Methacrylate-functionalized POSS influence on cross-linking and mechanical properties of styrene-butadiene rubber

Iranian Polymer Journal - The addition of methacrylate-functional polyhedral oligomeric silsesquioxane (MA-POSS) nanoparticles to styrene-butadiene rubber (SBR) composites was evaluated in terms of...     

Modeling of Step Voltage Regulators in Multiphase Load Flow Solution of Distribution Systems Using Newton's Method and Augmented Nodal Analysis

The increasing complexity of distribution systems requires general, efficient, and large-scale capable methods. This paper proposes a new technique to find the tap positions of step voltage regulators in multiphase load flow solvers in a direct and efficient manner. This is achieved by applying Newton method to the system of equations obtained by using the concept of augmented matrix formulation and adding the constraint equations. This approach allows employing the regulator equations directly. The regulators are modeled by taking into account the line drop compensator circuit with its settings, i.e., the desired voltage level, bandwidth, and R′ and X′ settings, which represent the scaled impedance parameters of the distribution feeder between the regulator and the load center at which the voltage is controlled. The limits of the regulators such as minimum and maximum tap positions are also accounted for. The proposed technique represents a voltage regulator with transformer equations using an augmented matrix formulation. The mismatch equations are developed using the desired voltage setting in constraint equations with transformation ratio of the transformer being the unknown variable. The Jacobian matrix, which is constructed using the augmented matrix formulation, is expanded to hold the constraint equations of voltage regulators. The proposed new method is tested on a variety of test circuits including the large-scale IEEE 8500 Node Test Feeder, and the minimum number of iterations reported in the literature is achieved as presented in this paper.     

Characterizations of Iron Particles Reduced from Iron Oxide Nanoparticles Under Hydrogen Atmosphere

Submicron iron particles were obtained by the reduction of co-precipitated superparamagnetic iron oxide nanoparticles under hydrogen atmosphere. The reduction was carried out at the temperatures ranging from 200 to 1000 °C. The magnetic properties were investigated in accordance with the structural properties. According to the X-ray diffraction patterns, the increase of crystallization was followed by the conversion from iron oxide to iron and also the particle size increased as the reduction temperature increased. Morphology observed by transmission electron microscope showed that the particles were individually seen at low temperatures; however, they stacked together and became larger at high temperatures. Magnetic measurements with a vibrating sample magnetometer disclosed that the saturation magnetization steadily increased with increasing temperature and almost stabilized at 800 °C. Highest saturation magnetization obtained by the reduction process is ～211 emu/g, which is close to that of bulk iron. It is disclosed that, at all temperatures, saturation magnetizations obtained from magnetic measurements were found to be compatible with the structural changes caused by reduction temperature.     

The effect of Fe content in electrodeposited CoFe/Cu multilayers on structural, magnetic and magnetoresistance characterizations

A series of CoFe/Cu multilayers were electrodeposited on Ti substrates from the electrolytes containing their metal ion under potentiostatic control, but the Fe concentration in the electrolytes was changed from 0.0125 M to 0.2 M. The deposition was carried out in a three-electrode cell at room temperature. The deposition of Cu layers was made at a cathode potential of -0.3 V with respect to saturated calomel electrode (SCE), while the ferromagnetic CoFe layers were deposited at -1.5 V versus SCE. The structural studies by X-ray diffraction revealed that the multilayers have face-centered-cubic structure. The magnetic characteristics of the films were investigated using a vibrating sample magnetometer and their easy-axis was found to be in film plane. Magnetoresistance measurements were carried out using the Van der Pauw method at room temperature with magnetic fields up to +/- 12 kOe. All multilayers exhibited giant magnetoresistance (GMR) and the GMR values up to 8% were obtained.     

Fracture and fatigue analysis of an agitator shaft with a circumferential notch

This paper is concerned with the fracture analysis of an agitator shaft of a large vessel and predicting its high cycle fatigue life. The agitator shaft has a circumferential notch around it and is subjected to remote bending and torque created by the mixing operation. The problem is comprised (i) the analyses of the bending force and torque acting on the agitator by using the analytical method, (ii) calculation of stress intensity factors under mode I and III loading conditions by using finite element method and, (iii) fatigue analysis of the agitator shaft failed in service.An agitator model is set up and data obtained from the agitator are processed to make more realistic approximations for bending forces, since they form a base for stress analysis, in which mode I stress intensity factors are evaluated. Mode I stress intensity factors obtained by finite element analysis are compared with the results provided by using the body force method.     

