Object-based analysis and change detection of major wetland cover types and their classification uncertainty during the low water period at Poyang Lake, China

Productive wetland systems at land-water interfaces that provide unique ecosystem services are challenging to study because of water dynamics, complex surface cover and constrained field access. We applied object-based image analysis and supervised classification to four 32-m Beijing-1 microsatellite images to examine broad-scale surface cover composition and its change during November 2007-March 2008 low water season at Poyang Lake, the largest freshwater lake-wetland system in China (> 4000 km²). We proposed a novel method for semi-automated selection of training objects in this heterogeneous landscape using extreme values of spectral indices (SIs) estimated from satellite data. Dynamics of the major wetland cover types (Water, Mudflat, Vegetation and Sand) were investigated both as transitions among primary classes based on maximum membership value, and as changes in memberships to all classes even under no change in a primary class. Fuzzy classification accuracy was evaluated as match frequencies between classification outcome and a) the best reference candidate class (MAX function) and b) any acceptable reference class (RIGHT function). MAX-based accuracy was relatively high for Vegetation (≥ 90%), Water (≥ 82%), Mudflat (≥ 76%) and the smallest-area Sand (≥ 75%) in all scenes; these scores improved with the RIGHT function to 87-100%. Classification uncertainty assessed as the proportion of fuzzy object area within a class at a given fuzzy threshold value was the highest for all classes in November 2007, and consistently higher for Mudflat than for other classes in all scenes. Vegetation was the dominant class in all scenes, occupying 41.2-49.3% of the study area. Object memberships to Vegetation mostly declined from November 2007 to February 2008 and increased substantially only in February-March 2008, possibly reflecting growing season conditions and grazing. Spatial extent of Water both declined and increased during the study period, reflecting precipitation and hydrological events. The “fuzziest” Mudflat class was involved in major detected transitions among classes and declined in classification accuracy by March 2008, representing a key target for finer-scale research. Future work should introduce Vegetation sub-classes reflecting differences in phenology and alternative methods to discriminate Mudflat from other classes. Results can be used to guide field sampling and top-down landscape analyses in this wetland.     

Antioxidant properties of various solvent extracts of potato peel,sugar beet pulp and sesame cake

BACKGROUND: Growing interest in the replacement of synthetic food antioxidants by natural ones has fostered research on vegetable sources and screening of raw materials to identify new antioxidants. The food‐processing industry generates substantial quantities of phenolic‐rich by‐products that could be valuable natural sources of antioxidants. In this study the antioxidant properties and total phenolic, flavonoid and flavonol contents of three industrial by‐products, sugar beet pulp, sesame cake and potato peel, extracted with various solvents were examined. Since different antioxidant compounds have different mechanisms of action, several methods were used to assess the antioxidant efficacy of extracts. RESULTS: Among the six solvents tested, methanol gave the highest extract yield of potato peel and sugar beet pulp, while diethyl ether gave the highest extract yield of sesame cake. Methanol exhibited the highest extraction ability for phenolic compounds, with total phenolics amounting to 2.91, 1.79 and 0.81 mg gallic acid equivalent g^?1 dry weight in potato peel, sugar beet pulp and sesame cake extracts respectively, and also showed the strongest antioxidant capacity in the three assays used. All three methods proved that potato peel extract had the highest antioxidant activity owing to its high content of phenolic compounds and flavonoids. CONCLUSION: On the basis of the results obtained, potato peel, sugar beet pulp and sesame cake extracts could serve as natural antioxidants owing to their significant antioxidant activity. Therefore they could be used as preservative ingredients in the food and/or pharmaceutical industries. Copyright © 2009 Society of Chemical Industry     

Photoalignment dynamics of azo dyes series with different coordination metals

There are many photoaligned azo dyes that can be used for orientation of liquid crystals in various display devices. However, the structure of these compounds needs to be optimized to increase the rate of the process of molecule photoalignment, as well as to spread the application of these compounds. The main coordination metal that presents in the molecules of azo dyes is sodium derivatives. The use of other alkali metals remains an open question. We used quantum‐chemical computation methods and reversible intermolecular bonding model to determine the effect of metal coordination on the velocity of photoalignment. The theoretical predictions were experimentally verified using sodium, potassium, lithium, and cesium salts of the model azo dye synthesized by us. We conclude that potassium azo derivatives are the fastest, ceteris paribus.     

Polymer derived ceramic materials from Si,B and MoSiB filler-loaded perhydropolysilazane precursor for oxidation protection

Silica-based coating systems were developed using polymer derived ceramics (PDCs) technology. Ceramic composites on the base of a SiO₂ and SiNO matrix and homogeneously distributed Mo₅SiB₂, SiB₆, Si and B fillers were manufactured. The coating systems have low porosity and provide a high oxidation resistance up to 100 h at 800 °C and 1100 °C in air. The influence of temperature and atmosphere of pyrolysis on the polymer precursor, the volume fraction of filler materials on the chemical composition of compacts as well as their high-temperature oxidation protection was investigated.     

Stroh formalism based boundary integral equations for 2D magnetoelectroelasticity

This paper presents a novel approach for obtaining boundary integral equations of 2D anisotropic magnetoelectroelasticity. This approach is based on the holomorphy theorems and the Stroh formalism and allows developing of the integral equations for the aperiodic, singly and doubly periodic problems of magnetoelectroelasticity. Obtained equations contain the unknown discontinuities of displacement, electric and magnetic potentials and also traction, electric displacement and magnetic induction that allow adopting the existing boundary element procedures for their solution. Analytical solutions for systems of collinear permeable or impermeable cracks are obtained. Numerical boundary element solutions are obtained for the singly and doubly periodic sets of permeable and impermeable cracks in the magnetoelectroelastic medium and a half-plane. Comparison with analytical solutions and other available results validate the present formulations and numerical computation.     

Potentiometric sensor for the indomethacin determination

A potentiometric indomethacin-selective sensor based on Rhodamine B indomethacinate ion-pair (IP) as a membrane carrier is reported. Influences of the membrane composition, pH, and possible interfering ions were investigated on the response properties of the electrode. The sensor exhibits significantly enhanced response toward indomethacinate ions over the concentration range 1 × 10^? 4 mol L^? 1 to 5 × 10^? 2 mol L^? 1 with a lower detection limit (LDL) of 3 × 10^? 5 mol L^? 1 and a slope of ? 60 mV decade^? 1. Fast and stable response, good reproducibility, long-term stability, applicability over a pH range of 6–10 is demonstrated. The proposed electrode shows good discrimination of indomethacin from several inorganic and organic ions. The proposed sensor has been applied for the direct potentiometric determination of indomethacin in pharmaceutical preparations.