Predicting the performance of concrete structures exposed to chemically aggressive environment—Field validation

The behavior of two series of concrete slabs exposed to sulfate-bearing soils was investigated by a numerical model called STADIUM. In addition to the diffusion of ions and moisture, the model also accounts for the effects of dissolution/precipitation reactions on the transport mechanisms. The simulations yielded by the model were compared to the actual degradation of the slabs after 8 years of exposure. The microstructural alterations of concrete resulting from the penetration of magnesium, chloride and sulfate ions were studied by backscatter mode scanning electron microscope observations and energy-dispersive X-ray analyses. The comparison of both series of data indicates that the model can reliably predict the various features of the microstructural alterations of concrete.

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Résumé Le comportement de deux séries de dalles sur sol en béton exposées à des sols chimiquement agressifs a été étudié à l'aide d'un code de calcul numérique appelé STADIUM. Ce modèle permet de décrire le transport couplé de l'eau et des ions dans des matériaux poreux non-saturés en prenant en considération l'influence des réactions chimiques. Les résultats des simultations de la dégradation du béton après huit ans d'exposition à des ions chlore, sulfate et magnésium. Les observations ont été réalisées par microscopie électronique à balayage. Des analyses par dispersion des rayons X ont également été effectuées. Les données démontrent clairement que le modèle perment de prédire avec précision le comportement du béton soumis à différents types d'agression chimique.

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Editorial Note Laval University (Canada) is a RILEM Titular Member. Prof. J. Marchand was awarded the 2000 Robert L'Hermite Medal. He is Editor in Chief for Concrete Science and Engineering and Associate Editor for Materials and Structures. He participates in RILEM TC 186-ISA ‘Internal Sulfate attack’.     

A Profile of Psychologists' Views of Critical Risk Factors for Completed Suicide in Older Adults.

The ability to accurately and reliably predict whether an older adult will commit suicide has eluded clinicians and researchers. A random national sample of psychologists who work with older adults was surveyed regarding their perception of 36 risk factors for completed suicide and indirect self-destructive behavior in older adults. This study produced a profile of psychologists' assessment and treatment practices when working with suicidal older adults. Determining what psychologists consider to be the most salient risk factors for completed suicide is important in identifying a minimum standard that clinicians should follow when assessing older adults. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Introduction to the special series: HIV infection among drug abusers.

Drug users are particularly at risk for contracting the human immunodeficiency virus and serve as a major mechanism for spreading the virus to other sectors of the population. As a result drug abuse treatment and potential behavioral change strategies are primary public health issues. The purpose of this article is to review the contributions included in this special edition, which represent an effort to describe the most current thinking in the field with a blend of theoretical, review, and empirical articles. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Telephone booster sessions for optimizing smoking cessation for patients in rehabilitation centers.

Smokers with smoking-related diseases who are hospitalized in rehabilitation centers should be offered smoking cessation. This is the first study evaluating whether telephone booster sessions after intensive inpatient treatment are an effective strategy. The present study was conducted in 13 rehabilitation centers for somatic disorders as a prospective multicenter study with a randomized treatment-control group design. We compared abstinence rates after hospital discharge from treatment that included a group smoking cessation program with (treatment group) and without telephone booster sessions (control group). Data from 290 smokers were analyzed. After 6 and 12 months the treatment group achieved abstinence rates twice as high as those of the control group. Men profited more from telephone booster sessions than did women. Results indicated that telephone booster sessions were highly effective (even) after an inherently intensive group program during a hospital stay. Further research should focus on the special needs of women receiving telephone counseling.     

A detailed analysis of ambipolar diffusion in nanostructured metal oxide films

In this paper a transport equation is derived which describes the behaviour of the nanostructured metal oxide films in a photoelectrochemical cell. It is shown that a detailed analysis of the charge compensation mechanism necessarily leads to a transport equation with characteristics similar to but logically distinct from the pure diffusion equation. The studied phenomenon was named ambipolar diffusion in the early 1950s. It takes into account the fact that the diffusion processes of ions and electrons occur at different speeds. A weak electric field therefore couples the processes together to preserve charge neutrality. The electric field in turn affects the transport resulting in a deviation from purely diffusive behaviour. However, this has not been widely recognised in the literature for nanostructured semiconductor films until very recently. In this paper a detailed analysis is presented. It is based on the assumption that the current density is solenoidal. It is shown that application of the ambipolar diffusion model to a photoelectrochemical cell based on a nanostructured metal oxide film leads to an additional term in the transport equation, rather than only a new diffusion coefficient as in earlier work. It is also shown that the boundary conditions interact closely with the equation to form a transport model.     

Effect of Surface Characteristics on Compressive Stress and Leakage Rate in Gasketed Flanged Joints

The effect of surface characteristics on compressive stress and leakage rate in gasketed flanged joints is discussed qualitatively and quantitatively based on experimental verifications. The sensitivity of the sealing phenomenon to the sealing surface characteristics, gas pressure and stress level is presented. Sealing surfaces produced with grinding, turning and milling procedures of different roughness values were the subject of the tests with three types of gasket, namely, PTFE (polytetrafluoroethylene), graphite, and spiral wound. The experimental results indicated that the roughness value Ra (average arithmetic height) has no effect on the sealing performance of the gasket, except for the ground type sealing surfaces. The platen (flange) surface forms were found to be the determining factor on the leakage rate and flow regime for gasketed flanged joints. It is shown that the surface characteristics have no effect on the leakage rate and on the gasket performance for the PTFE gasket at high stress levels. However, at low stress levels the rougher ground and milled sealing surfaces having radial channels on the surface produce larger leakage rates. The effect of surface characteristics, stress level, and gas pressure was more evident on the graphite and spiral wound gasket types, at both low and high stress levels. It is also shown that the leakage rate follows an exponential law as a factor of surface stress and gas pressure, for all sealing surface characteristics and gasket types. While there is little difference in the leakage rate for the PTFE gasket when the gasket stress level is increased by a factor of two, from S3 to S5, a substantial leakage rate reduction by a ratio of 17.5 times was observed for the graphite and spiral wound gaskets for most sealing surfaces. On the other hand, when increasing the helium gas pressure from 200 to 800 p.s.i., the leakage rate increased by 5 times for the PTFE, and up to10 times for the graphite and the spiral wound gaskets. It was determined that while molecular flow regimes can be achieved for the PTFE gasket for all sealing surfaces, the two other gasket types provided laminar flow under the same operating conditions.     

Oxidized Fullerene Derivatives Containing Hydroxyl, Nitro and Fluorine Groups

Oxidation of fullerene was performed with fuming nitric acid and a soluble orange compound was synthesized and identified as polyhydroxy-polynitro fullerene. The formation of fullerene derivatives containing oxygen and fluorine were attempted by different methods using F₂, HF aqueous solution and fuming nitric acid. Resulting compounds were generally characterized by X-ray diffraction and IR and NMR spectroscopy.