Effects of molybdenum additions on the structure, depth, and austenite grain size of the case of carburized 0.13% carbon steels

Carbon (0.13%) steel samples containing about 0.48% molybdenum (Mo) singly and in combination with nickel (Ni) were carburized in a natural Titas gas atmosphere at a temperature of 1223 K (950 °C) and at a pressure of about 0.10 MPa (15 psia) for time periods ranging from 1–4 h followed by slow cooling in the furnace. Their microstructure was studied by optical microscopy. The austenite grain size of the case and the case depths were determined. It was found that Mo and Ni alone and in combination decrease the thickness of the cementite network near the surface of the carburized case of the steels. However, Ni is found to be more effective than Mo in decreasing the thickness of cementite network. Both Mo and Ni enhance the formation of Widmanstätten cementite plates at the grain boundary and within the grains near the surface of the carburized steels. However, Ni alone is more effective than Mo in the formation of Widmanstätten cementite plates. In the presence of Ni, Mo is much more effective in the formation of Widmanstätten cementite plates than Mo in absence of Ni. It was also revealed that both Mo and Ni increased the case depth. Ni is more effective than Mo in increasing the case depth. The combined effect of Mo and Ni is much greater than that of either Mo or Ni alone in increasing case depth. Mo as Mo carbide (Mo₂C) particles refined the austenite grain size of the carburized case. Ni in solution was not found to have any effect in restricting grain growth of austenite, but the presence of Ni enhances the austenite grain size refining effect of Mo in the carburized case.     

PERFORMANCE OF THREE STAGE TURBO－EQUALIZATION－DECODING

An increasing demand for high data rate transmission and protection over bandlimited channels with severe inter-symbol interference has resulted in a flurry of activity to improve channel equalization. In conjunction with equalization, channel coding-decoding can be employed to improve system performance. In this letter, the performance of the three stageturbo-equalization-decoding employing log maximum a posteriori probability is experimentally evaluated by a fading simulator. The BER is evaluated using various information sequence and interleaver sizes taking into account that the communication medium is a noisy inter symbol interference channel.     

Effective fault detection and routing scheme for wireless sensor networks

In a wireless sensor network (WSN), random occurrences of faulty nodes degrade the quality of service of the network. In this paper, we propose an efficient fault detection and routing (EFDR) scheme to manage a large size WSN. The faulty nodes are detected by neighbour node’s temporal and spatial correlation of sensing information and heart beat message passed by the cluster head. In EFDR scheme, three linear cellular automata (CA) are used to manage transmitter circuit/ battery condition/microcontroller fault, receiver circuit fault and sensor circuit fault representation. On the other hand, L-system rules based data routing scheme is proposed to determine optimal routing path between cluster head and base station. The proposed EFDR technique is capable of detecting and managing the faulty nodes in an efficient manner. The simulation results show 86% improvement in the rate of energy loss compared to an existing algorithm.     

Heat exchanger network synthesis with detailed exchanger designs: Part 1. A discretized differential algebraic equation model for shell and tube heat exchanger design

A new method for the detailed design of shell and tube heat exchangers is presented through the formulation of coupled differential heat equations, along with algebraic equations for design variables. Heat exchanger design components (tube passes, baffles, and shells) are used to discretize the differential equations and are solved simultaneously with the algebraic design equations. The coupled differential algebraic equation (DAE) system is suitable for numerical optimization as it replaces the nonsmooth log mean temperature difference (LMTD) term. Discrete decisions regarding the number of shells, fluid allocation, tube sizes, and number of baffles are determined by solving an LMTD-based method iteratively. The resulting heat exchanger topology is then used to discretize the detailed DAE model, which is solved as a nonlinear programming model to obtain the detailed exchanger design by minimizing an economic objective function through varying the tube length. The DAE model also provides the stream temperature profiles inside the exchanger simultaneously with the detailed design. It is observed that the DAE model results are almost equal to the LMTD-based design model for one-shell heat exchangers with constant stream properties but shows significant differences when streams properties are allowed to vary with temperature or the number of shells are increased. The accuracy of the solutions and the required computational costs show that the model is well suited for solving heat exchanger network synthesis problems combined with detailed exchanger designs, which is demonstrated in Part 2 of the paper.     

