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排序方式: 共有162条查询结果,搜索用时 15 毫秒
1.
Prof. Alessia Carocci Dr. Mariagrazia Roselli Prof. Roberta Budriesi Dr. Matteo Micucci Prof. Jean-François Desaphy Dr. Concetta Altamura Dr. Maria Maddalena Cavalluzzi Dr. Maddalena Toma Dr. Giovanna Ilaria Passeri Dr. Gualtiero Milani Dr. Angelo Lovece Prof. Alessia Catalano Dr. Claudio Bruno Dr. Annalisa De Palma Prof. Filomena Corbo Prof. Carlo Franchini Prof. Solomon Habtemariam Prof. Giovanni Lentini 《ChemMedChem》2021,16(3):578-588
Under the hypothesis that cardioprotective agents might benefit from synergism between antiarrhythmic activity and antioxidant properties, a small series of mexiletine analogues were coupled with the 2,2,5,5-tetramethylpyrroline moiety, known for its antioxidant effect, in order to obtain dual-acting drugs potentially useful in the protection of the heart against post-ischemic reperfusion injury. The pyrroline derivatives reported herein were found to be more potent as antiarrhythmic agents than mexiletine and displayed antioxidant activity. The most interesting tetramethylpyrroline congener, a tert-butyl-substituted analogue, was at least 100 times more active as an antiarrhythmic than mexiletine. 相似文献
2.
Giovanni Capurso Filippo Agresti Laura Crociani Gilberto Rossetto Benedetto Schiavo Amedeo Maddalena Sergio Lo Russo Giovanni Principi 《International Journal of Hydrogen Energy》2012
Several mixtures of LiBH4 and Mg(BH4)2 borohydrides in different stoichiometric ratios (1:0, 2:1, 1:1, 1:2, 0:1), prepared by high energy ball milling, have been investigated with X-ray powder diffraction and thermal programmed desorption (TPD) volumetric analysis to test the dehydrogenation kinetics in correlation with the physical mixture composition. Afterwards mixed and unmixed borohydrides were dispersed on high specific surface area ball milled graphite by means of the solvent infiltration technique. BET and statistical thickness methods were used to characterize the support surface properties, and SEM micrographs gave a better understanding of the preparation techniques. It has been observed by TPD volumetric measurements that the confinement of the reactive borohydrides on the nanoporous supports leads to a lower dehydrogenation temperature compared to unsupported borohydrides. Moreover, a further decrease of the dehydrogenation temperature has been observed by increasing the specific surface area of the support and the pores volume and by using the prepared mixtures instead of pure materials. The dehydrogenation process seems to be favoured by the heterogeneous nucleation on the graphite surface of decomposition products or intermediate phases from melted liquid borohydrides. 相似文献
3.
Francesco Merola Simonetta Grilli Sara Coppola Veronica Vespini Sergio De Nicola Pasquale Maddalena Cosimo Carfagna Pietro Ferraro 《Advanced functional materials》2012,22(15):3267-3272
Investigation on the behavior of nematic liquid crystals on functionalized polar dielectric crystal substrates is accomplished. Very interesting effects can be observed in maneuvering liquid crystal droplets on the substrate surface, driven by electric fields generated by pyroelectric effect. Reversible drops fragmentation and self‐assembling in different configurations can be achieved. The dynamics of the observed phenomena is studied and the repeatability of the process is full assessed. 相似文献
4.
Ultrafine,fine, and black carbon particle concentrations in California child‐care facilities 下载免费PDF全文
F. W. Gaspar R. Maddalena J. Williams R. Castorina Z.‐M. Wang K. Kumagai T. E. McKone A. Bradman 《Indoor air》2018,28(1):102-111
Although many U.S. children spend time in child care, little information exists on exposures to airborne particulate matter (PM) in this environment, even though PM may be associated with asthma and other respiratory illness, which is a key concern for young children. To address this data gap, we measured ultrafine particles (UFP), PM2.5, PM10, and black carbon in 40 California child‐care facilities and examined associations with potential determinants. We also tested a low‐cost optical particle measuring device (Dylos monitor). Median (interquartile range) concentrations for indoor UFP, gravimetric PM2.5, real‐time PM2.5, gravimetric PM10, and black carbon over the course of a child‐care day were 14 000 (11 000‐29 000) particles/cm3, 15 (9.6‐21) μg/m3, 15 (11‐23) μg/m3, 48 (33‐73) μg/m3, and 0.43 (0.25‐0.65) ng/m3, respectively. Indoor black carbon concentrations were inversely associated with air exchange rate (Spearman's rho = ?.36) and positively associated with the sum of all Gaussian‐adjusted traffic volume within a one‐kilometer radius (Spearman's rho = .45) (P‐values <.05). Finally, the Dylos may be a valid low‐cost alternative to monitor PM levels indoors in future studies. Overall, results indicate the need for additional studies examining particle levels, potential health risks, and mitigation strategies in child‐care facilities. 相似文献
5.
