Controlling the initial phase of PECVD growth of vertically aligned carbon nanofibers on TiN

We explore the growth of vertically aligned carbon nanofibers by plasma enhanced chemical vapor deposition, using lithographically defined Ni catalyst seeds on TiN. TiN is selected for being an electrically conducting diffusion barrier suitable for the realization of electronic devices. We show that the rate of Ni diffusion correlates to both the level of oxygen content in the TiN film and to the film resistivity. The synthesis of the nanofibers was characterized using electron microscopy with an emphasis on three growth parameters: substrate temperature, plasma power, and chamber pressure. We propose that a catalyst surface free from carbon deposits throughout the process will induce diffusion-limited growth. The growth will shift towards a supply-limited process when the balance between acetylene, as the effective carbon bearing gas, and atomic hydrogen, as the main etching agent, is skewed in favor of acetylene. This determines whether the dominating growth mode will be vertically aligned ‘tip-type’ or disordered ‘base-type’, by affecting the competition between the formation of the first graphitic sheets on the catalyst surface and at the catalyst-substrate interface.     

Evaluation of Linguistic Features for Word Sense Disambiguation with Self-Organized Document Maps

Word sense disambiguation automatically determines the appropriate senses of a word in context. We have previously shown that self-organized document maps have properties similar to a large-scale semantic structure that is useful for word sense disambiguation. This work evaluates the impact of different linguistic features on self-organized document maps for word sense disambiguation. The features evaluated are various qualitative features, e.g. part-of-speech and syntactic labels, and quantitative features, e.g. cut-off levels for word frequency. It is shown that linguistic features help make contextual information explicit. If the training corpus is large even contextually weak features, such as base forms, will act in concert to produce sense distinctions in a statistically significant way. However, the most important features are syntactic dependency relations and base forms annotated with part of speech or syntactic labels. We achieve 62.9% ± 0.73% correct results on the fine grained lexical task of the English SENSEVAL-2 data. On the 96.7% of the test cases which need no back-off to the most frequent sense we achieve 65.7% correct results.     

Atomistic modelling of the Fe-Cr-C system

For the purpose of modelling the impact of carbon on radiation damage phenomena in steels, we have performed an extensive set of first principle calculations on the Fe-Cr-C system. The calculated solution and diffusion enthalpies of carbon in iron and in chromium agree well with experimental data, as do the relative formation energies of mono-carbides, cementite, Hägg and M₂₃C₆ carbides. Our data further indicate that interstitial carbon is attracted to a solute iron atom in bcc chromium, while the reaction between carbon and a solute chromium atom in bcc iron is repulsive. An empirical potential fitted to data for iron carbides is capable of reproducing melting behaviour of cementite, while the predicted interaction with point defects agrees less well with DFT data than a potential recently published by Hepburn and Ackland.     

Synthesis of mono- and diglycerides in water-in-oil microemulsions

Enzyme-catalyzed esterification was carried out in single-phase, oil-continuous microemulsions. The lipozyme was solubilized, along with glycerol and water, in the aqueous core of water/diethylhexyl sodium sulfosuccinate/hydrocarbon microemulsion system. Upon addition of fatty acid, mono- and diglycerides were formed, due to the esterification reaction taking place at the interface of the droplets in the microemulsion. The initial rate of conversion of oleic acid increases with oil chainlength of the continuous phase whereas final conversion is maximum for hexane. The conversion of stearic acid is 30% whereas conversion of oleic acid is 70%. The percent conversion of various fatty acids in the same continuous medium increases with fatty acid chainlength. The oleic acid/glycerol ratio is an important parameter for optimum conversion of oleic acid into glycerides. The yield can be increased by subsequent addition of glycerol after equilibrium is reached. High-performance liquid chromatography analysis of samples from microemulsions shows the presence of mono- and diglycerides. Possible mechanisms for the abovementioned effects are discussed.     

