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排序方式: 共有374条查询结果,搜索用时 31 毫秒
1.
Aqueous solutions of poly(vinyl pyrrolidone)-fullerene complexes (PVP-C70) have been studied using static and dynamic light scattering methods. Two diffusive processes were detected. The slow diffusion was interpreted as dynamics of large intermolecular PVP-C70 complexes while the fast diffusion was associated with the presence of individual PVP molecules in solution. It was also shown that the molecular weights and dimensions of PVP-C70 complexes are smaller than for PVP-C60 by a factor of 2.5-3. In aqueous solutions of PVP-C70 complex the depolarization and dissymmetry of scattered light were observed in contrast to PVP-C60 solutions. It reveals the existence of anisotropic structures in PVP-C70 solutions. Intermolecular interactions within PVP-C70 complexes are weak and a hydrodynamic field can destroy complexes. 相似文献
2.
Heikki Hämmäinen Eero Eloranta Esko Pohjanpalo 《Journal of Intelligent Manufacturing》1990,1(4):203-215
Flexible integration of distributed design and manufacturing activities is one of the key issues in applying just-in-time principles along the logistics chain. The potential of AI based approaches in this field is clear, but the inherent asynchrony, concurrency, and inconsistency of distributed operations has reduced enthusiasm so far.This paper discusses coordination in the context of geographically distributed manufacturing of one-of-a-kind products. Cooperation of partners is based on semi-automated user agents which operate as an integrative layer between more dedicated tools and systems. The management of order changes in elevator manufacture is used as a case example.The work reported here is part of the DIMUN project (DIMUN, 1989) in the RACE program. 相似文献
3.
Bonny K. Larsson Heikki Pyysalo Marketta Sauri 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1988,187(6):546-551
Zusammenfassung Es wird über ein Verfahren zur Abtrennung der in gegrillten und geräucherten Lebensmitteln enthaltenen mutagenen polycyclischen organischen Stoffe in einzelne Klassen berichtet. Das Verfahren umfaßt eine erste Extraktion mit Aceton, das Abscheiden von Fett und Proteinen durch Ausfällung bei –55 °C und eine Säure-Base-Extraktion. Die weitere Fraktionierung erfolgte durch Gelfiltration und Silicagel-Chromatographie. Bei vier Proben von gegrillten Würsten waren 80 bis 90% der extrahierten Mutagenität (TA98 + S9) in den basischen Fraktionen enthalten. Die in der Flamme gegrillten Würste hatten eine höhere Mutagenität als die auf Holzkohle gegrillten. Bei den geräucherten Fischen war die Mutagenität gering und verteilte sich gleichmäßig auf die basischen und die neutralen/sauren Fraktionen. Einige Proben zeigten schwache Direktmutagenität in den neutralen/sauren Fraktionen. Die Anwesenheit von Nitrit in den gegrillten Würsten hatte keinen erheblichen Einfluß auf die Mutagenität. Die Gaschromatographie, Selektive Ionregistrierung-Technik, wurde erfolgreich zur Identifizierung mehrerer PAH-Verbindungen eingesetzt, und mit ihr konnten mehrere Nitro-PAH und oxydierte Verbindungen vorläufig identifiziert werden. Der Nachweis der Mutagene in den basischen Fraktionen gestaltete sich jedoch wegen Peak-Schweifbildung und mit-eluierenden Materials kompliziert.Summary A method for class separation of mutagenic polycyclic organic material in grilled and smoked foods is described. The procedure involves an initial extraction with acetone, removal of fat and proteins by precipitation at –55 °C, and an acid-base extraction. Further fractionation was carried out by gel filtration and silica gel chromatography. In four samples of grilled sausages, 80%–90% of the extracted mutagenicity (TA98 + S9) was contained in the basic fractions. Flame-grilled sausages showed higher mutagenicity than charcoal-grilled ones. In a smoked fish sample, the mutagenicity was low and evenly distributed between the basic and the neutral/acidic fractions. A few samples showed a weak direct-acting mutagenicity in the neutral/acidic fractions. The presence of nitrite in grilled sausages did not influence the mutagenicity markedly. Gas chromatography-selected ion monitoring was used to successfully identify a number of polycyclic aromatic hydrocarbons (PAHs) and tentatively identify several nitro-PAHs and oxygenated compounds. However, the identification of mutagens in the basic fractions was complicated by peak tailing and the presence of co-eluting material.
