Preparation of dye sensitized titanium oxide nanoparticles for solar cell applications

A new method for synthesis of titanium dioxide (TiO₂)-dye nanoparticles is reported. TiO₂ nanocrystals were obtained at 150 and 200 °C by using chemically bonded TiO₂-sensitizer dye as a precursor. Titanium tetraisopropoxide was first modified with a dye molecule and then precipitated by dropping into acidic water. A strongly colored precipitate was obtained. Hydrothermal growth of a colloidal solution was carried out in a Teflon-lined stainless steel autoclave. Dye sensitized solar cell efficiencies obtained were comparable and fill factor values were close to the analogous cells prepared by the use of conventional TiO₂ paste techniques. This method allows the use of different substrates together with nanocrystalline TiO₂ for many technological applications.     

Photovoltaic Properties and Negative Capacitance Spectroscopy of PCBM:P3HT/FTO Nanostructured Counter Electrode for TiO2-Based DSSC

Nano-clusters blind films of phenyl C61-butyric acid methyl ester (PCBM) and poly(3-hexylthiophene) (P3HT) were deposited on fluorine doped tin-oxide (FTO) substrate by spin coating and applied as counter electrodes instead of platinum for a new FTO/TiO₂?+?K30 dye-sensitized solar cell. The photovoltaic parameters of the fabricated solar cell; open circuit voltage, short circuit current, output power and fill factor, were studied under various light intensities in the range 20:110?mW?cm^?2. An impedance spectroscopy study was also performed in a wide frequency range (5?kHz–1?MHz) to study the electron transport properties of the solar cells. The capacitance–voltage of the prepared DSSC is characterized by two parts: positive values of capacitance at low frequency range, f?≤?100?kHz and negative capacitance i.e., an inductive behavior, in higher frequency range f?≥ 300 kHz Conducting polymer electrode based on PCBM:P3HT/FTO can be used as a counter electrode in a DSSC.     

Optimizing the processing conditions of sodium potassium niobate thin films prepared by sol-gel spin coating technique

In the present study, potassium sodium niobate (KNN) thin films were synthesized by means of sol-gel spin coating method. Along with the synthesis, the effects of annealing temperature and various number of coating layers on both the structural and electrical properties were looked into. The results of the study revealed that the annealing temperature had a great impact on the properties of KNN. In addition, the XRD diffractograms and texture coefficient of the synthesized films confirmed that a highly oriented orthorhombic perovskite structure was obtained at 650 °C, whereas at a relatively higher temperature (700 °C), a spurious phase of K₄Nb₆O₁₇ was evolved. In addition, the growth of KNN at 650 °C exhibited a reasonable resistivity value for piezoelectric applications. Looking into the results, it was discovered that the KNN thin films also found to be dependent on a number of coating layers. Field emission scanning electron microscopy (FESEM) showed that KNN with five coating layers was highly crystalline, cracks-free, and had significantly more homogenous surface morphology and the size of grains being uniform, the resistivity of KNN thin films improved with the increasing number of coating layers i.e., up to five.     

屏蔽泵常见故障分析及解决方案

轻质油装置屏蔽泵在运行中发生泵体内有杂音、振动超标、轴承磨损的故障。通过对屏蔽泵结构和故障现象的分析,找到了故障产生的原因。含气态组分的介质进入屏蔽泵冷却腔体和润滑轴承的循环管路,使得轴承容易磨损;泵体结构的流向设计得不合理,造成介质在泵腔内汽化,形成汽蚀,并造成轴承磨损;介质流量不平稳造成轴向力不平衡。实施了相应的解决方案,降低了设备故障率和检修率,确保了装置安全平稳运行。     

维吾尔语词首音节元音声学分析

该文利用“维吾尔语语音声学参数数据库”,统计分析和归纳了维吾尔语词首音节元音的共振峰模式及其分布格局。声学元音图有多种画法,该文采用JOOS型声学元音图。这种元音图的特点是以F1为纵坐标,以F2为横坐标。这样绘制成的声学元音图与元音舌位图有很好的对应性。维语标准音词首音节中有[y, i, e, O, u, o, ;, A]等8个元音。舌位前后的分布特点是[u, o, A]为后元音,[y, i, e, O, ;]为前元音;开口度(舌位高低)分布特点是[y, i, u]为高元音,[e, O, o]为次高元音,[;]为次低元音, [A]为低元音.     

A compact hybrid feature vector for an accurate secondary structure prediction

Amino acid propensity score is one of the earliest successful methods used in protein secondary structure prediction. However, the score performs poorly on small-sized datasets and low-identity protein sequences. Based on current in silico method, secondary structure can be predicted from local folds or local protein structure. In biology, the evolution of secondary structure produces local protein structure with different lengths. To precisely predict secondary structures, we propose a derivative feature vector, DPS that utilizes the optimal length of the local protein structure. DPS is the unification of amino acid propensity score and dihedral angle score. This new feature vector is further normalized to level the edges. Prediction is performed by support vector machines (SVM) over the DPS feature vectors with class labels generated by secondary structure assignment method (SSAM) and secondary structure prediction method (SSPM). All experiments are carried out on RS126 sequences. The results from this proposed method also highlight the overall accuracy of our method compared to other state-of-the-art methods. The performance of our method was acceptable specifically in dealing with low number and low identity sequences.     

Effect of near-field coupling on far-field inelastic scattering imaging of gold nanoparticles

The optical near-field enhancement induced by coupling between noble nanoparticles and the substrate has been studied by a far-field imaging method. The longitudinal mode of the incident laser is revealed to contribute to the coupling. The far-field images of individual gold nanoparticles exhibit a peanut-shaped pattern; these were constructed by the intensity of inelastically scattered light. The coupling between gold nanoparticles and the silicon substrate leads to the patterned image. By tuning the separation between the gold nanoparticles and substrate using SiO(2) layers of different thickness, the coupling efficiency decreases with the thickness of the SiO(2) layer.