Evaluation of data sources for mapping glacial meltwater features

The meltwater system of disintegrating ice sheets provides an important source of information for the reconstruction of ice-retreat patterns during deglaciation. Recent method development in glacial geomorphology, using satellite imagery and digital elevation models (DEMs) for glacial landform mapping, has predominantly been focused on the identification of lineation and other large-scale accumulation features. Landforms created by meltwater have often been neglected in these efforts. Meltwater features such as channels, deltas and fossil shorelines were traditionally mapped using stereo interpretation of aerial photographs. However, during the transition into the digital era, driven by a wish to cover large areas more economically, meltwater features were lost in most mapping surveys. We have evaluated different sets of satellite images and DEMs for their suitability to map glacial meltwater features (lateral meltwater channels, eskers, deltas, ice-dammed lake drainage channels and fossil shorelines) in comparison with the traditional mapping from aerial photographs. Several sets of satellite images and DEMs were employed to map the landform record of three reference areas, located in northwestern Scotland, northeastern Finland and western Sweden. The employed satellite imagery consisted of Landsat 7 Enhanced Thematic Mapper Plus (ETM+), Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), Satellite Pour l'Observation de la Terre (SPOT) 5 and Indian Remote Sensing (IRS) 1C, and the DEMs used were from NEXTMap Britain, Panorama, National elevation data set of Sweden and National Land Survey of Finland. ASTER images yielded better results than the panchromatic band of Landsat 7 ETM+?in all three regions, despite the same spatial resolution of the data. In agreement with previous studies, this study shows that DEMs display accumulation features such as eskers suitably well. Satellite images are shown to be insufficiently detailed for the interpretation of smaller features such as meltwater channels. Hence, satellite imagery and DEMs of intermediate resolution contain meltwater system information only at a general level that allows for the identification of landforms of medium to large sizes. It is therefore pertinent that data with an appropriate spatial and spectral resolution are accessed to fulfil the need of a particular mapping effort. Stereo interpretation of aerial photographs continues to be an advisable method for local meltwater system reconstructions; alternatively, it can be replaced by mapping from high-resolution DEMs such as NEXTMap Britain. For regional to sub-continental reconstructions, the use of ASTER satellite imagery is recommended, because it provides both spectral and spatial resolutions suitable for the identification of meltwater features on a medium to large scale.     

Upgrading of Raw Gas from Biomass and Waste Gasification: Challenges and Opportunities

The depletion of fossil fuel-based resources and concerns for increasing emissions of CO₂ call for new ways of producing environmentally-friendly substitutes for motor fuels and chemicals. Thermo-chemical conversion of biomass and waste using gasification is a strong candidate to meet these challenges. For efficient and cost-effective application of this technique, novel solutions for hot gas cleaning are needed. This review highlights some important areas for improvement of upgrading technologies for pressurised fluidised bed gasification systems using biomass as a fuel.     

Ester-based surfactants: Are they stable enough?

Surfactants with an ester bond connecting the polar headgroup and the hydrophobic tail are common. They are easy to synthesize, they can often be made from natural raw materials and their biodegradation profile is generally good, partly due to lipase or esterase catalyzed breakdown of the ester bond in sewage plants. A labile ester bond in the molecule may cause problems, however. Surfactants are often formulated at relatively high pH and it is important that they remain intact for a given period of time. In this article we discuss alkaline hydrolysis of different types of ester-based surfactants—cationic, anionic and nonionic—and also of surfactant mixtures. We show that the ester bond in a surfactant has a different hydrolysis pattern than ester bonds in non-surface active uncharged molecules. Cationic ester-based surfactants are hydrolyzed rapidly while anionic and also nonionic ester-containing surfactants are relatively resistant to hydrolysis.     

Cleavable surfactants

Cleavable surfactants are of interest for several reasons. Above all, the development of surfactants with weak bonds deliberately built into the structure is driven by the need for improved biodegradability of amphiphiles. The breakdown may be catalyzed by enzymes, and biodegradation would be the normal mechanism in sewage plants. Alternatively, the surfactant may degrade by chemical means, e.g., induced by acid, alkali, ultraviolet (UV) light, heat, or ozone. Acid- and alkali-labile surfactants have attracted particular attention, and there is often a compromise between required stability at one stage and ease of breakdown at a subsequent stage. The paper reviews the main routes used to prepare cleavable surfactants and points out advantages and disadvantages of the different approaches. Emphasis is placed on the development during recent years. Cyclic and acyclic acetals, ketals, and ortho esters are the most important types of bonds for the preparation of acid-labile surfactants, whereas alkali-labile amphiphiles usually are based on ester bonds. The ester bond approach has been particularly important for cationic surfactants, and so-called ester quats have rapidly taken a large share of the traditional market for quats. Betaine esters constitute a special class of ester with very pronounced pH dependence. UV-labile surfactants based, for instance, on an azo bond, offer promise for the future.     

Selective determination of lithium and boron in minerals by means of an SSNTD-technique

A method has been worked out to identify lithium and boron in mineral samples by means of a solid state nuclear track detector technique. The samples have been irradiated with thermal neutrons which react with ¹⁰B and ⁶Li and give α-particles of different energies. The ranges of these α-particles in air are measured with the SSNTD-technique and found to be sufficiently different to make identification possible. A number of tests are made and the possibility for determining the distribution and the abundance of lithium and boron in a specific mineral in a rock sample is discussed.