Evaluation of an ultrasonic acid digestion procedure for total heavy metals determination in environmental and biological samples

In this study, a sample preparation method based on ultrasonic assisted acid digestion (UAD) has been evaluated for total heavy metals (Cd, Cr, Ni and Pb) determination in different environmental (soil, sediment and sewage sludge), and biological (fish muscles, vegetables and grains) samples, using electrothermal atomic absorption spectrometry (ETAAS). The investigated parameters influencing UAD such as presonication time, sonication time, temperature of ultrasonic bath, and different acid mixtures were fully optimized, whereas power was maintained constant at 100% of nominal power of ultrasonic bath. Six different sets of above parameters were applied on six certified reference materials (CRMs) having different matrices. The accuracy of the method was also tested by comparing the results with those obtained from conventional hot plate assisted acid digestion method on same CRMs. Analytical results for HMs by both methods showed no significant difference at 95% confidence limit (p<0.05). Recoveries of HMs ranging from 96.2% to 102% and 96.3% to 98.6% were obtained from biological and environmental samples, respectively. The average relative standard deviation of UAD method varied between 3.5% and 8.2%, depending on the analyte.     

CtpB Facilitates Mycobacterium tuberculosis Growth in Copper-Limited Niches

Copper is required for aerobic respiration by Mycobacterium tuberculosis and its human host, but this essential element is toxic in abundance. Copper nutritional immunity refers to host processes that modulate levels of free copper to alternately starve and intoxicate invading microbes. Bacteria engulfed by macrophages are initially contained within copper-limited phagosomes, which fuse with ATP7A vesicles that pump in toxic levels of copper. In this report, we examine how CtpB, a P-type ATPase in M. tuberculosis, aids in response to nutritional immunity. In vitro, the induced expression of ctpB in copper-replete medium inhibited mycobacterial growth, while deletion of the gene impaired growth only in copper-starved medium and within copper-limited host cells, suggesting a role for CtpB in copper acquisition or export to the copper-dependent respiration supercomplex. Unexpectedly, the absence of ctpB resulted in hypervirulence in the DBA/2 mouse infection model. As ctpB null strains exhibit diminished growth only in copper-starved conditions, reduced copper transport may have enabled the mutant to acquire a “Goldilocks” amount of the metal during transit through copper-intoxicating environments within this model system. This work reveals CtpB as a component of the M. tuberculosis toolkit to counter host nutritional immunity and underscores the importance of elucidating copper-uptake mechanisms in pathogenic mycobacteria.     

Sedentary behaviour and health at work: an investigation of industrial sector,job role,gender and geographical differences

This article presents baseline data from 1120 employees across 10 worksites enrolled in a workplace physical activity intervention. The study provides new data on physical activity, sedentary behaviour, and health and highlights gender, geographical, job type and industrial sector differences. Sitting at work accounted for more than 60% of participants’ total daily sitting time on work days. Weekly and monthly hours worked, body mass index (BMI) and waist circumference were significantly higher for workers in the private sector compared to the public sector. Employees in sales and customer services had significantly higher BMI scores and significantly lower scores for workability index (WAI), job satisfaction, organisational commitment and job motivation, compared to other groups. This study provides further evidence that work is a major contributor to sedentary behaviour and supports the pressing need for interventions particularly targeting private sector industries and sales and customer service sectors.

Practitioner Summary: Work accounts for more than 60% of the daily sitting time. Private sector employees had higher BMIs than those in the public sector and employees in sales and customer services had higher BMIs and poorer health compared to other occupations, suggesting that these groups should be targeted in workplace interventions.     

Simultaneously determination of methyl and inorganic mercury in fish species by cold vapour generation atomic absorption spectrometry

A simple and rapid non-chromatographic method was developed to determine methylmercury (MeHg) and inorganic mercury (iHg) levels in muscles tissues of 10 freshwater fish species. The MeHg and iHg were determined by cold vapour atomic absorption spectrometry after alkaline wet digestion of samples. The digested samples were reduced sequentially with stannous chloride and sodium tetrahydroborate for iHg and MeHg, respectively. Parameters such as carrier gas flow rate (argon), volume of oxidizing and potassium persulphate solutions were investigated in detail. The accuracy of the technique was evaluated by using certified reference material (DORM-2) and spiking the both Hg species in muscles tissue of a fish. The limits of detection were 0.117 and 0.133 μg kg⁻¹ for MeHg and iHg, respectively. The concentrations of MeHg and iHg in muscles tissues of ten fish species were found in the range of (28.4–56.3) and (3.01–8.11) μg kg⁻¹, respectively.