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排序方式: 共有550条查询结果,搜索用时 15 毫秒
1.
Sahar Hashemi Daryan Jafar Javadpour Alireza Khavandi Mohammad Erfan 《Ceramics International》2018,44(16):19743-19750
Well-ordered and surface engineered hierarchical hydroxyapatite microspheres (HAM) were prepared via a template free hydrothermal process. Ethylene diamine tetra (methylene phosphonic acid) (EDTMP) was used as chelating or regulating agent for the first time in this study. The results indicated the formation of sheet-like particles in the absence of EDTMP. On the other hand, microspheres with radially grown nanorods (HAMNR) or nanosheets (HAMNS) on the surface were obtained (with average diameter of 5?µm) in the presence of EDTMP. X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy were used to characterize the crystalline phases in the synthesized samples. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) showed that EDTMP concentration played an important part in regulating the morphology to form well organized microspheres with nanosheets or nanorods on the surface. Brunauer-Emmett-Teller (BET) revealed an increase in the specific surface area with the change in morphology from the HAMNS to HAMNR. Possible mechanisms are proposed to account for the formation of different morphologies based upon thermodynamic and kinetic theories. 相似文献
2.
Novel polyurethane insulating coatings were prepared from the reaction of glycerin‐terminated polyurethane prepolymers (GPUPs) and a blocked isocyanate curing agent (BIC). The GPUPs were prepared from the reaction of one equivalent of polycaprolactone polyol (CAPA 210) with an excess amount of 4,4′‐methylene bis(phenyl isocyanate) (MDI) and subsequent reaction of the NCO‐terminated polyurethane with glycerin. The BIC was prepared from the reaction of trimethylol propane (TMP), toluene diisocyanate (TDI) and N‐methylaniline (NMA). The polyols and curing agent were characterized by conventional methods while the curing condition was optimized via gel content measurements. The curing kinetics of the polyurethane coating were investigated and the kinetic parameters derived. The crosslink densities of the samples were determined via the equilibrium swelling method, using the Flory–Rehner equation. The relationships between the crosslink density and the electrical, physical, mechanical and dynamic mechanical properties of the coatings were also studied. Copyright © 2005 Society of Chemical Industry 相似文献
3.
Yu.V. Butenko P.R. Coxon M. Yeganeh A.C. Brieva K. Liddell V.R. Dhanak L. iller 《Diamond and Related Materials》2008,17(6):962-966
It is generally accepted that diamond is resistant to a wide spectrum of electromagnetic radiation from the ultraviolet through to the soft X-ray range, which makes it very attractive for the fabrication of diamond-based photodetectors. However the effect of photon radiation on the diamond structure has not yet been examined. In the work presented here, photoelectron spectroscopy has been used to study the graphitization of nanodiamond crystallites exposed to extreme ultraviolet radiation. Under such irradiation, the surface hydrogen groups and graphite species are found to prevent graphitization. The mechanism of radiation-induced nanodiamond graphitization is discussed. 相似文献
4.
Khaled Chahine Mark Ballico John Reizes Jafar Madadnia 《International Journal of Thermophysics》2007,28(6):2118-2127
A simple quasi-2D model for the temperature distribution in a graphite tube furnace is presented. The model is used to estimate
the temperature gradients in the furnace at temperatures above which contact sensors can be used, and to assist in the redesign
of the furnace heater element to improve the temperature gradients. The Thermogage graphite tube furnace is commonly used
in many NMIs as a blackbody source for radiation thermometer calibration and as a spectral irradiance standard. Although the
design is robust, easy to operate and can change temperature rapidly, it is limited by its effective emissivity of typically
99.5–99.8%. At NMIA, the temperature gradient along the tube is assessed using thermocouples up to about 1,500°C, and the
blackbody emissivity is calculated from this. However, at higher operating temperatures (up to 2,900°C), it is impractical
to measure the gradient, and we propose to numerically model the temperature distributions used to calculate emissivity. In
another paper at this conference, the model is used to design an optimized heater tube with improved temperature gradients.
In the model presented here, the 2-D temperature distribution is simplified to separate the axial and radial temperature distributions
within the heater tube and the surrounding insulation. Literature data for the temperature dependence of the electrical and
thermal conductivities of the graphite tube were coupled to models for the thermal conductivity of the felt insulation, particularly
including the effects of allowing for a gas mixture in the insulation. Experimental measurements of the temperature profile
up to 1,500°C and radial heat fluxes up to 2,200°C were compared to the theoretical predictions of the model and good agreement
was obtained. 相似文献
5.
In this article, we consider the project critical path problem in an environment with hybrid uncertainty. In this environment, the duration of activities are considered as random fuzzy variables that have probability and fuzzy natures, simultaneously. To obtain a robust critical path with this kind of uncertainty a chance constraints programming model is used. This model is converted to a deterministic model in two stages. In the first stage, the uncertain model is converted to a model with interval parameters by alpha-cut method and distribution function concepts. In the second stage, the interval model is converted to a deterministic model by robust optimization and min-max regret criterion and ultimately a genetic algorithm with a proposed exact algorithm are applied to solve the final model. Finally, some numerical examples are given to show the efficiency of the solution procedure. 相似文献
6.
