Densities and Viscosities of Oleic Acid at Atmospheric Pressure

The densities of oleic acid were measured over the temperature range from (293 to 459) K at atmospheric pressure using a densimeter based on the modified hydrostatic weighing method. The dynamic viscosities of the same oleic acid sample were measured using a capillary viscometer (VPZ-2 m) in the range from (293 to 363) K at atmospheric pressure. The combined expanded uncertainty of the density, atmospheric pressure, viscosity, and temperature measurements at the 95% confidence level with a coverage factor of k = 2 is estimated to be 0.15%, 1.0%, 3.5%, and 15 mK, respectively. The values of uncertainty for density and viscosity include the effects of purity and calibration (total expanded uncertainty). These experimental data were used to develop wide-range correlations for the density and viscosity based on theoretically confirmed Arrhenius–Andrade and Vogel-Tamman-Fulcher (VTF) models. The value of the glass temperature ( T _g= 179.78 K.) for the oleic acid was estimated using the VTF parameters derived from the present viscosity measurements. To additionally validate the reliability of the measured density data, the same oleic acid samples were measured using the pycnometric method. The present study showed that the densities measured using the modified hydrostatic weighing densimeter (HWD) agree with the values obtained using the pycnometric method within 0.09% for Sample 1 and 0.25% for Sample 2.     

The grinding rate and specific cost of internal plunge-cut diamond grinding of hardmetals with periodic electrical discharge actions

The authors have studied the influence of diamond wheel grain size on the grinding rate and specific cost of internal plunge-cut elastic-mode grinding of VK15 (WC-15Co). Periodic electric-discharge actions on the wheel working surface, with an optimal cyclicity, provide an 396% improvement of the grinding rate and an 305% reduction of specific cost in comparison to grinding performed with no such actions.     

Supercritical fluid CO<Subscript>2</Subscript>-extraction regeneration of nickel–molybdenum catalyst for hydrotreatment

Results from studying the supercritical fluid СО₂-extraction regeneration of DN-3531 industrial nickel–molybdenum hydrotreatment catalyst in the temperature range of 323.15–383.15 K, at pressures of up to 30 MPa, and with modification of the basic extragent with such polar compounds as chloroform, methanol, ethanol, acetone, and dimethylsulfoxide (DMSO), are presented. The order of modifiers corresponds to the increase in the solubilizing ability of modified supercritical carbon dioxide (SC-СО₂) with respect to catalyst- deactivating deposits. With DMSO as the most efficient modifier, however, not only are deactivating compounds removed but nickel and molybdenum as well, considerably reducing the final activity of a regenerated sample. During extraction regeneration, the content of coke in the catalyst is reduced by two-thirds, while the specific surface area and the pore volume grow. The activity of the deactivated catalyst in dibenzothiophene hydrodesulfurization (HDS) and naphthalene hydrogenation grows by several hundred per cent after one-time SC-CO₂ treatment and is 2.5 times higher than for a sample regenerated using the traditional oxidative method.     

Impregnation of carbonate rock by deasphalted oil with the use of a supercritical fluid impregnation process

The authors present the results of investigation and experimental implementation of several processes: production of heavy oil residue and its deasphaltizing and impregnation of carbonate rock with deasphalted oil. Heavy oil residue has been produced during fractionation of highly-vicious oil by steam-thermal method. Deasphaltizing of oil-residue and impregnation of carbonate rock are implemented with the use of extraction and supercritical fluid impregnation processes with propane-butane solvent.     

Thermal Conductivity and Thermal Diffusivity of Liquid Aromatic Hydrocarbons Undistorted by Radiation Heat Transfer

The values of thermal conductivity and thermal diffusivity are measured for seven substances (benzene, toluene, -n-m-xylenes, ethylbenzene, and isopropylbenzene) at temperatures T = 293–593 K and pressures P = P _S – 30 MPa. The obtained values of thermal conductivity and thermal diffusivity differ from the reference values by not more than 15%. The generalizing dependences are given, which describe the thermal conductivity, thermal diffusivity, and heat capacity per unit volume of n-alkanes, alkenes, and aromatic hydrocarbons.     

PMD-induced fluctuations of bit-error rate in optical fiber systems

This paper presents a method that allows evaluating the performance of an optical fiber system where bit errors result from a complex interplay of spontaneous noise generated in optical amplifiers and birefringent disorder of the transmission fiber. We demonstrate that in the presence of temporal fluctuations of birefringence characteristics, the bit-error rate (BER) itself is insufficient for characterizing system performance. Adequate characterization requires introducing the probability distribution function (PDF) of the BER obtained by averaging over many realizations of birefringent disorder. Our theoretical analysis shows that this PDF has an extended tail indicating the importance of anomalously large values of BER. We present the results of comprehensive analysis of the following issues: 1) The dependence of the PDF tail shape on detection details, such as filtering and regular temporal shift adjustment; 2) the changes in the PDF of BER that occur when the first- or higher order polarization mode dispersion (PMD) compensation techniques are applied; 3) an alternative PMD compensation method capable of providing more efficient suppression of extreme outages.     

Transesterification of rapeseed and palm oils in supercritical methanol and ethanol

The results of the rapeseed and palm oils transesterification with supercritical methanol and ethanol were presented. The studies were performed using the experimental setups which are working in batch and continuous regimes. The effect of reaction conditions (temperature, pressure, oil to alcohol ratio, reaction time) on the biodiesel production (conversion yield) was studied. Also the effect of preliminary ultrasonic treatment (ultrasonic irradiation, emulsification of immiscible oil and alcohol mixture) of the initial reagents (emulsion preparation) on the stage before transesterification reaction conduction on the conversion yield was studied. We found that the preliminary ultrasonic treatment of the initial reagents increases considerably the conversion yield. Optimal technological conditions were determined to be as follows: pressure within 20-30 MPa, temperature within 573-623 K. The optimal values of the oil to alcohol ratio strongly depend on preliminary treatment of the reaction mixture. The study showed that the conversion yield at the same temperature with 96 wt.% of ethanol is higher than with 100 wt.% of methanol.     

Robot-Assisted Laser Strengthening: Mathematical Aspects

Russian Engineering Research - Abstract—A mathematical model is developed for predicting the surface characteristics of dies after laser strengthening by the Geksapod robotic system. The...     

Cascaded optical communication systems with in-line semiconductoroptical amplifiers

The optimization of the performance of installed standard-monomode fibers based optical transmission systems with in-line semiconductor optical amplifiers (SOA's) is reported in this paper. Both solitons and nonreturn-to-zero (NRZ) signals are studied and their capacities are compared. This investigation is based on numerical simulations by solving the nonlinear Schrodinger equations with the split-step method while the SOA is simulated with two different models that we show to be in a good agreement, transmissions over distances of the order of several hundreds of kilometers are shown to be possible, and very long distances can be reached especially if in-line sliding filters are used