Camilla Costa Renzo Di Felice Paolo Moretti Maddalena Oliva Rouzbeh Ramezani 《加拿大化工杂志》2020,98(12):2516-2529
This work is a companion to a previous article, Part I, published in The Canadian Journal of Chemical Engineering, dealing with CO2 absorption in aqueous solutions containing a single aminic reagent (specifically methyldiethanolamine (MDEA) or piperazine (PZ)). In this second part, different PZ/MDEA mixtures are experimentally studied and their performances are compared with that of the single reagents. It is indeed well known that small quantities of PZ added to MDEA aqueous solutions are sufficient to obtain a significant improvement in the kinetics of the process. PZ is considered an activator or promoter for MDEA, but the mechanism of this synergy has still not been clearly demonstrated. The aim of this study is an attempt to understand how PZ and MDEA can interact by experimentally analyzing this beneficial mutual effect and by explaining it with the help of a suitable yet not complex model. We believe that the involved chemistry is not more complex than that reported in Part I for the single reagents. According to our findings, it is MDEA that enhances the action of PZ, as opposed to what many authors claim. Moreover, our results seem to rule out the existence of any PZ shuttle effect. 相似文献
6.
Timothy F. L. McKenna Estevan Tioni Maria Maddalena Ranieri Arash Alizadeh Christophe Boisson Vincent Monteil 《加拿大化工杂志》2013,91(4):669-686
Despite the fact that the very early stages (several tens of seconds) of catalysed olefin polymerisation processes appear negligibly short with respect to the residence time of most industrial reactors, they are critical in terms of catalyst activation, obtaining good particle morphology, and avoiding irreparable problems caused by particle overheating. The different types of reactors that have been used over the course of the past few years are discussed in this feature article. It is shown that despite the difficulties encountered in finding the perfect experimental tool for this purpose, different configurations of stopped flow reactors can be used successfully to explore different aspects of what happens to the catalyst (supported and molecular) during these critical moments of polymerisation. © 2012 Canadian Society for Chemical Engineering 相似文献
7.
M. Verga F. Armanasco C. Guardamagna C. Valli A. Bianchin F. Agresti S. Lo Russo A. Maddalena G. Principi 《International Journal of Hydrogen Energy》2009
A research program addressed to evaluate the magnesium hydride storage scaling up effects is being developed by CESI RICERCA, Milano, and the Hydrogen Group of Padova University. A storage device containing 500 g of magnesium hydride powder (manufactured by Venezia Tecnologie S.p.A. using high-energy ball milling) has been designed and tested in different operating conditions. A number of absorption and desorption cycles at different temperatures and pressures has been carried out in order to see if the results are comparable with laboratory data obtained on small amounts (fractions of grams) of powder samples. A sensible performance degradation that reduced the overall storage capacity of about 50% has been noticed after 20 cycles, presumably due to local powder heating, fragmentation and subsequent compaction. Further tests on a smaller tank equipped also with a porous baffle gave useful indications for the design of an improved large hydrogen reservoir. 相似文献
8.
9.
Since the beginning of the 20th century, in Italy as in many other countries, reinforced concrete (RC) became one of the most popular construction materials and it was used for buildings, monuments, infrastructures, etc. Several of these structures, although of recent formation, have now been included in the cultural heritage, because of their architectural or social relevance. As a consequence of the typical urban or rural exposure conditions of these buildings, they often suffer damage due to carbonation‐induced corrosion of reinforcement, such as concrete spalling or cracking or rust stains that may affect the serviceability of structures. Furthermore, chloride‐induced corrosion of reinforcement, may also concern buildings exposed to de‐icing salts or marine environments. Due to strict requirements related to the preservation of the original materials and texture, the repair of structures that belong to the cultural heritage cannot rely on the conventional repair technique, based on the replacement of carbonated concrete. Therefore, the conservation of RC buildings of the cultural heritage is a challenge, since it requires the development of specific strategies aimed at finding the best compromise between, on one hand, the restoration of structural safety and the prevention of future damage and, on the other hand, the preservation of the original materials and surfaces. This paper analyses the results of inspections carried out on several buildings, built in Italy throughout the 20th century in different micro‐ and macro‐climates, with the aim of showing their peculiarities with regard to steel corrosion and the selection of restorations strategies. 相似文献
10.
Effects of ventilation rate per person and per floor area on perceived air quality,sick building syndrome symptoms,and decision‐making 下载免费PDF全文
R. Maddalena M. J. Mendell K. Eliseeva W. R. Chan D. P. Sullivan M. Russell U. Satish W. J. Fisk 《Indoor air》2015,25(4):362-370
Ventilation rates (VRs) in buildings must adequately control indoor levels of pollutants; however, VRs are constrained by the energy costs. Experiments in a simulated office assessed the effects of VR per occupant on perceived air quality (PAQ), Sick Building Syndrome (SBS) symptoms, and decision‐making performance. A parallel set of experiments assessed the effects of VR per unit floor area on the same outcomes. Sixteen blinded healthy young adult subjects participated in each study. Each exposure lasted four hours and each subject experienced two conditions in a within‐subject study design. The order of presentation of test conditions, day of testing, and gender were balanced. Temperature, relative humidity, VRs, and concentrations of pollutants were monitored. Online surveys assessed PAQ and SBS symptoms and a validated computer‐based tool measured decision‐making performance. Neither changing the VR per person nor changing the VR per floor area, had consistent statistically significant effects on PAQ or SBS symptoms. However, reductions in either occupant‐based VR or floor‐area‐based VR had a significant and independent negative impact on most decision‐making measures. These results indicate that the changes in VR employed in the study influence performance of healthy young adults even when PAQ and SBS symptoms are unaffected. 相似文献