可生物降解热熔胶粘剂的研究进展

综述了近年来可生物降解热熔胶的发展、合成、性能、应用、最新的研究进展。     

Application of membrane reactor for dehydrogenation of ethylbenzene

Two types of membrane reactors have been constructed in order to evaluate the influence of membrane reactor configuration on the performance of the dehydrogenation of ethylbenzene in a porous alumina membrane reactor. The type I construction combine reaction and separation in the same space. The type II configuration is comprised of three parts, i.e., reaction prior to separation, reaction and separation, and reaction after separation. The results showed that the overall yield of styrene in Type I is only 4% higher than that of the fixed bed reactor at 893 K, while 11 % enhancement in yield to styrene was obtained with Type II through optimizing the reaction conditions.     

砀山酥梨黑星病综合管理专家系统的设计与实现①

梨黑星病（Venturia pirina）是砀山酥梨最为严重的病害之一,梨种植户每年因为这种病害遭受了很大的损失。随着农业信息化的发展,国内外目前已有很多关于农业专家系统报道,但关于砀山酥梨黑星病综合管理专家系统尚未见报道。在搜集梨黑星病相关资料和领域专家生产实践经验的基础上,结合黄河故道地区砀山酥梨黑星病发生发展的现状,基于CBR和RBR混合推理模式,利用Visual Basic 6．0编程和Photoshop图像处理等软件,开发了砀山酥梨黑星病综合管理专家系统。该系统由“砀山酥梨黑星病预测与防治子系统”和“砀山酥梨黑星病综合防治决策支持子系统”两个子系统构成,系统涵盖内容全面、界面简洁、针对性强、操作容易,可为黄河故道地区农业技术人员和梨种植户在防治梨黑星病实践中提供决策咨询。     

增稠剂PGE的研制

将脂肪酸和聚乙二醇经酯化反应再经复配而成新型非离子表面后性剂ＰＧＥ。ＰＧＥ是洗发香波、各类液体洗涤剂的特效增稠剂，也是纺织业的高效印染助剂￣［１］。本文采用正交试验法确定了脂肪酸与聚乙二醇酯化反应的最佳条件。     

Transient natural convective heat transfer of a low-Prandtl-number fluid from a heated horizontal circular cylinder to its coaxial triangular enclosure

Transient natural convective heat transfer of liquid gallium, which has a Prandtl number of 0.023 at 310 K, from a heated horizontal circular cylinder to its coaxial triangular enclosure is studied numerically by employing the control volume method. Two orientations of the triangular cylinder are investigated and the Grashof number is varied from 10⁴ to 10⁷. Development of natural convection is presented by means of the evolutions of the average Nusselt number over the outer triangular wall. Temporal stages during the course of development are identified and demonstrated through representative snapshots of streamlines and isotherms. The time-averaged Nusselt number is scaled with Grashof number for both conduction- and convection-dominated regimes. It is found that by placing horizontally the top side of the triangular cylinder, the convective flow becomes more stable and the overall heat transfer is enhanced. In addition, pitchfork bifurcation is explored quantitatively and its onset times are predicted as well.     

Transient natural convective heat transfer of a low-Prandtl-number fluid inside a horizontal circular cylinder with an inner coaxial triangular cylinder

A numerical study of transient natural convection of liquid gallium (Pr = 0.023) from a horizontal triangular cylinder to its coaxial cylindrical enclosure is performed. The aspect ratio is fixed at 2 and two positions of the inner triangular cylinder are considered. The development of the convective flow and heat transfer is shown via the time histories of the average Nusselt number over the outer circular wall for various Grashof numbers. Temporal phases of the flow development are identified as: initializing, developing, transitioning, and steady/quasi-steady state or oscillating. Typical flow patterns and temperature distributions at these phases are presented by means of streamlines and isotherms, respectively. Pitchfork bifurcation is present for both positions of the inner triangular cylinder when Gr ? 5 × 10⁴. The time-averaged Nusselt number over the outer circular cylinder, the flow development time, and the onset time of pitchfork bifurcation are predicted and scaled with the Grashof number. It is found that the time-averaged Nusselt number is apparently increased by horizontally placing the top side of the inner triangular cylinder for Gr ? 1 × 10⁵.     