Ali Kargar nigje Esmaeil Salimi Mohammad Jafar Molaei Mojtaba Ghatee 《International Journal of Applied Ceramic Technology》2021,18(6):1921-1929
This study reported the synthesis of fluorescent hydroxyapatite/alginate/carbon quantum dots (HA/Alg/CQDs) nanocomposites via the co-precipitation technique. The N-doped CQDs as a new class of fluorescent materials were prepared by the citric acid pyrolysis method, with an average size around 4 nm. Physical, chemical, and optical properties of the synthesized nanocomposites were investigated by X-ray diffraction (XRD), Fourier-transformed infrared spectroscopy (FTIR), atomic force microscopy (AFM), field-emission scanning electron microscopy (FESEM), UV–visible spectroscopy, and photoluminescence (PL) spectroscopy, respectively. The PL spectroscopy data verified the favorable in vitro luminescent emission of the HA/Alg/CQDs nanocomposites in comparison with HA/Alg and HA samples. The XRD patterns of the prepared samples confirmed the formation of crystalline HA in all composites, possessing a Ca/P ratio around 1.5 as obtained by EDX elemental analysis. The FESEM analysis exhibited HA nanoplates that homogeneously distributed throughout the alginate matrix. Therefore, the synthesized nanocomposites could be regarded as potential trackable drug carriers for hard tissue engineering applications. 相似文献
7.
Bagher Heidarpour Bahram Saghafian Jafar Yazdi Hazi Mohammad Azamathulla 《Water Resources Management》2017,31(13):4187-4205
The peak flow of extraordinary large floods that occur during a period of systematic record is a controversial problem for flood frequency analysis (FFA) using traditional methods. The present study suggests that such floods be treated as historic flood data even though their historical period is unknown. In this paper, the extraordinary large flood peak was first identified using statistical outlier tests and normal probability plots. FFA was then applied with and without the extraordinary large floods. In this step, two goodness-of-fit tests including mean absolute relative deviation and mean squared relative deviation were used to identify the best-fit probability distributions. Next, the generalized extreme value (GEV), three-parameter lognormal (LN3), log-Pearson type III (LP3), and Wakeby (WAK) probability distributions were used to incorporate and adjust the extraordinary large floods with other systematic data. Finally, procedures with and without historical adjustment were compared for the extraordinary large floods in terms of goodness-of-fit and flood return-period quantiles. The results of this comparison indicate that historical adjustment from an operational perspective was more viable than without adjustment procedure. Furthermore, the results without adjustment were unreasonable (subject to over- and under-estimation) and produced physically unrealistic estimates that were not compatible with the study area. The proposed approach substantially improved the probability estimation of rare floods for efficient design of hydraulic structures, risk analysis, and floodplain management. 相似文献
8.
High purity multi-walled carbon nanotubes were synthesized from aromatic hydrocarbons (benzene, toluene, xylene and trimethyl benzene) using ferrocene as the source of Fe catalyst. Screening studies of aromatic feeds at 675 °C, residence time of 14 s and Fe/C atom ratio of 1.07%, resulted in feedstock carbon conversion of 20-31%, CNT yield of 19.8-30.5%, and catalyst yield of 5.3-8.3 (g CNT/g catalyst). While the quality of the CNTs as determined by TGA, SEM, TEM and Raman spectroscopy, were high and comparable for different feedstocks; their carbon conversion, CNT yield and catalyst yield differed noticeably. A process optimization study for toluene feed showed that carbon conversion of more than 39%, CNT yield of 38.7% and catalyst yield of 18.3 can be achieved at temperature of 800 °C, Fe/C atom ratio of 0.47%, and residence time of 10-20 s. 相似文献
9.
Robust Unknown Input Observer Design for Linear Uncertain Time Delay Systems with Application to Fault Detection 下载免费PDF全文
In this paper, a novel approach is proposed to design a robust fault detection observer for uncertain linear time delay systems. The system is composed of both norm‐bounded uncertainties and exogenous signals (noise, disturbance, and fault) which are considered to be unknown. The main contribution of this paper is to present unknown input observer (UIO)‐based fault detection system which shows the maximum sensitivity to fault signals and the minimum sensitivity to other signals. Since the system contains uncertainty terms, an H∞ model‐matching approach is used in design procedure. The reference residual signal generator system is designed so that the fault signal has maximum sensitivity while the exogenous signals have minimum sensitivity on the residual signal. Then, the fault detection system is designed by minimizing the estimation error between the reference residual signal and the UIO residual signal in the sense of H∞ norm. A sufficient condition for the existence of such a filter is exploited in terms of certain linear matrix inequalities (LMIs). Application of the proposed method in a numerical example and an engineering process are simulated to demonstrate the effectiveness of the proposed algorithm. Simulation results show the validity of the proposed approach to detect the occurrence of faults in the presence of modeling errors, disturbances, and noise. 相似文献
10.
Mohammad Mizanur Rahman Md. Hasan Zahir Md. Eyasin Arafat Mohammad Abu Jafar Mazumder Rami Suleiman A. Madhan Kumar 《应用聚合物科学杂志》2021,138(9):49904
A waste material called oil fly ash (OFA) was acid-functionalized, yielding f-OFA-COOH, which was then reacted with cerium oxide (CeO2) to make CeO2-functionalized OFA, or f-OFA-CeO2. Pristine OFA and f-OFA-CeO2 were used to make waterborne polyurethane (WBPU) dispersions, referred to as WBPU/OFA and WBPU/f-OFA-CeO2, respectively, with defined OFA and f-OFA-CeO2 content. All the dispersions were applied to mild steel as organic coatings to evaluate their protective properties, such as their hydrophobicity, adhesive strength and UV-shielding resistance. These protective properties varied based on the OFA and f-OFA-CeO2 content. The highest water contact angle, minimum water swelling and maximum adhesive strength were found using WBPU/f-OFA-CeO2-20 coating (using 2.00 wt% f-OFA-CeO2), which also showed the maximum ultraviolet (UV) absorption via UV–vis spectroscopy analysis. This UV shielding result also matched field test results, as that coating was found to exhibit the lowest UV degradation near a marine atmosphere, as shown by X-ray photoelectron spectroscopy (XPS) analysis. The least affected hydrophobicity was also recorded for the sample with the WBPU/f-OFA-CeO2-20 coating. 相似文献