Mg-doped LiNi0.5Mn1.5O4 spinel for cathode materials

Lithium-ion batteries are becoming more and more important not only for portable electronic devices, but also in prevision of high power electric vehicles. In such an optic, deep studies regarding all the components of a secondary battery are in development. In this study, high voltage cathode materials have been selected. Crystals with spinel structure have a 3D vacancy pathway suitable for Li-ions transport. The material under study was LiNi_0.5Mn_1.5O₄ doped with magnesium replacing the nickel. Various samples were synthesized via three different routes: a solid-state method, a modified sol–gel method and a xerogel method. The structure and morphology of the powders were analyzed with HRTEM and XRD. Electrochemical tests were also performed. A wide range of particle sizes (from micro to nanosize) was the result of the different synthesis routes. Unfortunately pure materials were not always obtained. The electrochemical tests showed improvement of the material's cyclability, by reducing the particle size. The electrochemical tests further confirmed the existence of a Li_1+dMn_2−dO₄ impurity. The results are quite promising, however, further improvement of the purity of the electrode composition are needed.     

Promise is Debt, Threat Another Matter: The Effect of Credibility on the Interpretation of Conditional Promises and Threats.

Evidence from reasoning tasks shows that promises and threats both tend to receive biconditional interpretations. They also both display high speaker control. On the face of it, the only difference seems to be the positive or negative signing of the consequent. In a promise, the speaker tries to persuade the hearer to do something by holding out the prospect of a particular reward; in a threat, the speaker tries to refrain the hearer from doing something by holding out the prospect of a particular punishment. This paper investigates the respects in which conditional promises and threats differ further by means of an inference task. The credibility of the consequent was manipulated in order to examine whether the acceptability ratings of inferences based on promises and on threats would be equally affected. The results of the inference task and an analysis of the reasons people give for their answers suggest that the credibility of promises is less affected by the use of excessive consequents than the credibility of threats. In other words, promise remains debt, whereas threat is another matter. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Analytical study of slightly eccentric core–annular flow

An analytical study was conducted on the flow of a rigid core surrounded by an annular liquid layer through a horizontal tube. Special emphasis was placed on the question how the buoyancy force on the core, caused by a possible density difference between the core and the annular layer, is counterbalanced. The analysis was carried out under the following restrictions: Stokes flow (no inertia), gap between the core and tube wall small compared with the tube radius, and eccentricity small compared with the gap between the core and the tube wall. A perturbation calculation was carried out with the amplitude of the wave at the core–annular interface as small parameter. The restoring (levitation) force is due to the viscous force exerted by the azimuthal velocity components on the core.     

A new iterative diakoptics-based multilevel moments method forplanar circuits

This paper combines a multilevel moments method (MMM) scheme with a modified diakoptics (MD) technique and a block Gauss-Seidel (BGS) iterative technique to reduce the solution time of large planar microwave structures. The proposed MMM scheme has two levels. On the lower level, the planar circuit is divided into several subcircuits using two types of artificial ports. At the higher level, general basis functions defined over the complete circuit are generated in an iterative way. The validity and the efficiency of the new technique are validated by several examples, including a large low-pass filter     

Bubble size effect on low liquid input drift-flux parameters

We investigated the effect of bubble size on the drift-flux parameters at low liquid flow conditions by measuring the radial profiles of void fraction and phase velocities in a vertical bubbly pipe flow of diameter and height . To study the effect of the bubble size we used two different types of bubble inlets. We measured the local bubble fraction and velocity U_g by using single and four-point-optical fibre probes, and we used Laser Doppler Anemometry to determine the liquid velocity U_l. The distribution parameter C₀ and the weighted mean drift velocity |U_drift| were directly computed from the local measurements at a height on our experimental set-up. Both parameters were influenced by the bubble size. Provided no liquid flow reversal occurred at the near wall region, the distribution parameter reached a below unity minimum plateau value of C₀=0.95 for wall peaking void fraction profiles. At low liquid input conditions both the liquid input and bubble size had an influence on the distribution parameter. Extreme values such as C₀>2 were measured. From these measurements we developed models for the drift-flux parameters to take into account the effect of bubble size and input-flow conditions for our intermediate pipe diameter value. These models were tested and validated with separately collected experimental data.     

Novel catalytic membranes for selective reactions

A survey is given of the potentials of a new kind of catalytic membranes consisting of a catalyst that is immobilised in a dense polymer matrix. When homogeneous, catalytically active complexes are occluded, these membranes constitute a new way of heterogenation. In the case of solid state catalysts, these composite membranes can improve the activity of the catalyst by changing sorption or by allowing experimental set-ups in which solvents become redundant. This revised version was published online in June 2006 with corrections to the Cover Date.     

