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1.
Graphene oxide was chemically functionalized with a modifier synthesized from coupling reaction of ethylenediamine and 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid in low and high graft densities. Then, the modified graphenes were used in grafting from reversible addition-fragmentation chain transfer polymerization of styrene. Successful synthesis and grafting of modifier was approved by proton nuclear magnetic resonance and Fourier transform infrared spectroscopy (FTIR). Also, FTIR, X-ray photo electron spectroscopy, and Raman spectroscopy were used to confirm the successful grafting of modifier moieties. Molecular weight and polydispersity index of attached polystyrene chains were studied by size exclusion chromatography. Thermogravimetric analysis was used to investigate the degradation temperatures, char contents, and graft ratios. Weight ratio of modifier in modified graphenes is calculated to be 4.93 × 10?2 and 12.23 × 10?2 for low and high graft densities. Also, molar ratio of modifier is 121.22 and 300.71 μmol/g respectively. Scanning electron and transmission electron microscopies show that graphite layers with flat surface were wrinkled during the oxidation process and also polystyrene-grafted graphenes are observed as opaque layers. 相似文献
2.
A. Beitollahi Ch. Khezri 《Journal of Materials Science: Materials in Electronics》2001,12(12):707-714
In this work, an attempt is made to study
system with x=0.0125, 0.025, 0.050, 0.075 and 0.1. It was shown that there is limited solid solubility (0.625 mol %) of
or 1.25 mol % of
in PZT(53/47). For higher levels of dopant, mainly two other extra second phases were detected. The first was a Zr-rich phase in which some
and small amounts of
was dissolved. The second one was a Pb solid solution
composed of mainly PbO,
and
which was initially also seen in calcined samples. The formation of Zr-rich phase is thought possibly to originate due to the sublimation of Pb from
source during the sintering process. For higher x values, a structural shift towards Ti-rich region of PZT's phase diagram is seen. All piezoelectric parameters of the doped samples such as
,
are seen to decline sharply compared to that of undoped samples. Increasing the level of dopant gave rise to the increase of conductivity and dielectric loss of sintered samples. The formation of non-ferroelectric extra phases, and the Zr/Ti change of the main formed phase is believed to be responsible for this behavior. 相似文献
3.
Huanping Yang Jian Jiang Weiwei Zhou Linfei Lai Lifei Xi Yeng Ming Lam Zexiang Shen Bahareh Khezri Ting Yu 《Nanoscale research letters》2011,6(1):531
MnO2 supported on graphene oxide (GO) made from different graphite materials has been synthesized and further investigated as electrode materials for supercapacitors. The structure and morphology of MnO2-GO nanocomposites are characterized by X-ray diffraction, X-ray photoemission spectroscopy, scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and Nitrogen adsorption-desorption. As demonstrated, the GO fabricated from commercial expanded graphite (denoted as GO(1)) possesses more functional groups and larger interplane gap compared to the GO from commercial graphite powder (denoted as GO(2)). The surface area and functionalities of GO have significant effects on the morphology and electrochemical activity of MnO2, which lead to the fact that the loading amount of MnO2 on GO(1) is much higher than that on GO(2). Elemental analysis performed via inductively coupled plasma optical emission spectroscopy confirmed higher amounts of MnO2 loading on GO(1). As the electrode of supercapacitor, MnO2-GO(1) nanocomposites show larger capacitance (307.7 F g-1) and better electrochemical activity than MnO2-GO(2) possibly due to the high loading, good uniformity, and homogeneous distribution of MnO2 on GO(1) support. 相似文献
4.
Kinetic study of styrene atom transfer radical polymerization from hydroxyl groups of graphene nanoplatelets: Heterogeneities in chains and graft densities
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Hossein Roghani‐Mamaqani Vahid Haddadi‐Asl Khezrollah Khezri Mehdi Salami‐Kalajahi Mohammad Najafi 《Polymer Engineering and Science》2015,55(8):1720-1732
Confinement effect of graphene nanoplatelets on the kinetics of styrene atom transfer radical polymerization was studied by a “grafting from” reaction. Graphene oxide was modified by different amounts of (3‐aminopropyl) triethoxysilane and then alpha‐bromoisobutyryl bromide from the hydroxyl groups. Polymerization of styrene in the presence of modified graphene and free initiator, ethyl alpha‐bromoisobutyrate, was accomplished at 110°C. Then, effect of various graft densities and different graphene loadings on the heterogeneous graft and free polystyrene chains characteristics and also kinetics of polymerization was studied by gas and gel permeation chromatographies. Efficiency of grafting reactions along with the graft contents was studied by X‐ray photoelectron spectroscopy, elemental analysis, and thermogravimetric analysis. Confinement effects of graphene on the relaxation behavior of polystyrene chains and also morphology of the graphenes were studied by differential scanning calorimetry and transmission electron microscopy, respectively. POLYM. ENG. SCI., 55:1720–1732, 2015. © 2014 Society of Plastics Engineers 相似文献
5.
