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1.
Osmotic pressure measurements were satisfactorily used to compute the effective charge of poly(acrylic) acid (PAA) at different pHs and with different monovalent and divalent counterions. This experimental method is sensitive to the osmotically active species (polymer and counterions). After correction for the polymer contribution to the total osmotic pressure (solvency and excluded volume), the remaining pressure can be attributed to the polyelectrolyte counterions and processed with Donnan and equation of state in order to compute the effective charge number per polymeric chain (Zeff). The behavior of Zeff against the chain concentration and pH was investigated after neutralization of PAA with LiOH, NaOH, and TMAOH. The results clearly indicate that the nature of the monovalent counterion has no effect on Zeff leading to the conclusion that the interaction between monovalent counterions and the acrylate functionality is purely electrostatic in agreement with conductimetric and potentiometric results reported in the literature. The behavior of Zeff against the degree of ionization of the polymer and its concentration is also in good agreement with the theoretical expectations of the theory of ionic condensation. Osmotic measurements were also used in order to understand the influence of divalent cations (Mg2+, Ca2+, Ba2+) on Zeff of the sodium salt of PAA at pH 9 and at different divalent/acrylate molar ratio. All the divalent cations depress Zeff each of one at different degrees, confirming a specific divalent/polymer interaction. The energy of hydration of cations can explain most of the observed results with divalents. 相似文献
2.
Castonguay Louis G.; Schut Alexander J.; Aikens Deane E.; Constantino Michael J.; Laurenceau Jean-Philippe; Bologh Laura; Burns David D. 《Canadian Metallurgical Quarterly》2004,14(1):4
This study is a preliminary investigation of an integrative treatment aimed at improving the efficacy of cognitive therapy (CT) for depression. The development of the treatment protocol was based on process findings, which suggested that strategies used in CT to resolve alliance ruptures may actually exacerbate problems in the therapeutic relationship. The protocol integrates, within the traditional CT treatment manual, procedures to repair alliance ruptures that are derived from or consistent with humanistic and interpersonal therapies. Although conducted by inexperienced therapists, the integrative treatment led to greater improvement than a waiting-list condition. The results also compare favorably to previous findings for CT. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
3.
Sabri Boughorbel Jean-Philippe Tarel Fran?ois Fleuret Nozha Boujemaa 《The Journal of supercomputing》1988,2(4):449-450
Contributing authors 相似文献
4.
BACKGROUND AND AIMS: Outcome refers to the different facets of consequences resulting from an event or intervention. These consequences may be relevant for an individual patient, but also for society. There is a growing recognition that clinical research needs to define and focus on the outcomes of medical care. Outcome research should help health care professionals to better evaluate the effectiveness of specific interventions or a therapeutic concept. This broader base of evidence should then benefit the patients. METHODS: The literature was reviewed with respect to concepts of outcome research as well as results of outcome research after major trauma. RESULTS: Measuring outcome might be relevant for research purposes as well as in daily surgical practice. In the past, clinical research in trauma care has tended to focus on survival. Mortality rates are not out, complication rates are not out, but their value is limited and restricted to given scenarios with high mortality rates. New outcomes have to be added: such a functional status, emotional health, social interaction, cognitive function, degree of disability and other indicators of health. CONCLUSION: Despite differences in injury pattern and severity of injury, there is strong evidence from the literature that the quality of life is significantly impaired after major trauma. This is true for functional outcome as well as for psycho-social outcome in up to 70% of patients. 相似文献
5.
The ever-increasing amount of solid waste generated by wastewater treatment plants highlights emerging economic and environmental issues. In order to develop new processes producing less sludge, the use of ozone combined with anaerobic digestion was investigated for waste activated sludge treatment. This paper was aimed at evaluating the impact of ozone pretreatment on anaerobic digestion and particularly the enhancement of biogas production. Sludge solubilization was estimated in terms of modification of chemical oxygen demand, solids and nitrogen. Batch anaerobic digestion highlighted the enhancement of ozonated sludge biodegradability. Ozonation led to an increase in biogas production. The ozone dose of 0.15 g O3/g total solids resulted in a considerable increase in the soluble COD ratio from 4% to 37%. This ozone dose achieved the highest increase in biogas production: 2.4 times greater than without chemical pretreatment. 相似文献
6.
We have fabricated and characterized an n-doped InSb Faraday isolator in the mid-IR range (9.2 μm). A high isolation ratio (31(2) dB) and low insertion loss (1.9(3) dB) are obtained. Temperature dependance is analyzed. Further possible improvements are discussed, including the realization of a two-stage isolator. A similar design can be used to cover a wide wavelength range (λ ~ 7.5-30 μm). 相似文献
7.