基于多层次优化技术的XACML 策略评估引擎

给出一种采用多层次优化技术的XACML(extensible access control markup language)策略评估引擎实现方案MLOBEE(multi-level optimization based evaluation engine).策略判定评估前,对原始策略库实施规则精化,缩减策略规模并调整规则顺序;判定评估过程中,在引擎内部采用多种缓存机制,分别建立判定结果缓存、属性缓存和策略缓存,有效降低判定引擎和其他功能部件的通信损耗.通过两阶段索引实现的策略缓存,可显著降低匹配运算量并提高策略匹配准确率.仿真实验验证了MLOBEE所采用的多层次优化技术的有效性,其整体评估性能明显优于大多数同类系统.     

A numerical investigation of transient natural convection heat transfer of aqueous nanofluids in a horizontal concentric annulus

A numerical study of transient natural convection heat transfer of aqueous nanofluids in a horizontal annulus between two coaxial cylinders is presented. The effective thermophysical properties of water in the presence of copper oxide nanoparticles with four different volume fractions are predicted using existing models, in which the effects of the Brownian motion of nanoparticles are taken into consideration. The predicted development of convective flow and heat transfer of nanofluids is presented by means of the average Nusselt number over the outer cylinder. The flow development time towards a steady state and the time-averaged Nusselt number are predicted and scaled with Rayleigh number. It is shown that at constant Rayleigh numbers, the time-averaged Nusselt number is gradually lowered as the volume fraction of nanoparticles is increased. In addition, the time-averaged Nusselt number will be overestimated if the Brownian motion effects are not considered.     

基于ISO/IEC 15693无源标签芯片SoC结构分析和防冲撞控制研究

射频识别技术RFID(Radio Frequency Identification)是利用射频信号通过空间耦合实现非接触信息传递并通过所传递的信息达到识别目的的技术,它是自动识别技术在无线电技术方面的具体应用和发展。在HF频段通过线圈耦合磁场载波信号提供能量是RFID最大的特点,大大提高了卡片的使用寿命。文章首先分析了基于ISO/IEC15693协议的无源标签SoC系统结构,主要分析前端电路和数字基带处理电路的模块功能,详细分析了各个分模块的功能参数要求;其次对协议防冲撞指令进行了深入探讨,并基于Slot时隙EOF提出指令操作流程。     

Studies on the curing behavior,thermal, and mechanical properties of epoxy resin-co-amine-functionalized lead phthalocyanine

A high performance copolymer was prepared by using epoxy (EP) resin as matrix and 3,10,17,24-tetra-aminoethoxy lead phthalocyanine (APbPc) as additive with dicyandiamide as curing agent. Fourier-transform infrared spectroscopy, dynamic mechanical analysis (DMA), differential scanning calorimetric analysis (DSC), and thermogravimetric analysis (TGA) were used to study the curing behavior, curing kinetics, dynamic mechanical properties, impact and tensile strength, and thermal stability of EP/APbPc blends. The experimental results show that APbPc, as a synergistic curing agent, can effectively reduce the curing temperature of epoxy resin. The curing kinetics of the copolymer was investigated by non-isothermal DSC to determine kinetic data and measurement of the activation energy. DMA, impact, and tensile strength tests proved that phthalocyanine can significantly improve the toughness and stiffness of epoxy resin. Highest values were seen on the 20 wt% loading of APbPc in the copolymers, energy storage modulus, and impact strength increased respectively 388.46 MPa and 3.6 kJ/m², T_g decreased 19.46°C. TGA curves indicated that the cured copolymers also exhibit excellent thermal properties.