Mode choice modeling is probably the most important element of transportation planning. It affects the general efficiency of travel and the allocation of resources. The development of mode choice models has recently witnessed significant advances in many fields, such as passenger and freight transport. A large number of mathematical models have been used to model the traveler’s choice of mode and destination and the shipper’s choice of mode, shipment size and supply market, among others. Such models are not only becoming almost intractable but also data intensive, difficult to calibrate and update, and intransferable. These models cover a wide range of mathematical complexity and accuracy. This paper describes a new approach to mode choice of intercity freight transport modeling using artificial neural networks (ANNs) and adaptive neuro-fuzzy inference system (ANFIS) models. The new approach combines the learning ability of artificial neural networks and the transparent nature of fuzzy logic. The approach is found to be highly adaptive and efficient in investigating non-linear relationships among different variables. The adaptive neuro-fuzzy inference system model is tested on the freight transport market in Turkey, Germany, France and Austria by using information on the freight flows and their attributes. The ANNs and ANFIS models are more successful in the representation of the non-linear behavior of mode choice of intercity freight transport compared to the classical models. 相似文献
The dissolution kinetics of colemanite, a boron-containing mineral, in aqueous disodium EDTA solutions were studied. The effects
of concentration and pH of the solution, particle size, and temperature were examined. A decrease in pH and particle size
increased the dissolution rate, while an increase in the concentration of the solution and temperature increased the rate.
The activation energy and pre-exponential factor were calculated as 50.6 kJ mol-1 and 5.14 x 107 m s-1, respectively.
Mahir Alkan, Assistant Professor, formerly with Atatürk University, Kazim Karabekir Faculty of Education 相似文献
In this research, we studied the mating tolerance of various plug-in cable connectors and provide a mating tolerance dataset of 70 different connectors. This dataset will be highly advantageous to industries for wire harness assembly tasks using robots. Understanding the mating tolerance is crucial for automating the mating process because it is closely related to the control specifications of a robotic manipulator. Our system uses a 2-finger Robotiq adaptive gripper attached to a 6 degree-of-freedom industrial robot (ABB Robotics) to test the mating process of wire harness assembly tasks. In addition, we use 70 types of wire harness connectors with different numbers of pins widths, lengths, and thicknesses, and various shapes, to test the mating tolerance. The results indicate that the connector mating tolerance of our dataset is more generous than the repeatability of conventional industrial manipulators, and further demonstrate the suitability of the position control methods to wire harness assembly tasks.
The adsorption of PAM onto sepiolite from aqueous solutions has been investigated systematically as a function of some parameters such as calcination temperature of sepiolite, pH, ionic strength and temperature. The adsorption of cationic polyacrylamide (PAM) increases with pH from 5.50 to 11.00, temperature from 25 to 55 degrees C and ionic strength from 0 to 0.1molL(-1). The sepiolite sample calcined at 200 degrees C has a higher adsorption capacity than the other calcined samples. Adsorption isotherms of PAM onto sepiolite have been determined and correlated with common isotherm equations such as Langmuir and Freundlich isotherm models. The Langmuir isotherm model appeared to fit the isotherm data better than the Freundlich isotherm model. The physical properties of this adsorbent are consistent with the parameters obtained from the isotherm equations. The zeta potentials of sepiolite suspensions have been measured in aqueous solutions of NaCl and different PAM concentrations and pH. From the experimental results: (i) pH strongly alters the zeta potential of sepiolite, (ii) sepiolite has an isoelectric point at about pH 6.6 in water and about pH 8 in 250mgL(-1) PAM concentration, (iii) PAM changes the interface charge from negative to positive for sepiolite. Effect of temperature on adsorption has been quantified by calculating various thermodynamic parameters such as Gibbs free energy, enthalpy and entropy. The dimensionless separation factor (R(L)) has shown that sepiolite can be used for adsorption of PAM from aqueous solutions. 相似文献
ABSTRACTGluten contamination in manufactured gluten-free foods (mGFFs) is a major health, well-being and economic issue worldwide for both mandatory and voluntary GFF-consumers. Although scarce, a number of surveys have shown that up to 21.5 % of mGFFs in circulation in the market are contaminated with gluten. However, at the present time there is no published work reporting gluten contamination in mGFFs produced in Turkey. In this paper miscellaneous mGFFs produced in Turkey were analysed for gluten concentration (G) to fill this knowledge gap, and to compare the situation in Turkey with worldwide efforts on this issue. A total of 200 mGFFs from 8 product categories (snack, pasta, bread, cookie, cracker, farina, traditional and others), and manufactured using 7 main ingredients (cereal mixture, buckwheat, corn, rice, locust bean, potato, and others) were analysed. A significant portion of mGFFs (17.5 %) were contaminated with gluten and therefore unacceptable as being GFF. The results point to buckwheat as the main cause of this contamination. If buckwheat is excluded, the ratio of unacceptable mGFFs dramatically decreases to 6.3 % and probably to 1.8 %, which are comparable figures to those reported for other countries. Almost all countries are subjected to the same regulations on GFFs, and the problem of gluten contamination could readily be solved to a great extent if pre-market measures are mandated. Enforcing mGFF-producers to screen their raw materials and final products to detect the presence of gluten, and preventing the release of contaminated mGFFs into the market would be a practical measure in favour of all stakeholders involved in GFF-consumption. 相似文献
The removal of copper ions from aqueous solutions by kaolinite was investigated by using a batch-type method. Effects of factors such as pH, ionic strength, temperature, acid-activation and calcination on copper adsorption were investigated. The uptake of copper was determined from changes in concentration as measured by atomic absorption spectrometry. The extent of copper adsorption increased with increasing pH and temperature and with decreasing ionic strength, acid-activation and calcination temperature. The Langmuir and Freundlich adsorption models were used to determine the isotherm parameters associated with the adsorption process. The results provide support for the adsorption of copper ions onto kaolinite. Thermodynamic parameters indicated the endothermic nature of copper adsorption on kaolinite. The experimental results were applied a batch design. As a result, the kaolinite may be used for removal of copper ions from aqueous solutions. 相似文献
There is a great potential of woody hazelnut shell to use in some applications. Sorption studies are one of these. For this reason in this paper, batch adsorption of Cu(2+) ions onto hazelnut shells was studied. The capacity of the adsorption for the removal of copper ions from aqueous solution was investigated under different conditions such as solution contact time (1-360 min), particle size (0-75, 75-150 and 150-200 microm), temperature of solution (25-60 degrees ) and solution pH (3-7). Moreover, zeta potential of particles at different initial pHs (2-10) was measured. The equilibrium data were processed according to Langmuir and Freundlich's models and higher adsorption capacity values towards Cu(2+) ions were shown. The adsorption kinetics was investigated and the best fit was achieved by a second-order equation. 相似文献
The solubility of chlorine in aqueous hydrochloric acid solutions was studied. The effects of HCl concentration and temperature on the solubility were evaluated, and the thermodynamic parameters of the dissolution were calculated. It was found that the solubility isotherms had a minimum at about 0.5M HCl concentration at all the temperatures studied and that solubility decreased with the increase of temperature at all the HCl concentration range investigated. 相似文献