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1.
Keita Ikeue Shingo Ando Tomohiro Mitsuyama Yusuke Ohta Keishi Arayama Akiko Tsutsumi Masato Machida 《Topics in Catalysis》2008,47(3-4):175-180
Lanthanide-based oxysulfides and sulfide, LnTaO3.5S0.5, Ln10OS14 (Ln = La, Pr, Nd, Sm) and La4In5S13, were successively synthesized by sulfurization in a flowing H2S. The sulfurization decreased the band-gap energies from >4 eV to <3eV, because of the formation of occupied S3p orbitals
on the top of valence band. In accordance with the small band gap, the H2 evolution from a 0.01 M Na2S and 0.01 M Na2SO3 solution system was observed under irradiation of light up to >500 nm. The rate of H2 evolution under light irradiation of >500 nm increased in the order of Ni/LaTaO3.5S0.5 < Ru/La10OS14 < Pt/La4In5S13. 相似文献
2.
A combined technique of the rapid freezing, freeze substitution–fixation method and the osmium–DMSO-osmium method was devised. By this combined method we clearly observed the architecture of intracellular components in three dimensions. Morphological characteristics were generally similar to those of tissue prepared by the osmium–DMSO-osmium method but different in some respects. Mucigen droplets in intestinal goblet cells, for example, appeared as separated spheres, while in specimens prepared by chemical fixation they were observed as a mass of fused droplets. In the Golgi complex, all cisternae were extremely flat, although they usually dilated on the cis side after chemical fixation. Particles on the mitochondrial tubules of liver cells were well distinguished. They were mushroom shaped, as are those observed by negative staining. The combined method, that is, the rapid freezing, osmium–DMSO-osmium method, is thought to be effective for studying the true structure of intracellular components by scanning electron microscopy. 相似文献
3.
A mist of a hydrosol consisting of silica, alumina/NaAlO2 and sodium hydroxide was produced by a supersonic atomization, and treated successively in three furnaces of different temperatures. The temperatures of the furnaces were adjusted for the evaporation of water, the dehydration and the crystallization of the mixed oxide, respectively. The spherical particles ( 0.5m) of carnegieite were found to be formed in a narrow composition range of the raw materials at temperatures of 650 to 900° C. The factors affecting the properties of the particles were investigated. 相似文献
4.
5.
Polystyrene (PS)/poly(ethylene oxide) (PEO) prototype brushes were prepared by alternating free‐radical copolymerization of methacryloyl‐terminated PS and α‐vinylbenzyl‐ω‐hydroxy or α‐vinylbenzyl‐ω‐perfluoroalkyl (Rf) PEO macromonomers with the addition of Lewis acid (SnCl4). It was found from their dilute‐solution properties that PS/PEO end‐capped with Rf (PBRf), and PS/PEO having OH groups at terminal ends (PBOH) prototype brushes formed a single molecule in benzene and aggregates in chloroform, respectively. However, the brush PBOH formed a single molecule in N,N‐dimethylformamide. Such aggregation behaviors seemed to be caused by the interaction between hydroxy groups of PEO chain ends. The brush PBOH was also converted into PBRf‐type brush by chemical modification, using corresponding acid chloride. The substitution of Rf groups was ~70% due to slipping of terminal hydroxy groups into PEO internal domains. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 772–778, 2006 相似文献
6.
Catalyst performance of NiO–MgO solid solution catalysts for methane reforming with CO2 and H2O in the presence of oxygen using fluidized and fixed bed reactors under atmospheric and pressurized conditions was investigated. Especially, methane and CO2 conversion in the fluidized bed reactor in methane reforming with CO2 and O2 was higher than those in the fixed bed reactor over Ni0.15Mg0.85O catalyst under 1.0 MPa. In contrast, conversion levels in the fluidized and fixed bed reactor were almost the same over MgO-supported Ni and Pt catalysts. It is suggested that the promoting effect of catalyst fluidization on the activity is related to the catalyst reducibility. On a catalyst with suitable reducibility, the oxidized and deactivated catalyst can be reduced with the produced syngas and the reforming activity regenerates in the fluidized bed reactor during the catalyst fluidization. In addition, the catalyst fluidization inhibited the carbon deposition. 相似文献
7.
