全文获取类型
收费全文 | 2245篇 |
免费 | 35篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 143篇 |
综合类 | 6篇 |
化学工业 | 701篇 |
金属工艺 | 65篇 |
机械仪表 | 39篇 |
建筑科学 | 46篇 |
矿业工程 | 1篇 |
能源动力 | 59篇 |
轻工业 | 126篇 |
水利工程 | 27篇 |
石油天然气 | 2篇 |
无线电 | 178篇 |
一般工业技术 | 322篇 |
冶金工业 | 386篇 |
原子能技术 | 58篇 |
自动化技术 | 123篇 |
出版年
2022年 | 19篇 |
2021年 | 21篇 |
2020年 | 14篇 |
2019年 | 17篇 |
2018年 | 17篇 |
2017年 | 16篇 |
2016年 | 23篇 |
2015年 | 27篇 |
2014年 | 28篇 |
2013年 | 88篇 |
2012年 | 56篇 |
2011年 | 111篇 |
2010年 | 58篇 |
2009年 | 103篇 |
2008年 | 90篇 |
2007年 | 66篇 |
2006年 | 70篇 |
2005年 | 73篇 |
2004年 | 79篇 |
2003年 | 67篇 |
2002年 | 63篇 |
2001年 | 53篇 |
2000年 | 46篇 |
1999年 | 47篇 |
1998年 | 138篇 |
1997年 | 126篇 |
1996年 | 69篇 |
1995年 | 55篇 |
1994年 | 41篇 |
1993年 | 42篇 |
1992年 | 34篇 |
1991年 | 32篇 |
1990年 | 21篇 |
1989年 | 36篇 |
1988年 | 27篇 |
1987年 | 16篇 |
1986年 | 22篇 |
1985年 | 33篇 |
1984年 | 29篇 |
1983年 | 42篇 |
1982年 | 34篇 |
1981年 | 33篇 |
1980年 | 23篇 |
1979年 | 31篇 |
1978年 | 22篇 |
1977年 | 26篇 |
1976年 | 29篇 |
1975年 | 9篇 |
1973年 | 12篇 |
1972年 | 11篇 |
排序方式: 共有2282条查询结果,搜索用时 0 毫秒
1.
Mitsuo Miyazawa Tomohiko Takahashi Kazuki Sakata Isao Horibe 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(7):1006-1011
BACKGROUND: The biotransformation of sesquiterpenoids, which are a large class of naturally occurring compounds, using microorganisms as a biocatalyst to produce useful novel organic compounds was investigated. The biotransformation of sesquiterpenoids, (+)‐aromadendrene ( 1 ), (−)‐alloaromadendrene ( 2 ) and (+)‐ledene ( 3 ) has been investigated using Aspergillus wentii as a biocatalyst. Results: Compound 1 was converted to (−)‐(10S,11S)‐10,13,14‐trihydroxyaromadendrane ( 4 ). Compound 2 was converted to (+)‐(1S,11S)‐1,13‐dihydroxyaromadendrene ( 5 ) and (−)‐5,11‐epoxycadin‐1(10)‐en‐14‐ol ( 6 ). Compound 3 was converted to compound 6 , (+)‐(10R,11S)‐10,13‐dihydroxyaromadendr‐1‐ene ( 7 ) and (+)‐(10S,11S)‐10,13‐dihydroxyaromadendr‐1‐ene ( 8 ). The structure of the metabolic products has been elucidated on the basis of their spectral data. CONCLUSION: Compound 1 gave only one product that was hydroxylated at C‐10, C‐13 and C‐14. By contrast, compounds 2 and 3 gave a number of products, one of which was common. The differences in oxidation of 1–3 are due to the configuration of the C‐1 position. Compounds 4–8 were new compounds. Copyright © 2008 Society of Chemical Industry 相似文献
2.
Norihito Kijima Kenichi Morie Shoichi Nagata Isao Shimono 《Journal of Low Temperature Physics》1996,105(5-6):1511-1516
A strontium tantalum sulfide, SrTa2S5, has a hexagonal structure with lattice constants of a =3.32 and c=24.1 Å. With decreasing temperature the electrical resistivity decreases monotonically and exhibits an abrupt superconducting transition at 3.16 K (midpoint). The diamagnetic susceptibility is observed below Tc. The magnetic susceptibility is nearly independent of temperature above Tc and shows Pauli paramagnetism. 相似文献
3.
Data fitting with a spline using a real-coded genetic algorithm 总被引:2,自引:0,他引:2
Fujiichi Yoshimoto Author Vitae Toshinobu Harada Author Vitae Author Vitae 《Computer aided design》2003,35(8):751-760
To obtain a good approximation for data fitting with a spline, frequently we have to deal with knots as variables. The problem to be solved then becomes a continuous nonlinear and multivariate optimization problem with many local optima. Therefore, it is difficult to obtain the global optimum. In this paper, we propose a method for solving this problem by using a real-coded genetic algorithm. Our method can treat not only data with a smooth underlying function, but also data with an underlying function having discontinuous points and/or cusps. We search for the best model among candidate models by using the Bayes Information Criterion (BIC). With this, we can appropriately determine the number and locations of knots automatically and simultaneously. Five examples of data fitting are given to show the performance of our method. 相似文献
4.