Deposition of AgGaS<Subscript>2</Subscript> thin films by double source thermal evaporation technique

In this study, polycrystalline AgGaS₂ thin films were deposited by the sequential evaporation of AgGaS₂ and Ag sources with thermal evaporation technique. Thermal treatment in nitrogen atmosphere for 5 min up to 700 °C was applied to the deposited thin films and that resulted in the mono phase AgGaS₂ thin films without the participation of any other minor phase. Structural and compositional analyses showed the structure of the films completely changes with annealing process. The measurements of transmittance and reflectance allowed us to calculate the band gap of films lying in 2.65 and 2.79 eV depending on annealing temperature. The changes in the structure with annealing process also modify the electrical properties of the films. The resistivity of the samples varied in between 2 × 10³ and 9 × 10⁶ (Ω-cm). The room temperature mobility depending on the increasing annealing temperature was in the range of 6.7–37 (cm² V⁻¹ s⁻¹) with the changes in carrier concentrations lying in 5.7 × 10¹³–2.5 × 10¹⁰ cm⁻³. Mobility-temperature dependence was also analyzed to determine the scattering mechanisms in the studied temperature range with annealing. The variations in the electrical parameters of the films were discussed in terms of their structural changes.     

Structural, optical and electrical properties of N-doped ZnO thin films prepared by thermal oxidation of pulsed filtered cathodic vacuum arc deposited ZnxNy films

In this study, N-doped ZnO thin films were fabricated by oxidation of Zn_xN_y films. The Zn_xN_y thin films were deposited on glass substrates by pulsed filtered cathodic vacuum arc deposition (PFCVAD) using metallic zinc wire (99.999%) as a cathode target in pure nitrogen plasma. The influence of oxidation temperature, on the electrical, structural and optical properties of N-doped ZnO films was investigated. P-type conduction was achieved for the N-doped ZnO obtained at 450 °C by oxidation of Zn_xN_y, with a resistivity of 16.1 Ω cm, hole concentration of 2.03 × 10¹⁶ cm⁻³ and Hall mobility of 19 cm²/V s. X-ray photoelectron spectroscopy (XPS) analysis confirmed the incorporation of N into the ZnO films. X-ray diffraction (XRD) pattern showed that the films as-deposited and oxidized at 350 °C were amorphous. However, the oxidized films in air atmosphere at 450-550 °C were polycrystalline without preferential orientation. In room temperature photoluminescence (PL) spectra, an ultraviolet (UV) peak was seen for all the samples. In addition, a broad deep level emission was observed.     

Hemodialysis for an unusual occurrence of leptospirosis in a nonendemic region

Leptospirosis, an endemic zoonotic disease caused by Leptospira, is frequently seen in tropical regions and areas with low socioeconomic status. The disease can present a range of symptoms from mild to fatal, with potential involvement of multiple organs. This case report describes the treatment and clinical course of a 44-year-old male patient infected with Leptospira semeranga patoc 1 and presenting with jaundice and renal failure. The patient was residing in the Syrian Refugee Camp in the arid city of Sanliurfa. This case serves as an example of a nonendemic occurrence of leptospirosis, and a brief overview of relevant literature on the subject is also provided.     

Effect of Synthesis Parameters on the Properties of Superparamagnetic Iron Oxide Nanoparticles

Iron oxide nanoparticles were coprecipitated in air medium using different sodium hydroxide (NaOH) concentrations, and their structural and magnetic properties were studied. It was observed that the precipitation of superparamagnetic iron oxide nanoparticles could be achieved above a critical NaOH concentration. This was followed by the investigation of the effect of the stirring rate on the structural and magnetic properties of the nanoparticles precipitated at 8.5?M NaOH and over. Morphological observation made by a transmission electron microscope (TEM) showed that the particle size of iron oxide nanoparticles was around 7.5?nm. Magnetization curves measured by a vibrating sample magnetometer showed zero coercivity indicating that the samples are superparamagnetic and the highest saturation magnetization (70.4?emu/g) was obtained at the stirring rate of 1100?rpm. The mean particle sizes of iron oxide nanoparticles calculated from the magnetization data are found to be consistent with the particle sizes obtained from the TEM images.