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Microsystem Technologies - Single-Walled Carbon Nanotubes (SWCNTs) are widely used as potential carriers in drug delivery systems. The objective of this work was to observe the effects of pristine,...  相似文献   
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The Journal of Supercomputing - Hpcfolder is a user-friendly high-performance computing tool that can be used to analyze the performance of algorithms parallelized using MPI. It is possible to view...  相似文献   
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Ionic self‐assembly of charged molecular building blocks relies on the interplay between long‐range electrostatic forces and short‐range, often cooperative, supramolecular interactions, yet has been seldom studied in two dimensions at the solid–liquid interface. Here, we demonstrate anion‐driven switching of two‐dimensional (2D) crystal structure at the Au(111)/octanoic acid interface. Using scanning tunneling microscopy (STM), three organic salts with identical polyaromatic cation (PQPC6+) but different anions (perchlorate, anthraquinonedisulfonate, benzenesulfonate) are shown to form distinct, highly ordered self‐assembled structures. Reversible switching of the supramolecular arrangement is demonstrated by in situ exchange of the anion on the pre‐formed adlayer, by changing the concentration ratio between the incoming and outgoing anion. Density functional theory (DFT) calculations reveal that perchlorate is highly mobile in the adlayer, and corroborate why this anion is only resolved transiently in STM. Surprisingly, the templating effect of the anion persists even where it does not become part of the adlayer 2D fabric, which we ascribe to differences in stabilization of cation conformations by the anion. Our results provide important insight into the structuring of mixed anion–cation adlayers. This is essential in the design of tectons for ionic self‐assembled superstructures and biomimetic adaptive materials and valuable also to understand adsorbate–adsorbate interactions in heterogeneous catalysis.  相似文献   
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Performance evaluation of mathematical expression recognition systems is attempted. The proposed method assumes expressions (input as well as recognition output) are coded following MathML or TEX/LaTEX (which also gets converted into MathML) format. Since any MathML representation follows a tree structure, evaluation of performance has been modeled as a tree-matching problem. The tree corresponding to the expression generated by the recognizer is compared with the groundtruthed one by comparing the corresponding Euler strings. The changes required to convert the tree corresponding to the expression generated by the recognizer into the groundtruthed one are noted. The number of changes required to make such a conversion is basically the distance between the trees. This distance gives the performance measure for the system under testing. The proposed algorithm also pinpoints the positions of the changes in the output MathML file. Testing of the proposed evaluation method considers a set of example groundtruthed expressions and their corresponding recognized results produced by an expression recognition system.  相似文献   
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We study dynamic routing in store-and-forward packet networks where each network link has bounded buffer capacity for receiving incoming packets and is capable of transmitting a fixed number of packets per unit of time. At any moment in time, packets are injected at various network nodes with each packet specifying its destination node. The goal is to maximize the throughput, defined as the number of packets delivered to their destinations. In this paper, we make some progress on throughput maximization in various network topologies. Let n and m denote the number of nodes and links in the network, respectively. For line networks, we show that Nearest-to-Go (NTG), a natural distributed greedy algorithm, is -competitive, essentially matching a known lower bound on the performance of any greedy algorithm. We also show that if we allow the online routing algorithm to make centralized decisions, there is a randomized polylog(n)-competitive algorithm for line networks as well as for rooted tree networks, where each packet is destined for the root of the tree. For grid graphs, we show that NTG has a competitive ratio of while no greedy algorithm can achieve a ratio better than . Finally, for arbitrary network topologies, we show that NTG is -competitive, improving upon an earlier bound of O(mn). An extended abstract appeared in the Proceedings of the 8th Workshop on Approximation Algorithms for Combinatorial Optimization Problems, APPROX 2005, Berkeley, CA, USA, pp. 1–13, Lecture Notes in Computer Science, vol. 1741, Springer, Berlin. S. Angelov is supported in part by NSF Career Award CCR-0093117, NSF Award ITR 0205456 and NIGMS Award 1-P20-GM-6912-1. S. Khanna is supported in part by an NSF Career Award CCR-0093117, NSF Award CCF-0429836, and a US-Israel Binational Science Foundation Grant. K. Kunal is supported in part by an NSF Career Award CCR-0093117 and NSF Award CCF-0429836.  相似文献   
7.