5.
Evaluation of Slow Crack Growth Resistance in Ceramics for High-Temperature Applications 总被引:1,自引:0,他引:1
The slow (subcritical) crack growth (SCG) resistance of Si3 N4 and SiC ceramics has been evaluated by a stepwise loading test on bending bars precracked by Vickers indentation. Three highly refractory materials were selected for the evaluation: i.e., (1) high-purity Si3 N4 sintered by hot isostatic pressing (HIP) without additives and (2,3) α - and β - SiC pressureless sintered with B and C addition. Under the hypothesis of linear elastic behavior at high temperature, which was found satisfied in the present materials, the SCG resistance was expressed in terms of initial stress intensity factor critical for SCG failure within a predetermined lifetime. The present method was found useful in shortening the testing time and consistent with other traditional fatigue tests (e.g., static-fatigue test): It is recommended as a screening test for materials under research and development. Among the materials tested in the present study, the highest SCG resistance up to 1440°C was found in the high-purity Si3 N4 without additives. 相似文献
6.
7.
Changes in the brain lactate concentration in cerebral extracellular fluid (ECF) during intravenous infusion of glucose and local administration of glucose were investigated in adult, conscious, unrestrained rats, with a microdialysis probe in the posterior hippocampus. The rats were infused intravenously with either 25% sucrose solution or 25% glucose solution at a rate of 16.6 microliters.min-1.100 g-1 for three hours. The blood glucose concentration reached 17.0 +/- 2.6 mM at the end of the glucose infusion, and brain ECF glucose showed a parallel change with the blood glucose concentration and increased to 2.37 +/- 0.30 mM. However, blood and brain ECF glucose concentrations did not change in animals infused with the sucrose solution. On the other hand, the blood lactate concentration in the glucose-infused group also increased from 0.93 +/- 0.18 mM to 2.85 +/- 0.39 mM at the end of the glucose infusion, which was significantly higher than that measured in the sucrose-infused group. The blood lactate level in the glucose-infused group returned to the basal level by the end of the experiment. Brain ECF lactate concentrations increased from 1.21 +/- 0.06 mM to 1.69 +/- 0.11 mM in glucose-infused animals, but did not change in the sucrose-infused animals. The brain ECF lactate concentration showed a positive correlation with the brain ECF glucose concentration in glucose-infused animals. Another group of rats was administered glucose locally for 90 min after substitution of artificial cerebrospinal fluid.(ABSTRACT TRUNCATED AT 250 WORDS) 相似文献
8.
9.
Analysis of characteristic odors from human male axillae 总被引:7,自引:0,他引:7
Xiao -nong Zeng James J. Leyden Henry J. Lawley Kiyohito Sawano Isao Nohara George Preti 《Journal of chemical ecology》1991,17(7):1469-1492
A number of studies concerning the analysis of axillary odors have assumed that the characteristic odor produced in the axillae is due to volatile steroids and isovaleric acid. Organoleptic evaluation of Chromatographic eluants from axillary extracts was employed to isolate the region in the chromatogram where the characteristic odor eluted. The odor of the dissolved eluant was eliminated when it was treated with base, suggesting that acids make up the characteristic axillary odor. Subsequent extraction of the pH-adjusted axillary extract in conjunction with organoleptic evaluation of the Chromatographic eluant, preparative gas chromatography, and analysis by GC-MS as well as GC-FTIR showed the presence of a number of C6 to C11 straight-chain, branched, and unsaturated acids as important contributors to the axillary odor. The major odor component is (E)-3-methyl-2-hexenoic acid. Three homologous series of minor components are also important odor contributors; these consist of the terminally unsaturated acids, the 2-methyl-C6 to -C10 acids and the 4-ethyl-C5 to -C11 acids. These types of acids have not been reported previously as components of the human axillary secretions and have not been proposed previously as part of the principal odor components in this area. 相似文献
10.
Takakazu Yamamoto Kouichi ShiraishiMahmut Abla Isao YamaguchiL.“Bert” Groenendaal 《Polymer》2002,43(3):711-719
Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C6(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C6(Ni) was soluble in organic solvents and 1H NMR data indicated that it had an Mn of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave Mn and Mw of about 1700 and 2400, respectively. PEDOTh-C6(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl3. Electrochemical oxidation of PEDOTh-C6(Ni) started at about −0.40 V vs Ag+/Ag and gave a peak at 0.20 V vs Ag+/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C6(Ni), both in solutions and in a solid state, led to weakening of the original π-π∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C6(Ni) caused not only a decrease in the intensity of 1H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm−3; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data. 相似文献