Hydrophobic Cross-Linked Poly(dimethylsiloxane)-Based Sorbents for Oil Spill Applications

With the increase of industrialization and urbanization, humankind faces massive oil-based pollution due to tanker accidents, human error, and natural disasters. For this, hydrophobic sorbents are fabricated and their applications for the removal of oil from polluted water sources are investigated. These hydrophobic sorbents are prepared by the condensation reaction of poly(dimethylsiloxane) and tris[3-(trimethoxysilyl)propyl]isocyanurate cross-linker via bulk polymerization. The obtained sorbents exhibit high oil sorption capacity, fast absorption–desorption kinetics, and great reusability. Moreover, they can selectively absorb oil from the water surface, thus making them practical for water clean-up applications.     

The Evolving Role of Fetuin-A in Nonalcoholic Fatty Liver Disease: An Overview from Liver to the Heart

Nonalcoholic fatty liver disease (NAFLD) is strongly associated to the features of metabolic syndrome which can progress to cirrhosis, liver failure and hepatocellular carcinoma. However, the most common cause of mortality in people with NAFLD is not liver-related but stems from atherosclerotic cardiovascular disease (CVD). The prevalence of NAFLD is on the rise, mainly as a consequence of its close association with two major worldwide epidemics, obesity and type 2 diabetes (T2D). The exact pathogenesis of NAFLD and especially the mechanisms leading to disease progression and CVD have not been completely elucidated. Human fetuin-A (alpha-2-Heremans Schmid glycoprotein), a glycoprotein produced by the liver and abundantly secreted into the circulation appears to play a role in insulin resistance, metabolic syndrome and inflammation. This review discusses the links between NAFLD and CVD by specifically focusing on fetuin-A’s function in the pathogenesis of NAFLD and atherosclerotic CVD.     

Using an artificial bee colony algorithm for the optimal placement of viscous dampers in planar building frames

In this study, an Artificial Bee Colony Algorithm (ABCA) is used to obtain the optimal size and location of viscous dampers in planar buildings to reduce the damage to the frame systems during an earthquake. The transfer function amplitude of the top displacement and the elastic base shear force evaluated at the first natural circular frequency of structures are chosen as objective functions. The damper coefficients of the added viscous dampers are taken into consideration as design variables in a planar building frame. Transfer function amplitude of the top displacement and the amplitude of the elastic base shear force at the fundamental natural frequency are minimized under an active constraint on sum of the damper coefficients of the added dampers. According to two specified objective functions, an optimization algorithm based on the ABCA is proposed. The proposed method is verified by a gradient-based algorithm; steepest direction search algorithm (SDSA). The proposed ABCA and the SDSA are applied to find the optimal damper distribution for a nine-storey planar building then the optimal damper allocation obtained from the ABCA is investigated to rehabilitate models of irregular planar buildings. The validity of the proposed method was demonstrated through a time history analysis of the optimal damper designs, which were determined based on the frequency domain using the ABCA. The numerical results of the proposed optimal damper design method show that the use of the ABCA can be a practical and powerful tool to determine the optimal damper allocation in planar building structures.     

A color-based face tracking algorithm for enhancing interaction with mobile devices

A color-based face tracking algorithm is proposed to be used as a human-computer interaction tool on mobile devices. The solution provides a natural means of interaction enabling a motion parallax effect in applications. The algorithm considers the characteristics of mobile use-constrained computational resources and varying environmental conditions. The solution is based on color comparisons and works on images gathered from the front camera of a device. In addition to color comparisons, the coherency of the facial pixels is considered in the algorithm. Several applications are also demonstrated in this work, which use the face position to determine the viewpoint in a virtual scene, or for browsing large images. The accuracy of the system is tested under different environmental conditions such as lighting and background, and the performance of the system is measured in different types of mobile devices. According to these measurements the system allows for accurate (7% RMS error) face tracking in real time (20–100 fps).     

Review of the natural conditions and anthropogenic threats to the Ethiopian Rift Valley rivers and lakes

This review article considers the lakes found within the Ethiopian Rift Valley system and the rivers draining from the highlands towards them. The Ethiopian Rift Valley system extends in a north‐east–south‐west direction, bisecting the Ethiopian highlands. They differ in sizes and hydrological and hydrogeological settings. The lakes support a variety of flora and fauna, mainly fishes, reptiles, birds and mammals. The lakes and their feeder rivers, however, are currently being subjected to more human use pressure than previously experienced, attributable mainly to water abstractions for irrigation, household water supply and industrial activities in the catchments. Soil erosion, primarily attributable to the lack of soil conservation practices on farm lands, overgrazing and deforestation, along with unregulated irrigation practices, are generating large quantities of silt reaching the lakes. Improper utilization of water and land resources in the catchments, along with population growth and climate change impacts, is escalating the threats to the health of the lake and river ecosystems. As a result, some of the lakes exhibited reduced water levels and increased salinity. This article reviews the major environmental changes happening to these lakes and their feeder rivers. Visits were made to the area to update previous information while also consolidating the trends of change in the aquatic systems and the watersheds attributed to intense development practices.     

Electro‐induced polymerization of acrylamide initiated by the potassium permanganate–titriplex VI redox system

The polymerization of acrylamide (AAm) was carried out with a potassium permanganate–Titriplex VI redox initiator system with and without electrolysis. Because of the high metal‐ion concentration in general, low‐molecular‐weight polymers were obtained (weight‐average molecular weight = 2600–4000). The effect of potassium permanganate and AAm concentrations and temperature on the polymerization yield was studied and compared with results obtained under the same experimental conditions used for electrolysis. The results of Fourier transform infrared spectroscopy, atomic absorption spectrometry, and scanning electron microscopy (SEM) results are given. SEM micrographs of the polymer obtained by electrochemical methods exhibited smoother surfaces than those obtained by nonelectrolytic methods. In the absence of potassium permanganate, there was no polymerization under experimental conditions. A possible reaction mechanism is suggested. The electro‐induced system resulted in about a 50% increase in the yield. Manganese content in the electro‐induced and chemical polymerization systems were 2.7 and 8.2%, respectively, supporting the yield increase in the electro‐induced system. A graphite electrode was used and resulted in a high yield and a fibrous polymeric structure. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 81: 1526–1534, 2001     

Contribution of extracellular polymeric substances from Shewanella sp. HRCR-1 biofilms to U(VI) immobilization

The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) to U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells with minimal EPS, we show that (i) bEPS from Shewanella sp. HRCR-1 biofilms contribute significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; (ii) bEPS can be considered a functional extension of the cells for U(VI) immobilization and they likely play more important roles at lower initial U(VI) concentrations; and (iii) the U(VI) reduction efficiency is dependent upon the initial U(VI) concentration and decreases at lower concentrations. To quantify the relative contributions of sorption and reduction to U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(VI). We found that, when reduced, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated the reactivity of laEPS, while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, possibly facilitated U(VI) reduction.