The starting point of our research is the following problem: given a doubling metric ?=(V,d), can one (efficiently) find an unweighted graph G′=(V′,E′) with V?V′ whose shortest-path metric d′ is still doubling, and which agrees with d on V×V? While it is simple to show that the answer to the above question is negative if distances must be preserved exactly. However, allowing a (1+ε) distortion between d and d′ enables us bypass this hurdle, and obtain an unweighted graph G′ with doubling dimension at most a factor O(log?ε ?1) times the doubling dimension of G.More generally, this paper gives algorithms that construct graphs G′ whose convex (or geodesic) closure has doubling dimension close to that of ?, and the shortest-path distances in G′ closely approximate those of ? when restricted to V×V. Similar results are shown when the metric ? is an additive (tree) metric and the graph G′ is restricted to be a tree.  相似文献   
8.
Animals foraging alone are hypothesized to optimize the encounter rates with resources through Lévy walks. However, the issue of how the interactions between multiple foragers influence their search efficiency is still not completely understood. To address this, we consider a model to study the optimal strategy for a group of foragers searching for targets distributed heterogeneously. In our model, foragers move on a square lattice containing immobile but regenerative targets. At any instant, a forager is able to detect only those targets that happen to be in the same site. However, we allow the foragers to have information about the state of other foragers. A forager who has not detected any target walks towards the nearest location, where another forager has detected a target, with a probability exp(−αd), where d is the distance between the foragers and α is a parameter characterizing the propensity of the foragers to aggregate. The model reveals that neither overcrowding (α → 0) nor independent searching (α → ∞) is beneficial for the foragers. For a patchy distribution of targets, the efficiency is maximum for intermediate values of α. In addition, in the limit α → 0, the length of the walks can become scale-free.  相似文献   
9.
The present experimental investigation deals with the transformation of waste plastic into oil in a pyrolysis reactor. A single feed at a rate of 8?kg yielded 675?ml of pyrolytic oil. The physiochemical properties of plastic oil (PO) were found to be within American Society for Testing and Material standards with higher kinematic viscosity and carbon residue. The GC-MS and Fourier Transform Infrared Analysis studies revealed the presence of 14 different compounds in PO. Straight diesel–PO blending was carried out at 15% and 30% in volume ratio. At full-load condition, in-cylinder pressure, rate of pressure rise, rate of heat release and peak pressure were higher for PO30% than straight diesel. The brake thermal efficiency for PO blends was found to be slightly higher than straight diesel with a significant increase in brake-specific fuel consumption. Unburned hydrocarbon (UBHC), CO NO x and smoke emission showed significant variation with PO blends. The physiochemical properties of PO blends significantly affect the engine performance.  相似文献   
10.
Encapsulation of organogels is a novel perspective in the field of controlled drug delivery. This study reports encapsulation of lanolin based organogels within alginate microparticles. The microparticles were prepared by emulsification/internal gelation method. Microscopic studies suggested spherical shape of the microparticles. Fourier transform infrared, X‐ray diffraction and thermal studies confirmed the presence of organogels within the microparticles. Organogels containing microparticles showed improved drug (e.g., salicylic acid and metronidazole) entrapment efficiency. The release of the drugs from the microparticles was dependent on the pH of the dissolution medium. The release was diffusion mediated. The drug loaded microparticles showed antimicrobial activity against E. coli and B. subtilis. The preliminary study suggested that the encapsulation of the organogels may help prolonging the release of the drugs and hence may be tried as vehicles for controlled drug delivery. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40910.  相似文献   
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