model-based method) methods were selected for processing the ICA Doppler signals. The parameters in the autoregressive method were found by using maximum likelihood estimation. The Doppler power spectra of the ICA Doppler signals were obtained by using these spectral analysis techniques. The variations in the shape of the Doppler spectra as a function of time were presented in the form of sonograms in order to obtain medical information. These Doppler spectra and sonograms were then used to compare the applied methods in terms of their frequency resolution and the effects in determination of stenosis and occlusion in the ICA. Reliable information on haemodynamic alterations in the ICA can be obtained by evaluation of these sonograms. 相似文献