Abtrennung mutagenen polycyclischen organischen Materials in gegrillten und geräucherten Lebensmitteln相似文献
4.
Pekka Manninen Päivi Laakso Heikki Kallio 《Journal of the American Oil Chemists' Society》1995,72(9):1001-1008
This study demonstrates the usefulness of capillary supercritical fluid chromatography (SFC) for the characterization of triacylglycerols
of edible oils and fats. Triacylglycerols were separated according to the acyl carbon number and the degree of unsaturation
on a 25% cyanopropyl/25% phenyl/50% methylpolysiloxane stationary phase. Valuable information concerning the triacylglycerol
composition of berry oils was obtained, despite the overlapping of certain triacylglycerol peaks. Simultaneous analysis of
fat-soluble vitamins and triacylglycerols is not practical by capillary SFC with flame-ionization detection because of the
low concentration of naturally-occurring fat-soluble vitamins in edible oils. Therefore, higher loading of the sample, which
led to overloading of triacylglycerols, was required to get reasonable peaks for fat-soluble vitamins. The method was applied
to the characterization of triacylglycerols and tocopherols in sea buckthorn pulp and seed oil, and cloudberry seed oil without
any sample purification prior to SFC. In addition, the stationary phase proved useful for separating the more complex mixtures
of triacylglycerols found in milk fat and in fish oil. 相似文献
5.
Heikki Srkel Jari Takatalo Patrick May Mikko Laakso Gte Nyman 《International journal of human-computer studies》2009,67(9):787-799
Human movement in virtual environments (VEs) is a largely unstudied area, and there are no well-established methods of measuring it in VEs. Consequently, it is unclear how movement affects the experiential side of VEs. We introduce a novel method of measuring and modelling human movement. A specific information entropy-based modelling method enabled us to identify different movement patterns and analyse the experiential components related to them. The data was collected by registering the movement patterns of 68 participants who were in a virtual house doing a search task. The experiential side of the VE was measured with the Experimental Virtual Environment Questionnaire (EVEQ). Four movement patterns were identified. In addition, fluent movement in VEs was related to a high sense of presence. Moreover, the participants who moved fluently in the environment assessed their skills high. The results show how movement is related the way in which people experience the VE. The movement analysis method introduced here is applicable to other related research areas as well. 相似文献
6.
We extracted a collection of eye movement signals employed for almost two decades in clinical otoneurological tests at a balance laboratory. During those years we designed and programmed signal analysis methods to analyse their features in detail and to compute medically important attributes. In the present study, using such attributes and their results computed we classified test cases into groups of healthy subjects and patients with multilayer perceptron neural networks. Classification succeeded in total accuracies from 60% to 90% depending on the type of eye movements, which were saccades, nystagmus, sinusoidal movements and vestibulo-ocular reflex stimulated in two different ways; these are the chief eye movement tests applied in otoneurology. 相似文献
7.
Heikki Ailisto Lauri Pohjanheimo Pasi Välkkynen Esko Strömmer Timo Tuomisto Ilkka Korhonen 《Personal and Ubiquitous Computing》2006,10(6):333-344
The prevalent visions of ambient intelligence emphasise natural interaction between user and functions and services embedded in the environment or available through mobile devices. In these scenarios the physical and virtual worlds seamlessly gear into each other, making crossing the border between these worlds natural or even invisible to the user. The bottleneck in reaching these scenarios appear in the natural mapping between the physical objects and their virtual counterparts. The emergence of local connectivity in mobile devices opens possibilities for implementing novel user interface paradigms to enhance this mapping. We present physical selection paradigm for implementing an intuitive human technology interaction for mobile devices. In order to demonstrate the feasibility of the paradigm we implemented two experimental set-ups using commercially available smart phones with IrDA connectivity. The experiments involved selecting a website by physically pointing at its symbol and making a phone call by pointing at an icon representing the person to be called. In tentative user experiments the physical selection method was more time-efficient and it was perceived more positively by the users than a conventional method.
