Synthesis and thermal properties of polyamide 6 (A)-polyimide (B) block copolymers of ABA type

Summary Polyimides (PI) having different molecular weights were prepared by condensation of oxydiphthalic anhydride with 9,9-bis-(4-aminophenyl)fluorene in nitrobenzene solution at 180°C. These polyimides carried two amino chain ends which allowed us to fix polycaprolactam chains (PA6) to obtain PA6-PI-PA6 type copolymers. The elemental analysis and infrared spectroscopic determination gave the proportion of PA6 (or PI) in the copolymers. The studies of thermal properties-DSC and TGA-allowed us to characterize the copolymers.     

A prototype of a superconducting magnet for a 170-GHz gyrotron

Within the framework of the “International Thermonuclear Experimental Reactor” (ITER) program, a prototype of a superconducting magnet for a 170-GHz gyrotron has been developed, manufactured, and tested. The operating induction value (7.1 T at the center of a 219-mm-diameter cold hole and 8.1 T on the winding) is reached at a current of 185.2 A. In the final version of the magnet, the required induction value was reached without aging. Special requirements are imposed on the distribution of the magnetic field along the axis, including an abrupt field decrease on both sides of the magnet. Axial forces are additionally taken by a special device. The magnet’s sections are wound with multifiber conductors based on niobium-tin and niobium-titanium alloys. Seventeen resistive shunts are provided for protecting sections during their transition to the normal state. The magnet is equipped with a device for removing a part of energy from the sections. Mechanical stresses in the magnet’s sections and the structure’s power elements have been measured during tests.     

An H∞non‐fragile observer‐based adaptive sliding mode controller design for uncertain fractional‐order nonlinear systems with time delay and input nonlinearity

In this paper the problem of non‐fragile adaptive sliding mode observer design is addressed for a class of nonlinear fractional‐order time‐delay systems with uncertainties, external disturbance, exogenous noise, and input nonlinearity. An H_∞ observer‐based adaptive sliding mode control considering the non‐fragility of the observer is proposed for this system. The sufficient asymptotic stability conditions are derived in the form of linear matrix inequalities. It is proven that the sliding surface is reachable in finite time. An illustrative example is provided which corroborates the effectiveness of the theoretical results.     

Model updating of multistory shear buildings for simultaneous identification of mass,stiffness and damping matrices using two different soft-computing methods

In this research, two novel methods for simultaneous identification of mass–damping–stiffness of shear buildings are proposed. The first method presents a procedure to estimate the natural frequencies, modal damping ratios, and modal shapes of shear buildings from their forced vibration responses. To estimate the coefficient matrices of a state-space model, an auto-regressive exogenous excitation (ARX) model cooperating with a neural network concept is employed. The modal parameters of the structure are then evaluated from the eigenparameters of the coefficient matrix of the model. Finally, modal parameters are used to identify the physical/structural (i.e., mass, damping, and stiffness) matrices of the structure. In the second method, a direct strategy of physical/structural identification is developed from the dynamic responses of the structure without any eigenvalue analysis or optimization processes that are usually necessary in inverse problems. This method modifies the governing equations of motion based on relative responses of consecutive stories such that the new set of equations can be implemented in a cluster of artificial neural networks. The number of neural networks is equal to the number of degree-of-freedom of the structure. It is shown the noise effects may partially be eliminated by using high-order finite impulse response (FIR) filters in both methods. Finally, the feasibility and accuracy of the presented model updating methods are examined through numerical studies on multistory shear buildings using the simulated records with various noise levels. The excellent agreement of the obtained results with those of the finite element models shows the feasibility of the proposed methods.     

Network Formation: Bilateral Contracting and Myopic Dynamics

We consider a network formation game where nodes wish to send traffic to each other. Nodes contract bilaterally with each other to form bidirectional communication links; once the network is formed, traffic is routed along shortest paths (if possible). Cost is incurred to a node from four sources: 1) routing traffic; 2) maintaining links to other nodes; 3) disconnection from destinations the node wishes to reach; and 4) payments made to other nodes. We assume that a network is stable if no single node wishes to unilaterally deviate, and no pair of nodes can profitably deviate together (a variation on the notion of pairwise stability). We study such a game under a form of myopic best response dynamics. In choosing their action, nodes optimize their single period payoff only. We characterize a simple set of assumptions under which these dynamics converge to a stable network; we also characterize an important special case, where the dynamics converge to a star centered at a node with minimum cost for routing traffic. In this sense, our dynamics naturally select an efficient equilibrium.     

Preparation of a sensor substrate using functionalized mesoporous silica on a gold film for surface plasmon resonance (SPR) spectroscopy

The use of surface plasmon resonance (SPR) spectroscopy has been applied to a wide variety of fields such as biosensors and surface analysis instruments. In general, a SPR substrate is prepared using self-assembled monolayer (SAM) method of organic molecules as receptor for the target on a layer of gold or silver. However, mesoporous inorganic materials such as SBA-15 have benefits as sensor substrate for SPR. Mesoporous silica has a large surface area which receptor molecule can be attached and has a rigid body which has an excellent stability in the extreme condition compared to organic sensing layer. We prepared an organic modified mesoporous silica and successfully immobilized it on a gold surface, in an attempt to use as a substrate for SPR spectroscopy. For the comparison of sensitivity of prepared substrate, Pt²⁺ detection was selected as a model system. Substrate prepared in this study exhibited the capability of selective sensing for Pt²⁺ ions.     

Development and research of MIS varicaps with charge transfer

A new type of a double-electrode MIS varicap with a carrier transfer has been proposed. It is shown that in a device of this type, there are no negative effects associated with the processes of thermal generation and accumulation of minority carriers. This makes it possible to increase the limiting frequency and improve the temperature stability of varicap operation. Two designs of the device are considered. The characteristics of the varicaps that were measured experimentally agree with the results of the calculations.     

Synthesis and Characterization of Novel Sulfur-Functionalized Silica Gels as Mercury Adsorbents

This paper describes the synthesis, functionalization, and characterization of silica gels as mercury adsorbents. The synthesis was carried out according to the modified Stöber method using tetraethyl orthosilicate [TEOS], 3-mercaptopropyl trimethoxysilane [MPTMS] and bis(triethoxysilylpropyl) tetrasulfide [BTEPST] as precursors. The functionalization was carried out via co-condensation and impregnation methods using MPTMS, BTESPT, elemental sulfur [ES], and carbon disulfide [CS₂] as sulfur ligands. The choice of the sulfur ligands as precursors and functionalization agents was due to the existence of sulfur active groups in their molecular structures which were expected to have high affinity toward Hg(II) ions. The synthesized adsorbents were characterized by using scanning electron microscope, fourier transform infrared spectrophotometer, nitrogen adsorption/desorption, and energy dispersive X-ray diffractometer. The batch Hg(II) adsorption experiments were employed to evaluate the Hg(II) adsorption performances of the synthesized adsorbents under different pH values. The results revealed that the highest Hg(II) adsorption capacity was obtained for the SG-MPTMS(10) which was 47.83 mg/g at pH 8.5. In general, the existence of sulfur functional groups, especially MPTMS in the silica matrices, gave a significant enhancement of Hg(II) adsorption capacity and the sulfur functionalization via co-condensation method, which is potential as a superior approach in the mercury adsorbent synthesis.