Real-time X-ray diffraction study at different scan rates of phase transitions for dipalmitoylphosphatidylcholine in KSCN

A questionnaire survey was carried out to examine the attitudes and practices of Australian and New Zealand intensivists with regard to brain death and organ donation. A return rate of 82.5% was achieved. Fifty-eight per cent had written evidence of their own wishes to donate organs and 94% would agree to donation from a dependent. At least one intensivist is involved in certifying brain death on 95% of occasions. Intensivists are involved in the request for organ donation over 90% of the time although one-third do not believe that it is their role to request organ donation. Although two-thirds believe that the family should always be approached for organ donation, another 52 out of 254 indicated that it was their (the intensivist's) role to decide if families should be asked for organ donation. Possible reasons for not requesting are language or other communication problems, perceptions of cultural differences and degrees of family distress. Twenty per cent of respondents do not provide haemodynamic support before brain death confirmation. Australian and New Zealand intensivists overwhelmingly support the concept of brain death, current methods of confirmation of brain death, organ donation and transplantation. Possible reasons behind loss of potential donors include decisions not to resuscitate both before and after brain death is confirmed. Perceptions of family grief and cultural differences clearly inhibit requests for organ donation. A very few units have an effective policy on approaching families about organ donation. Intensivists have almost exclusive control over requests for organ donation and thus bear a full professional responsibility for this element of hospital practice.     

Dexterous workspace optimization of an asymmetric six-degree of freedom Stewart–Gough platform type manipulator

In this paper, an asymmetric Generalized Stewart–Gough Platform (GSP) type parallel manipulator is designed by considering the type synthesis approach. The asymmetric six-Degree Of Freedom (DOF) manipulator optimized in this paper is selected among the GSPs classified under the name of 6D. The dexterous workspace optimization of Asymmetric parallel Manipulator with tEn Different Linear Actuator Lengths (AMEDLAL) subject to kinematics and geometric constraints is performed by using the Particle Swarm Optimization (PSO). The condition number and Minimum Singular Value (MSV) of homogenized Jacobian matrix are employed to obtain the dexterous workspace of AMEDLAL. Finally, the six-DOF AMEDLAL is also compared with the optimized Traditional Stewart–Gough Platform Manipulator (TSPM) considering the volume of the dexterous workspace in order to demonstrate its kinematic performance. Comparisons show that the manipulator proposed in this study illustrates better kinematic performance than TSPM.     

Digital ischemia and gangrene due to red blood cell aggregation induced by acquired dysfibrinogenemia

Digital gangrene was observed in a patient who had angiographic findings of digital arterial occlusion. The patient's blood showed a marked red blood cell aggregation with rouleaux formation in long chains, which could not be dispersed at shear rates up to 200 sec-1. Studies of the patient's blood revealed the presence of an abnormal fibrinogen capable of aggregating normal red blood cells. This fibrinogen was found by Raman spectroscopy to have an increased alpha-helical content, whereas the beta-sheet content was decreased. Defibrinogenation therapy with ancrod resulted in a dramatic symptomatic relief. The disappearance of the abnormal fibrinogen 6 months later and an absence of a family history indicate that this dysfibrinogenemia was acquired.     

FPGA Based Implementation and Comparison of Beamformers for CDMA2000

For the integration of smart antennas into third generation code division multiple access (CDMA) base stations, it still remains as a challenging task to implement smart antenna algorithms on programmable processors. In this paper, we study implementations of some CDMA compatible beamforming algorithms, namely least mean square (LMS), constant modulus (CM), and space code correlator (SCC) algorithms, using Xilinx??s Virtex family FPGAs. This study exhibits feasibility of implementing even simple, practical, and computationally small algorithms based on today??s most powerful FPGA technologies. 16 and 32 bits floating point implementations of the algorithms are investigated using both Virtex II and Virtex IV FPGAs. CDMA2000 reverse link baseband signal format is used in the signal modeling. Randomly changing fading and Direction-of-arrivals (DOAs) of multipaths are considered as a channel condition. The implementation results in terms of beamforming accuracy, FPGA resource utilization, weight vector computation time, and DOA estimation error are presented. Beamformer weight vectors using LMS and CM can be computed within less than 20 ??s on Virtex II FPGA and 10 ??s on Virtex IV FPGA, and using SCC it can be achieved within less than 22 ??s on Virtex IV FPGA. These results show that FPGAs provide approximately 500 times faster speed in implementations than our previous work with DSPs.     

