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排序方式: 共有96条查询结果,搜索用时 0 毫秒
1.
Qiu Zhuxian Fan Liman K. Grjotheim H. Kvande 《Journal of Applied Electrochemistry》1987,17(4):707-714
Visual observations of several molten salt electrolysis processes were made in a two-compartment, see-through quartz cell. The electrolyses of aluminium, magnesium, lead, zinc, sodium and potassium were studied. The colour of the melt in the anode compartment was pale yellow for fluoride-chloride melts and red for chloride melts, caused by the presence of dispersed anode gases during electrolysis. In the cathode compartment, streamers of metal fog were formed. The colours of the metal fog were purple for aluminium, grey for magnesium, lead and zinc, blue for sodium and green for potassium.The metal fog tended to sink to the bottom of the cell, which indicated that it had a higher density than that of the melt. The metal fog also penetrated into the anode compartment, probable due to convection and diffusion in the melt. The most probable explanation of the nature of the metal fog is that it consisted ofdispersed metal particles. This chemically unstable phase dissolved easily in the melt and was oxidized quickly by the anode gases. 相似文献
2.
Attila Diószegi 《中国铸造》2007,4(3):210-214
The thermal conductivity or diffusivity of pearlitic grey irons with various carbon contents is investigated by the laser flash method. The materials are cast in controlled thermal environments and produced in three dissimilar cooling rates. The cooling rate together with the carbon content largely influence the thermal conductivity of grey iron. Linear relationships exist between the thermal conductivity and the carbon content, the carbon equivalent and the fraction of former primary solidified austenite transformed into pearlite. The work shows that optimal thermal transport properties are obtained at medium cooling rates. Equations describing the thermal conductivity of pearlite,solidified as pre-eutectic austenite, and the eutectic of grey iron are derived. The thermal conductivity of pearlitic grey iron is modeled at both room temperature and elevated temperature with good accuracy. 相似文献
3.
Slips and falls and associated outdoor injuries are prevalent in cold climates. The objectives of this field investigation were to describe the consequences of slips and falls on ice and snow and the associated injuries, to assess the risks of various icy and snowy surfaces, to identify design needs of footwear, and to ascertain preventive measure preferences of outdoor workers. The organizations investigated were a newspaper delivery service, a military regiment, mining and construction industries. The results showed that fall events occur most frequently on ice covered with snow. This is due to the difficulty of perceiving hidden risks in order to adjust gait strategies. The professional footwear provided does not provide enough protection against slips and falls. Slip resistant properties are ranked as one of the top requirements by the users. Their most preferred preventive measures are footwear with anti-slip properties and the application of anti-slip materials, such as sand or salt. 相似文献
4.
Classification of metabolic and respiratory demands in fire fighting activity with extreme workloads
Fire fighting work comprises work tasks requiring an energy yield at maximal or close to maximal levels of the individual. Due to the very nature of fire fighting more complex physiological variables are difficult to measure. We measured metabolic and respiratory responses in 15 male, professional fire fighters during simulated work tasks on a test ground. Work time was on the average 22 min with individual components of work tasks lasting 2-4 min. The mean oxygen consumption for the whole exercise (22 min) was 2.75+/-0.29 l/min. The most demanding work task demanded an oxygen uptake of 3.55+/-0.27 l/min. Corresponding values for respiratory minute volumes were 82+/-14 and 102+/-14l/min, respectively. Heart rates averaged 168+/-12 for the whole test and 179+/-13 beats/min for the heaviest work task. Two new classes for classification of intensive and exhausting, short term physical work are proposed for inclusion in ISO8996 and values for relevant parameters are proposed. 相似文献
5.