We have been developed novel catalysts for gasification of biomass with much higher energy efficiency than conventional methods (non-catalyst, dolomite, commercial steam reforming Ni catalyst). From the result of the gasification of cellulose over novel Rh/CeO2/SiO2 catalysts, it is found that the gasification process consists of the reforming of tar and the combustion of solid carbon. We also tested novel Rh/CeO2/SiO2 in the gasification with air, pyrogasification, and steam reforming of cedar wood. As a result, Rh/CeO2/SiO2 gave higher yield of syngas than the conventional steam reforming Ni catalyst. Furthermore, we compared the performance between single and dual bed reactors. Single bed reactor was effective in the gasification of cedar, however, it was not suitable for the gasification of rice straw since a rapid deactivation was observed. Gasification of rice straw, jute stick, baggase using the fluidized dual-bed reactor and Rh/CeO2/SiO2 was also investigated. Especially, the catalyst stability in the gasification of rice straw clearly was enhanced by using the fluidized dual bed reactor. 相似文献
8.
Keiichi Okajima 《Electrochimica acta》2005,50(11):2227-2231
Modified activated carbon fibers (ACFs) were used as the electrodes of an electric double-layer capacitor and showed an enhanced capacitance effect after a RF-plasma treatment. The capacitance and the surface functional groups of the ACFs were studied. For the plasma-treated ACFs having a specific surface area of 1500 m2 g−1, the capacitance increased by 28% compared to the untreated sample and the highest electric capacitance value of 142 F g−1 was achieved with an oxygen feed concentration of 10 vol.%. The Brunauer-Emmett-Teller (BET) surface area was 2103 m2 g−1, which was 34% higher than that of the untreated sample. The pore volume was similarly increased to 483.1 cm3 g−1 STP, and from the pore distribution plot, quantities of mesopores of 10 nm or less and micropores also increased. However, in order to enhance the capacitance, the quinone functional group had a significant influence in addition to the BET surface area. The correlation between the capacitance and the number of quinone functional groups was confirmed because quinone is an electron acceptor. 相似文献
9.
Imoto Taiji; Ueda Tadashi; Tamura Tomohiro; Isakari Yoshimasa; Abe Yoshito; Inoue Makoto; Miki Takeyoshi; Kawano Keiichi; Yamada Hidenori 《Protein engineering, design & selection : PEDS》1994,7(6):743-748
Mutations around His15 which lie far away from the active site,stimulated glycol chitin activity of lysozyme at physiologicaltemperature. Del-Argl4Hisl5 lysozyme, a mutant lysozyme whoseArgl4 and Hisl5 were deleted together, and has the highest activityamong these mutant lysozymes, had a similar binding abilityto a trimer of N-acetyl-glucosamine, a substrate analogue, relativeto native lysozyme. This suggests that the increased activitywas due to an increased kcat in the catalysis reaction. TheH-D exchange rate of the N-1 proton in the Trp63 which is locatedin the active site cleft, was enhanced in the Del-Argl4Hisl5lysozyme, while 2-D proton NMR analysis revealed no conformationalchange around Trp63. We conclude that some sort of fluctuationat the active site might be required for the manifestation ofactivity. This theory is supported by the finding that the Del-Argl4Hisl5lysozyme showed a shift in temperature dependency of activityto lower temperatures compared with that of native lysozyme. 相似文献
10.
Keiichi Tomishige Tomohisa Miyazawa Takeo Kimura Kimio Kunimori Naoto Koizumi Muneyoshi Yamada 《Applied catalysis. B, Environmental》2005,60(3-4):299-307
In the partial oxidation of tar derived from the pyrolysis of cedar wood, the effect of H2S addition was investigated over non-catalyst, steam reforming Ni catalyst, and Rh/CeO2/SiO2 using a fluidized bed reactor. In the non-catalytic gasification, the product distribution was not influenced by the presence of H2S. Steam reforming Ni catalyst was effective for the tar removal without H2S addition, however, the addition of H2S deactivated drastically. In contrast, Rh/CeO2/SiO2 exhibited higher and more stable activity than the Ni catalyst even under the presence of high concentration of H2S (280 ppm). On the Ni catalyst, the adsorption of sulfur was observed by XPS and Ni species was oxidized during the partial oxidation of tar. In the case of Rh/CeO2/SiO2, the adsorption of sulfur was below the detection limit of XPS. This can be related to the self-cleaning of catalyst surface during the circulation in the fluidized bed reactor for the partial oxidation of tar derived from cedar pyrolysis. 相似文献