Activation and inactivation of Talaromyces macrosporus ascospores by high hydrostatic pressure

The effect of high hydrostatic pressure treatment (with pressures of up to 700 MPa) on Talaromyces macrosporus ascospores was investigated. At 20 degrees C, pressures of > or = 200 MPa induced the activation and germination of dormant ascospores, as indicated by increased colony counts for ascospore suspensions after pressure treatment and the appearance of germination vesicles and tubes. Pressures of > 400 MPa additionally sensitized the ascospores to subsequent heat treatment. At pressures of > 500 MPa, activation occurred in a few minutes but was followed by inactivation with longer exposure. However, even with the most extreme pressure treatment, a fraction of the ascospore population appeared to resist both activation and inactivation, and the maximal achievable reduction of ascospores was on the order of 3.0 log10 units. Pressure-induced ascospore activation at 400 MPa was temperature dependent, with minimum activation at 30 to 50 degrees C and > or = 10-fold higher activation levels at 10 to 20 degrees C and at 60 degrees C, but it was not particularly pH dependent over a pH range of 3.0 to 6.0. Pressure inactivation at 600 MPa, in contrast, was pH dependent, with the inactivation level being 10-fold higher at pH 6.0 than at pH 3.0. Observation of pressure-treated and subsequently dried spores with the use of light and scanning electron microscopy revealed a collapse of the spore structure, indicating a loss of the spore wall barrier properties. Finally, pressure treatment sensitized T. macrosporus ascospores to cell wall lytic enzymes.     

Background and foreground interaction: Influence of complementary colors on the search task

Labels are indispensable visual (communication) elements that completely deliver the geospatial message of maps. The objective of this study is to investigate the impact of complementary colors between the map's background and text on the readability of cartographic texts and thus on the efficiency of the map user's search task. This is compared with the use of the “traditional” black labels on the corresponding colored backgrounds. Furthermore, a number of user characteristics, such as gender and expertise, are taken into account as well. The users' eye movements were registered to study their attentive behavior during the visual search task. In addition to the complement of the color's hue, the analyses were based on the difference in luminance, which could also affect the labels' readability. The difference between the black and colored label design was significantly different versus the eye‐tracking metrics. A correlation was found between the color difference and reaction time measurement and between the luminance difference and fixation duration. © 2014 Wiley Periodicals, Inc. Col Res Appl, 40, 437–445, 2015     

0.9-V DSP blocks: a 15-ns 4-k SRAM and a 45-ns 16-bmultiply/accumulator

4-k SRAM and 16-b multiply/accumulate DSP blocks have been designed and fabricated in complementary heterostructure GaAs. Both circuits operate from 1.5 V to below 0.9 V. The SRAM uses 28,272 transistors in an area of 2.44 mm². Cell size is 278 μm ² at 1.0-μm gate length. Measured results show an access delay of 5.3 ns at 1.5 V and 15.0 ns at 0.9 V. At 0.9 V, the power dissipated is 0.36 mW. The CGaAs multiplier uses a 16-b modified Booth architecture with a 3-way 40-b accumulator. The multiplier uses 11,200 transistors in an area of 1.23 mm². Measured delay is 19.0 ns at 1.5 V and 44.7 ns at 0.9 V. At 0.9 V, current is less than 0.4 mA     

Net flow of compressible viscous liquids induced by travelling waves in porous media

The influence of ultrasonic radiation on the flow of a liquid through a porous medium is analyzed. The analysis is based on a mechanism proposed by Ganiev et al. according to which ultrasonic radiation deforms the walls of the pores in the shape of travelling transversal waves. Like in peristaltic pumping, the travelling transversal wave induces a net flow of the liquid inside the pore. In this article, the wave amplitude is related to the power output of an acoustic source, while the wave speed is expressed in terms of the shear modulus of the porous medium. The viscosity as well as the compressibility of the liquid are taken into account. The Navier–Stokes equations for an axisymmetric cylindrical pore are solved by means of a perturbation analysis, in which the ratio of the wave amplitude to the radius of the pore is the small parameter. In the second-order approximation a net flow induced by the travelling wave is found. For various values of the compressibility of the liquid, the Reynolds number and the frequency of the wave, the net flow rate is calculated. The calculations disclose that the compressibility of the liquid has a strong influence on the net flow induced. Furthermore, by a comparison with the flow induced by the pressure gradient in an oil reservoir, the net flow induced by a travelling wave can not be neglected, although it is a second-order effect.