Comparative relationships of direct, indirect, and semi-direct ultrasonic pulse velocity measurements in concrete

An experimental study is conducted to compare direct, indirect and semi-direct ultrasonic pulse velocity (UPV) measurements on a total of 30 concrete blocks 30 × 30 × 25 cm³ in size that came from different mix batches and have cube compressive strength grades varying between 18.8 and 79.9 MPa. The correlations are established between the direct UPV and indirect UPV in the concrete casting direction as well as in the horizontal direction and semi-direct UPV measurements via statistical analysis. The statistical analysis reveals that the average value of direct UPV is 9%, 4%, and 4% higher than the average of indirect UPV in the casting direction, indirect UPV in the horizontal direction, and semi-direct UPV, respectively. The average value of indirect UPV in the horizontal direction is 5% higher than that in the casting direction. The text was submitted by the authors in English.     

Spatial inhomogeneity in poly(acrylic acid) hydrogels

The crosslink density distribution in gels known as the spatial gel inhomogeneity has been investigated in poly(acrylic acid) (PAAc) gels with the static light scattering measurements. PAAc gels were prepared at a fixed chemical crosslink density but at various initial monomer concentrations. The gels were characterized by swelling and elasticity tests as well as by light scattering measurements. PAAc gels exhibit a maximum degree of spatial inhomogeneity at a critical monomer concentration . shifts toward higher concentrations as the gel swells beyond its dilution degree after preparation. Depending on the polymer concentration in gels, swelling reduces or enhances the extent of the spatial inhomogeneities. It was shown that the apparent degree of the spatial gel inhomogeneity is determined by the combination of three effects, namely the effects of the effective crosslink density, charge density and segment density. The relative magnitudes of these effects vary depending on the polymer concentration and lead to the appearance of a maximum degree of spatial inhomogeneity at a critical concentration.     

A Practical Space-Code Correlator Receiver for DSP Based Software Radio Implementation in CDMA2000

Development of practical algorithms for beamforming in 3G CDMA systems and their software radio implementations are still a challenging task, which will facilitate upgrading of traditional base stations into smart antenna capable 3G base stations. In this paper, we propose a practical space-code correlator (SCC) receiver structure for its software radio implementation a DSP. SCC’s advantage comes from the fact that it doesn’t require any training sequence or learning parameter as in other algorithms (LMS or CM). DSP implementations of the SCC are performed using Texas Instruments C67xx family platforms. In the simulations, reverse link base band signal format of CDMA2000 is used and the effects of different array topologies (uniform linear array-ULA or uniform circular array-UCA) are considered. The implementation results regarding beamforming accuracy, weight vector computation time (execution time), search resolution effect on DOA estimation accuracy, DSP resource utilization, and received SINR are presented. The results show that DSP based SCC beamformer can estimate weight vectors within less than 10 ms with DOA search resolution of 2° especially when C6713 DSP is used. With faster DSPs and larger search resolutions, execution time could be significantly reduced as well. It provides comparable SINR performance with LMS and CM algorithms.

Kinetically Stable Oxide Overlayers on Mo3P Nanoparticles Enabling Lithium–Air Batteries with Low Overpotentials and Long Cycle Life

The main drawbacks of today's state-of-the-art lithium–air (Li–air) batteries are their low energy efficiency and limited cycle life due to the lack of earth-abundant cathode catalysts that can drive both oxygen reduction and evolution reactions (ORR and OER) at high rates at thermodynamic potentials. Here, inexpensive trimolybdenum phosphide (Mo₃P) nanoparticles with an exceptional activity—ORR and OER current densities of 7.21 and 6.85 mA cm⁻² at 2.0 and 4.2 V versus Li/Li⁺, respectively—in an oxygen-saturated non-aqueous electrolyte are reported. The Tafel plots indicate remarkably low charge transfer resistance—Tafel slopes of 35 and 38 mV dec⁻¹ for ORR and OER, respectively—resulting in the lowest ORR overpotential of 4.0 mV and OER overpotential of 5.1 mV reported to date. Using this catalyst, a Li–air battery cell with low discharge and charge overpotentials of 80 and 270 mV, respectively, and high energy efficiency of 90.2% in the first cycle is demonstrated. A long cycle life of 1200 is also achieved for this cell. Density functional theory calculations of ORR and OER on Mo₃P (110) reveal that an oxide overlayer formed on the surface gives rise to the observed high ORR and OER electrocatalytic activity and small discharge/charge overpotentials.