Flexible poly(styrene-ethylene-butadiene-styrene) hybrid nanofibers for bioengineering and water filtration applications

Among the thermoplastic elastomers that play important roles in the polymer industry due to their superior properties, styrene-based species and polyurethane block copolymers are of great interest. Poly(styrene-ethylene-butadiene-styrene) (SEBS) as a triblock copolymer seems to have the potential to meet many demands in different applications due to various industrial requirements where durability, biocompatibility, breaking elongation, and interfacial adhesion are important. In this study, the SEBS triblock copolymer was functionalized with natural (Satureja hortensis, SH) and synthetic (nanopowder, TiO₂) agents to obtain composite nanofibers by electrospinning and electrospraying methods for use in biomedical and water filtration applications. The results were compared with thermoplastic polyurethane (TPU) composite nanofibers, which are commonly used in these fields. Here, functionalized SEBS nanofibers exhibited antibacterial effect while at the same time improving cell viability. In addition, because of successful water filtration by using the SEBS composite nanofibers, the material may have a good potential to be used comparably to TPU for the application.     

Carbon Bonding State Has a Small Effect on Melting of Direct-Reduced Iron

Metallurgical and Materials Transactions B - The concentration and chemical bonding state of carbon in direct-reduced iron (DRI) might affect DRI melting temperature and rate. The effects of carbon...     

Effect of heat treatment in air on the thermal properties of SiC fibre reinforced composite: Part 2 A magnesium aluminium silicate (MAS) matrix glass ceramic composite

The thermal properties of a magnesium aluminium silicate (MAS) glass ceramic matrix composite reinforced by SiC (Nicalon) fibres have been investigated before and after heat treatment in the temperature range 600–1,200 °C. Within this temperature range, during the heat treatment at lower temperatures such as 600 and 700 °C, the oxidation of the carbon layer occurred and mixture of silicon and carbon was formed in the interface. This results in a decrease in thermal diffusivity values. After heat treatment at the temperatures higher than 1,000 °C, the carbon layer was thickened and resulted in the higher thermal diffusivity values.     

Fast Decodable Turbo Codes

Decoding delay is an important consideration for the use of turbo codes in practical applications. We propose a new structure for turbo codes which is very suitable for parallel decoding. It is shown by union bound analysis and simulation results that the proposed system performance is comparable to that of the classical turbo codes     

Significance of fluid regime in biological filtration

A dispersed flow model previously developed to study substrate utilization in unsaturated media was experimentally verified and its practical application was considered. For this purpose, measurements were made using tap water and a synthetic feed solution. The importance of the change in fluid regime as regards to the simultaneous transport and reaction within biological filters were demonstrated. The effect of drop formation and the breakage of liquid jets inside the filters on substrate utilization was also shown.     

Photoelectrocatalytic humic acid degradation kinetics and effect of pH,applied potential and inorganic ions

This study addresses the removal of humic acid (HA) dissolved in an aqueous medium by a photoelectrocatalytic process. UV₂₅₄ removal and the degradation of color (Vis₄₀₀) followed pseudo‐first order kinetics. Rate constants were 1.1 × 10^?1 min^?1, 8.3 × 10^?2 min^?1 and 2.49 × 10^?2 min^?1 (R² > 0.97) for UV₂₅₄ degradation and 1.7 × 10^?1 min^?1, 6.5 × 10^?2 min^?1 and 2.0 × 10^?2 min^?1 for color removal from 5 mg dm^?3, 10 mg dm^?3 and 25 mg dm^?3 HA respectively. Following a 2 h irradiation time, 96% of the color, 98% of the humic acid and 85% of the total organic carbon (TOC) was removed from an initial 25 mg dm^?3 HA solution in the photoanode cell. Photocatalytic removal on the same photoanode was also studied in order to compare the two methods of degradation. Results showed that the photoelectrocatalytic method was much more effective than the photocatalytic method especially at high pH values and with respect to UV₂₅₄ removal. The effect of other important reaction variables, eg pH, external potential and electrolyte concentration, on the photoelectrocatalytic HA degradation was also studied. Copyright © 2003 Society of Chemical Industry     

High-quality photonic sampling streams from a semiconductor diodering laser

We report on the development of an ultralow-noise, external-cavity, actively mode-locked semiconductor diode laser for application in next-generation photonic sampling systems. A summary of harmonically mode-locked noise characteristics in a 65-MHz ring cavity is presented through the range of pulse repetition frequencies between 130 MHz and 8.3 GHz (2nd-128th harmonic). Important implications regarding the use of gain-versus-loss modulation as the active modelocking mechanisms are discussed. We also report what are, to our knowledge, the lowest noise characteristics achieved to date for a semiconductor diode laser operating at 10 GHz. Individually optimized results of 0.12% rms amplitude noise (10 Hz-10 MHz), and 43 fs rms residual phase jitter (10 Hz-10 MHz) provide a theoretical resolution of 8.6 bits in a 10-GSPS optical analog-to-digital converter. We have also achieved dispersion-compensated pulsewidths; as short as 1.2 ps, and shown successful operation of a novel phase-locked-loop capable of reducing the rms; residual phase noise by as much as 91% within its response bandwidth. Finally, the first measurements of residual phase noise out to the Nyquist frequency (5 GHz) are presented, providing an upper bound on the rms residual phase jitter of 121 fs (10 Hz-5 GHz)     

A STUDY OF THE FLOTATION OF OXIDIZED AHASRA COAL

The flotation of oxidized Amasra Coal which was collected between 1973-1978 and, stored in the atmospheric conditions was examined In this work. Coal samples were fractioned by wet screening to +0.560 mm, -0.500 + 0.140 mm, -0.140 mm particle sizes and first fraction was ground to -0.560 mm before flotation. Motorin and pine oil which had been heated at 125° C for 5 hours were used ns flotation reagents. The influence of impeller speed, aeration rate, solid concent of the pulp, reagent amounts were examined and optimum values were determined. Increase of the pine oil amount added to the pulp, increased the coal. recovery on the flotation of this oxidized coal.     

Methane to higher hydrocarbons via halogenation

Activation of methane with a halogen followed by the metathesis of methyl halide is a novel route from methane to higher hydrocarbons or oxygenates. Thermodynamic analysis revealed that bromine is the most suitable halogen for this goal. Analysis of the published data on the reaction kinetics in a CSTR enabled us to judge on the effects of temperature, reactor residence time and the feed concentrations of bromine and methane to the conversion of methane and the selectivity towards mono or dibromomethane. The analysis indicated that high dibromomethane selectivity is attainable (over 90%) accompanied by high methane conversions. The metathesis of dibromomethane can provide an alternative route to the conversion of methane (natural gas) economically with smaller installations than the current syn-gas route.