Khezrollah Khezri Vahid Haddadi‐Asl Hossein Roghani‐Mamaqani Mehdi Salami‐Kalajahi 《Polymer Composites》2011,32(12):1979-1987
Exfoliated poly(styrene‐co‐methyl methacrylate) nanocomposites were synthesized using activators generated by electron transfer for atom transfer radical polymerization (AGET ATRP). Miniemulsion polymerization was used for its abundant advantages to encapsulate inorganic materials and eliminate organic solvents from products for environmentally friendly purposes. Cetyltrimethylammonium bromide (CTAB) as a cationic surfactant, which is an effective surfactant at higher temperatures, was used to stabilize the miniemulsion system. Successful miniemulsion AGET ATRP was carried out by using 4,4'‐dinonyl‐2,2'‐bipyridine (dNbPy) as a hydrophobic ligand. Formation of monodispersed droplets and particles with sizes in the range of 200nm was examined by dynamic light scattering (DLS). Conversion and molecular weight study were also carried out using gravimetry and gel permeation chromatography, respectively. By adding clay content, a decrease in the conversion and molecular weight of the nanocomposites are observed. However, an increase in the PDI values of nanocomposites was observed by the addition of nanoclay content. Thermogravimetric analysis results demonstrate that thermal stability of all the nanocomposites in comparison with the neat copolymer increases. Differential scanning calorimetry results show that Tg decreases by increasing clay content. Monodisperse distribution of spherical shape particles with sizes in the range of ∼ 200 nm was demonstrated by using scanning electron microscopy images of nanocomposite containing 1 wt% of nanoclay, which is more compiled with DLS results. Transmission electron microscopy results shows well‐dispersed exfoliated clay layers in the polymer matrix of PSMNM 1, which is coincidence with X‐ray diffraction data. POLYM. COMPOS., 2011. © 2011 Society of Plastics Engineers 相似文献
6.
Zohreh Khezri Hajar Shekarchizadeh Milad Fathi 《International Journal of Food Science & Technology》2021,56(5):2255-2263
Opopanax gum/gelatin nanofibre was produced by the electrospinning method, and the efficiency of this new technique for encapsulation of garlic essential oil was investigated. Fourier-transform infrared spectroscopy results showed the physical and weak interactions between opopanax gum and gelatin, as well as the improvement of their thermal stability in the nanofibres structure. Incorporating 10% garlic essential oil based on biopolymer weight in nanofibres was considered the best percentage. The results confirmed the presence of garlic essential oil in the nanofibres and the improvement of its thermal stability by entrapment to the nanofibre structure. The data of analysis of the stability of garlic essential oil in the forms of free and encapsulated conditions showed that its stability increased at 25 °C from 20 days to more than 60 days. It indicated the efficiency of opopanax gum/gelatin nanofibres as an applicable coating material for stability enhancement of essential oils. 相似文献
7.
Khezri Rahmat Golshannavaz Sajjad Shokoohi Shoresh Bevrani Hassan 《Neural computing & applications》2018,30(9):2709-2723
Neural Computing and Applications - Nowadays, the concept of multiple inverter-interfaced distributed generations (IIDGs)-based MG is recognized as a renowned notion. Encountering unexpected... 相似文献
8.
WS2 Nanoparticles: Bipolar Electrochemical Synthesis of WS2 Nanoparticles and Their Application in Magneto‐Immunosandwich Assay (Adv. Funct. Mater. 23/2016)
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9.
10.
Seyed‐Ataollah Mirshafiei‐Langari Vahid Haddadi‐Asl Hossein Roghani‐Mamaqani Masoud Sobani Khezrollah Khezri 《Polymer Composites》2013,34(10):1648-1654
Polystyrene nanocomposite with mixed free and anchored chains was synthesized by atom transfer radical polymerization. Attachment of 3‐(trimethoxysilyl)propyl methacrylate with a double bond on the nanoporous silica aerogel surface results in a double bond grafted silica aerogel which could be incorporated into the polystyrene chains by a grafting‐through process. Conversion and molecular weight evaluation was carried out using gas chromatography and gel permeation chromatography, respectively. Double bond containing silica aerogel has an inconsiderable effect on conversion. There is no considerable discrepancy between the molecular weights of the free and anchored chains. Addition of silica aerogel with pendant CC bonds leads to increase of apparent rate constant of polymerization and also molecular weights. This is mainly because of initiator trapping in silica aerogel pores. Every percent of double bond containing silica aerogel with respect to styrene results in trapping of about 0.08 mol of ethyl alpha‐bromoisobutyrate among the silica pores. POLYM. COMPOS., 34:1648–1654, 2013. © 2013 Society of Plastics Engineers 相似文献