Nina Hammer Ingvar Kvande Wouter van Beek De Chen Magnus Rønning 《Topics in Catalysis》2007,45(1-4):25-29
In situ X-ray absorption spectroscopy (XAS) has been performed to investigate the active site on Au-based catalysts in the water-gas
shift (WGS) reaction. The surface area and hence the WGS activity is higher for AuTiO2 catalysts supported on carbon nanofibres (CNF) than TiO2. The WGS reaction rate depends on the Au coordination number with an apparent maximum close to eight which corresponds to
a particle size of approximately 2.5–3.0 nm. A likely cause for the changes in the electronic structure of Au is the adsorption
of CO on the surface, which also creates a small positive charge in the Au atoms. The catalytic activity significantly improves
when titania is present compared to Au deposited directly on CNF. 相似文献
7.
8.
Barregard L Horvat M Mazzolai B Sällsten G Gibicar D Fajon V Dibona S Munthe J Wängberg I Haeger Eugensson M 《The Science of the total environment》2006,368(1):326-334
As part of the European Mercury Emissions from Chlor Alkali Plants (EMECAP) project, we tested the hypothesis that contamination of ambient air with mercury around chlor alkali plants using mercury cells would increase the internal dose of mercury in people living close to the plants. Mercury in urine (U-Hg) was determined in 225 individuals living near a Swedish or an Italian chlor alkali plant, and in 256 age- and sex-matched individuals from two reference areas. Other factors possibly affecting mercury exposure were examined. Emissions and concentrations of total gaseous mercury (TGM) around the plants were measured and modeled. No increase in U-Hg could be demonstrated in the populations living close to the plants. This was the case also when the comparison was restricted to subjects with no dental amalgam and low fish consumption. The emissions of mercury to air doubled the background level, but contributed only about 2 ng/m(3) to long-term averages in the residential areas. The median U-Hg levels in subjects with dental amalgam were 1.2 microg/g creatinine (micro/gC) in Italy and 0.6 microg/gC in Sweden. In individuals without dental amalgam, the medians were 0.9 microg/gC and 0.2 microg/gC, respectively. The number of amalgam fillings, as well as chewing, fish consumption, and female sex were associated with higher U-Hg. The difference between the countries is probably due to higher fish consumption in Italy, demethylated methyl mercury (MeHg) being partly excreted in urine. Post hoc power calculations showed that if the background mercury exposure is low it may be possible to demonstrate an increase in U-Hg of as little as about 10 ng/m(3) as a contribution to ambient mercury from a point source. 相似文献
9.
Qiuqing Geng Ingvar Holm r Coldsurf research group 《International Journal of Industrial Ergonomics》2001,27(6):387-391
This study deals with human fingers touching cold surfaces of four materials (aluminium, steel, nylon and wood) at different surface temperatures (−20°C, −15°C, −10°C, −4°C, 0°C and 2°C). Contact finger skin-surface interface temperature and subjective responses on thermal and pain sensations were determined during touching. Type of material and their surface temperature clearly affected the contact cooling of the finger. Individual variation in finger contact cooling was significant. Contact temperature limits for human fingers touching cold surfaces are suggested according to the experimental results. In addition, time to reach a critical temperature (7°C, 5°C or 0°C) when contacting a cold metallic surface is discussed.
Relevance to industry
The outcome of this experimental study supplies as a basis for the development of an ergonomics database to determine temperature limit values for cold touchable surfaces. The critical temperatures are relevant to all industries where cold surfaces cause a risk of finger contact cooling for the manual protection in the cold operations. 相似文献
10.
A compact, internally heated, catalytic reactor is demonstrated for the low-temperature oxidation of carbon monoxide. Carbon
nanofibres were grown on carbon felt and used as a support material for Au/TiO2 catalysts. The carbon composite plays two roles; as a support material for the catalyst and for providing heat to the reaction
by the Joule effect. The internal heating offers a stable reactor system with quick temperature response at relatively low
energy input. Comparison between external and internal heating shows higher conversion of CO in the low-temperature range
when using internal heating. The Au/TiO2 catalyst supported on the carbon-carbon composite shows good stability at 250°C. 相似文献