相似文献
Heikki AilistoEmail: |
8.
Reino R. Linko Heikki Kallio Tapani Pyysalo Kristiina Rainio 《Zeitschrift für Lebensmitteluntersuchung und -Forschung A》1978,166(4):208-211
Summary Volatile carbonyl compounds of carrot varietyFeonia Hunderup S-64 at various stages of maturity were analysed as their 2,4-DNPH's by a combined TLC-GLC-MS method. Twenty-three different carbonyl compounds were identified, of which undecanal, buten-2-al, methylbutenal, pentan-2-one, 6-methyl-5-hepten-2-one and 5-methylfurfural have not previously been found in carrot. During maturation the content of acetaldehyde and acetone increased significantly, while that of methylbutenal decreased.
Die leichtflüchtigen Monocarbonylverbindungen der Karotten in verschiedenen Stufen der Reife
Zusammenfassung Die leichtflüchtigen Carbonylverbindungen der Karotten Varietät Feonia Hunderup S-64 wurden in verschiedenen Stufen der Reife als 2,4-DNPH mit der kombinierten DC-GC-MS-Methode analysiert. Dreiundzwanzig verschiedene Carbonylverbindungen wurden nachgewiesen. Von diesen sind Undecanal, 2-Butenal, Methylbutenal, 2-Pentanon, 6-Methyl-5-hepten-2-on und 5-Methylfurfural noch nicht in Karotten aufgefunden worden. Während des Reifens nahm der Gehalt an Acetaldehyd und Aceton bedeutend zu. Der Gehalt an Methylbutenal verminderte sich.相似文献
9.
Elke Parkkinen Erkki Oura Heikki Suomalainen 《Journal of the Institute of Brewing》1976,82(5):283-285
The classical plate method for discriminating between viable and nonviable yeast cells in stored baker's yeast was compared with dead cell staining techniques using methylene blue and three fluorochrome stains. The increase of dead yeast cells during storage of baker's yeast for up to 16 days at 5°C, 20°C and 35°C was determined. During prolonged storage, especially at 35°C, the death rate increased rapidly and the yeast cake began to soften because of autolysis. In these conditions the choice of method for determining the proportion of dead cells proved to be of great importance. Useful results for yeast stored for some time at 35°C could be obtained only by the fluorochrome technique using primuline, acridine orange or acriflavine as fluorochromes. 相似文献
10.
Nataliya Strokina Jiri Matas Tuomas Eerola Lasse Lensu Heikki Kälviäinen 《Machine Vision and Applications》2016,27(3):387-396
The paper proposes a method for the detection of bubble-like transparent objects in a liquid. The detection problem is non-trivial since bubble appearance varies considerably due to different lighting conditions causing contrast reversal and multiple interreflections. We formulate the problem as the detection of concentric circular arrangements (CCA). The CCAs are recovered in a hypothesize-optimize-verify framework. The hypothesis generation is based on sampling from the partially linked components of the non-maximum suppressed responses of oriented ridge filters, and is followed by the CCA parameter estimation. Parameter optimization is carried out by minimizing a novel cost-function. The performance was tested on gas dispersion images of pulp suspension and oil dispersion images. The mean error of gas/oil volume estimation was used as a performance criterion due to the fact that the main goal of the applications driving the research was the bubble volume estimation. The method achieved 28 and 13 % of gas and oil volume estimation errors correspondingly outperforming the OpenCV Circular Hough Transform in both cases and the WaldBoost detector in gas volume estimation. 相似文献