Liu S Kang K Tarel JP Cooper DB 《IEEE transactions on pattern analysis and machine intelligence》2008,30(1):131-146
In this paper, the duality in differential form is developed between a 3D primal surface and its dual manifold formed by the surface's tangent planes, i.e., each tangent plane of the primal surface is represented as a four-dimensional vector which constitutes a point on the dual manifold. The iterated dual theorem shows that each tangent plane of the dual manifold corresponds to a point on the original 3D surface, i.e., the dual of the dual goes back to the primal. This theorem can be directly used to reconstruct 3D surface from image edges by estimating the dual manifold from these edges. In this paper we further develop the work in our original conference papers resulting in the robust differential dual operator. We argue that the operator makes good use of the information available in the image data, by using both points of intensity discontinuity and their edge directions; we provide a simple physical interpretation of what the abstract algorithm is actually estimating and why it makes sense in terms of estimation accuracy; our algorithm operates on all edges in the images, including silhouette edges, self occlusion edges, and texture edges, without distinguishing their types (thus resulting in improved accuracy and handling locally concave surface estimation if texture edges are present); the algorithm automatically handles various degeneracies; and the algorithm incorporates new methodologies for implementing the required operations such as appropriately relating edges in pairs of images, evaluating and using the algorithm's sensitivity to noise to determine the accuracy of an estimated 3D point. Experiments with both synthetic and real images demonstrate that the operator is accurate, robust to degeneracies and noise, and general for reconstructing free-form objects from occluding edges and texture edges detected in calibrated images or video sequences. 相似文献
8.
Partial 3D Shape Retrieval by Reeb Pattern Unfolding 总被引:2,自引:0,他引:2
This paper presents a novel approach for fast and efficient partial shape retrieval on a collection of 3D shapes. Each shape is represented by a Reeb graph associated with geometrical signatures. Partial similarity between two shapes is evaluated by computing a variant of their maximum common sub-graph.
By investigating Reeb graph theory, we take advantage of its intrinsic properties at two levels. First, we show that the segmentation of a shape by a Reeb graph provides charts with disk or annulus topology only. This topology control enables the computation of concise and efficient sub-part geometrical signatures based on parameterisation techniques. Secondly, we introduce the notion of Reeb pattern on a Reeb graph along with its structural signature. We show this information discards Reeb graph structural distortion and still depicts the topology of the related sub-parts. The number of combinations to evaluate in the matching process is then dramatically reduced by only considering the combinations of topology equivalent Reeb patterns.
The proposed framework is invariant against rigid transformations and robust against non-rigid transformations and surface noise. It queries the collection in interactive time (from 4 to 30 seconds for the largest queries). It outperforms the competing methods of the SHREC 2007 contest in term of NDCG vector and provides, respectively, a gain of 14.1% and 40.9% on the approaches by Biasotti et al. [ BMSF06 ] and Cornea et al. [ CDS*05 ].
As an application, we present an intelligent modelling-by-example system which enables a novice user to rapidly create new 3D shapes by composing shapes of a collection having similar sub-parts. 相似文献
By investigating Reeb graph theory, we take advantage of its intrinsic properties at two levels. First, we show that the segmentation of a shape by a Reeb graph provides charts with disk or annulus topology only. This topology control enables the computation of concise and efficient sub-part geometrical signatures based on parameterisation techniques. Secondly, we introduce the notion of Reeb pattern on a Reeb graph along with its structural signature. We show this information discards Reeb graph structural distortion and still depicts the topology of the related sub-parts. The number of combinations to evaluate in the matching process is then dramatically reduced by only considering the combinations of topology equivalent Reeb patterns.
The proposed framework is invariant against rigid transformations and robust against non-rigid transformations and surface noise. It queries the collection in interactive time (from 4 to 30 seconds for the largest queries). It outperforms the competing methods of the SHREC 2007 contest in term of NDCG vector and provides, respectively, a gain of 14.1% and 40.9% on the approaches by Biasotti et al. [ BMSF06 ] and Cornea et al. [ CDS*05 ].
As an application, we present an intelligent modelling-by-example system which enables a novice user to rapidly create new 3D shapes by composing shapes of a collection having similar sub-parts. 相似文献
9.
10.
Belhadj S Derridj A Aigouy T Gers C Gauquelin T Mevy JP 《Microscopy research and technique》2007,70(10):837-846
A comparative analysis was undertaken to conduct a micromorphological study of Pistacia atlantica leaves by comparing different populations grown under different climatic conditions. Leaf epidermis of eight wild populations was investigated under scanning electron microscope. Micromorphological characteristics (epidermis ornament, stomata type, waxes as well as trichomes) of the adaxial and abaxial leaf surfaces were examined. The epidermis ornament varied among populations and leaf surface, the abaxial leaf surface is reticulate with a striate surface. Messaad site shows a smooth uneven surface. The adaxial leaf surface is smooth but several ornamentations can be seen. The leaflet is amphistomatic; the stomata appeared to be slightly sunken. A variety of stomatal types were recorded; actinocytic and anomocytic types are the most frequent. The indumentum consisted of glandular and nonglandular trichomes. Unicellular glandular trichomes are recorded for P. atlantica leaves in this study. Their density is higher in Oued safene site, located at the highest altitude in comparison with the other populations. The wax occurred in all the sites and its pattern varied according to the populations studied, particularly between Berriane and Messaad. The morphological variability exhibited by the eight populations of P. atlantica may be interpreted as relevant to the ecological plasticity and the physiological mechanisms involved are discussed in this report. 相似文献