Electronic properties of magnetically doped nanotubes

Effect of doping of carbon nanotubes by magnetic transition metal atoms has been considered in this paper. In the case of semiconducting tubes, it was found that the system has zero magnetization, whereas in metallic tubes the valence electrons of the tube screen the magnetization of the dopants: the coupling to the tube is usually antiferromagnetic (except for Cr).     

Kinetic study of radical polymerization. II. Solid‐state bulk polymerization of sodium methacrylate by differential scanning calorimetry

The solid‐state radical polymerization of sodium methacrylate was investigated. It was initiated by azobisisobutyronitrile, which was used as a radical initiator. Differential scanning calorimetry (DSC) was used to observe the endothermic and exothermic transitions during the polymerization reaction. Structural studies were performed with the DSC thermograms and Fourier transform infrared and ultraviolet–visible spectra, and all of the results confirmed the progress of the reaction. The obtained data revealed that the polymerization reaction proceeded completely with a 100% conversion. ΔH of this reaction was calculated with various amounts of the initiator, and the peak temperatures were determined at different heating rates. The activation energy (19.7 kcal mol^?1) was also obtained by the Kissinger method for this type of solid polymerization reaction. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1648–1654, 2003     

A novel design of 8-bit adder/subtractor by quantum-dot cellular automata

Application of quantum-dot is a promising technology for implementing digital systems at nano-scale. QCA supports the new devices with nanotechnology architecture. This technique works based on electron interactions inside quantum-dots leading to emergence of quantum features and decreasing the problem of future integrated circuits in terms of size. In this paper, we will successfully design, implement and simulate a new full adder based on QCA with the minimum delay, area and complexities. Also, new XOR gates will be presented which are used in 8-bit controllable inverter in QCA. Furthermore, a new 8-bit full adder is designed based on the majority gate in the QCA, with the minimum number of cells and area which combines both designs to implement an 8-bit adder/subtractor in the QCA. This 8-bit adder/subtractor circuit has the minimum delay and complexity. Being potentially pipeline, the QCA technology calculates the maximum operating speed.     

Modification of glassy carbon electrode with multi-walled carbon nanotubes and iron(III)-porphyrin film: Application to chlorate, bromate and iodate detection

In this study, multi-wall carbon nanotubes (MWCTs) is evaluated as a transducer, stabilizer and immobilization matrix for the construction of amperometric sensor based on iron-porphyrin. 5,10,15,20-Tetraphenyl-21H,23H-porphine iron(III) chloride (Fe(III)P) adsorbed on MWCNTs immobilized on the surface of glassy carbon electrode. Cyclic voltammograms of the Fe(III)P-incorporated-MWCNTs indicate a pair of well-defined and nearly reversible redox couple with surface confined characteristics at wide pH range (2-12). The surface coverage (Γ) and charge transfer rate constant (k_s) of Fe(III)P immobilized on MWCNTs were 7.68 × 10⁻⁹ mol cm⁻² and 1.8 s⁻¹, respectively, indicating high loading ability of MWCNTs for Fe(III)P and great facilitation of the electron transfer between Fe(III)P and carbon nanotubes immobilized on the electrode surface. Modified electrodes exhibit excellent electrocatalytic activity toward reduction of ClO₃⁻, IO₃⁻ and BrO₃⁻ in acidic solutions. The catalytic rate constants for catalytic reduction of bromate, chlorate and iodate were 6.8 × 10³, 7.4 × 10³ and 4.8 × 10² M⁻¹ s⁻¹, respectively. The hydrodynamic amperometry of rotating-modified electrode at constant potential versus reference electrode was used for detection of bromate, chlorate and iodate. The detection limit, linear calibration range and sensitivity for chlorate, bromate and iodate detections were 0.5 μM, 2 μM to 1 mM, 8.4 nA/μM, 0.6 μM, 2 μM to 0.15 mM, 11 nA/μM, and 2.5 μM, 10 μM to 4 mM and 1.5 nA/μM, respectively. Excellent electrochemical reversibility of the redox couple, good reproducibility, high stability, low detection limit, long life time, fast amperometric response time, wide linear concentration range, technical simplicity and possibility of rapid preparation are great advantages of this sensor. The obtained results show promising practical application of the Fe(III)P-MWCNTs-modified electrode as an amperometric sensor for chlorate, iodate and bromate detections.     

Parallel Lagrange interpolation on <Emphasis Type="Italic">k</Emphasis>-ary <Emphasis Type="Italic">n</Emphasis>-cubes with maximum channel utilization

This paper proposes an efficient parallel algorithm for computing Lagrange interpolation on k-ary n-cube networks. This is done using the fact that a k-ary n-cube can be decomposed into n link-disjoint Hamiltonian cycles. Using these n link-disjoint cycles, we interpolate Lagrange polynomial using full bandwidth of the employed network. Communication in the main phase of the algorithm is based on an all-to-all broadcast algorithm on the n link-disjoint Hamiltonian cycles exploiting all network channels, and thus, resulting in high-efficiency in using network resources. A performance evaluation of the proposed algorithm reveals an optimum speedup for a typical range of system parameters used in current state-of-the-art implementations.

An ant colony optimization algorithm for the bi-objective shortest path problem

Multi-objective shortest path problem (MOSP) is an extension of a traditional single objective shortest path problem that seeks for the efficient paths satisfying several conflicting objectives between two nodes of a network. MOSP is one of the most important problems in network optimization with wide applications in telecommunication industries, transportation and project management. This research presents an algorithm based on multi-objective ant colony optimization (ACO) to solve the bi-objective shortest path problem. To analyze the efficiency of the algorithm and check for the quality of solutions, experimental analyses are conducted. Two sets of small and large sized problems that generated randomly are solved. Results on the set problems are compared with those of label correcting solutions that is the most known efficient algorithm for solving MOSP. To compare the Pareto optimal frontiers produced by the suggested ACO algorithm and the label correcting algorithm, some performance measures are employed that consider and compare the distance, uniformity distribution and extension of the Pareto frontiers. The results on the set of instance problems show that the suggested algorithm produces good quality non-dominated solutions and time saving in computation of large-scale bi-objective shortest path problems.     

Estimating the scattering distribution of the received signals in multipath fading channels

This paper presents a novel approach for estimating the distribution of the incoming waves at the mobile unit antenna, i.e. the scattering distribution, in a typical micro-cellular system. This estimate is vital in determining many system parameters of interest as well as designing unbiased estimators for the velocity of mobile units in micro-cellular systems. The proposed approach deploys the zero-crossing rates of the quadrature components and the instantaneous frequency of the received signal at the mobile unit to estimate the scattering distribution. We also propose a new model for simulating multipath fading channels with non-isotropic scattering. We use the channel simulator to evaluate the performance of the proposed estimator for the scattering distribution. Simulation results show that proposed estimator exhibits small bias and root mean square error.     

Revisiting the free transverse vibration of embedded single-layer graphene sheets acted upon by an in-plane magnetic field

Murmu et al. [23] recently presented a nonlocal model for the transverse vibration of simply supported graphene sheets in the presence of a unidirectional in-plane magnetic field. Further studies showed that the majority of Lorentz’s force components were improperly provided and led to invalid governing equations. To remove such deficiencies, the most general form of Lorentz’s force components is carefully extracted in the present work. The nonlocal equations of motion of the problem are reconstructed and solved again. The influences of crucial parameters on the flexural frequencies of magnetically affected graphene sheets and nanoribbons are examined in detail. Furthermore, the crucial discrepancies between the results obtained in this study and those of the abovementioned previous work are rationally discussed. Some erroneous results of the latter are also rectified.