Oleic acid-coated superparamagnetic iron oxide nanoparticles (Fe3O4) encapsulated within poly(d,l-lactide-co-glycolide) (PLGA) particles were prepared by the w/o/w emulsion technique using poly(vinyl alcohol) as a dispersant. The concentration of PLGA in the oil phase was varied (5, 15, 30, 45, and 60?mg/ml) at constant magnetite concentration in the oil phase (5?mg/ml) to study the properties of composite Fe3O4–PLGA nanoparticles. Even though PLGA concentration varied widely in the oil phase, the weight percent of 7–16?nm diameter magnetite in the particles varied only from 56 to 62?% (23–28?vol.%). The obtained composite nanoparticles were essentially spherical with magnetite spatially uniformly dispersed in individual PLGA particles, as measured by transmission electron microscopy (TEM). Also, the magnetite concentration in each particle did not vary widely as determined qualitatively via microscopy. Hydrodynamic diameters of the composite nanoparticles as measured by dynamic light scattering increased by approximately 10?% with added magnetite, with a smaller relative increase in diameter measured by TEM. The zeta potential of the particles was about ?26?mV, independent of Fe3O4 loading. Relatively high saturation magnetizations (36–45?emu/g) were measured for these highly loaded particles, with the latter value only 7?emu/g lower than the value measured for the oleic acid-coated particles alone. 相似文献
Rheology of blends of polyamide 6 with low-density polyethylene compatibilized with sodium-, zinc-,
and lithium-neutralized ethylene-methacrylic acid ionomers were investigated at 11, 33 and 55% neutralization
of ionomer. Blends of polyamide 6 with low-density polyethylene without compatibilizer had lower shear
viscosities than a mixing rule would predict. After adding compatibilizer, the shear viscosity of the blend
is increased, presumably due to the formation of graft copolymer from the reaction of the primary amine
with free acid groups. The increase of shear and elongational viscosity properties is less with EMAA than
with the ionomers; which is consistent with mechanical property and dispersed phase size results presented
in an earlier publication. For high polyamide 6 content blends, zinc-neutralized compatibilizers yielded
the highest shear and elongational viscosities; while for low polyamide 6 contents, lithium-neutralized
compatibilizers yielded the highest viscosities. 相似文献
Summary: In the present contribution, polyamide‐6 (PA‐6) solutions were prepared in various pure and mixed‐solvent systems and later electrospun with the polarity of the emitting electrode being either positive or negative. The PA‐6 concentration in the as‐prepared solutions was fixed at 32% w/v. Some of the solution properties, i.e., shear viscosity, surface tension, and conductivity, were measured. Irrespective of the polarity of the emitting electrode, only the electrospinning of PA‐6 solution in formic acid (85 wt.‐% aqueous solution) produced uniform electrospun fibers, while solutions of PA‐6 in m‐cresol or sulfuric acid (either 20 or 40 wt.‐% aqueous solution) did not. In the mixed‐solvent systems, formic acid (85 wt.‐% aqueous solution) was blended with m‐cresol, sulfuric acid (either 20 or 40 wt.‐% aqueous solution), acetic acid, or ethanol in the compositional range of 10–40 vol.‐% (based on the amount of the minor solvent). Generally, the average fiber diameter increased with increasing amount of the minor solvent or liquid. Interestingly, the diameters of the fibers obtained under the negative electrode polarity were larger than those obtained under the positive one.
Optical images of electrospun fibers from solutions of polyamide‐6 in a mixed solvent of 85 wt.‐% formic acid and 20 vol.‐% m‐cresol under positive (left) and negative (right) electrode polarity. 相似文献
Blends of polyamide-6 (PA-6) and high-density polyethylene (HDPE) with blend ratios of 80/20 (wt/wt) and 20/80 (wt/wt) were studied using zinc-neutralized maleic anhydride (MAH) grafted HDPE as compatibilizers. MAH groups were hydrolyzed and neutralized with different amounts of zinc acetate dihydrate in a twin-screw extruder to produce different levels of zinc-neutralization (0, 14, 41, 69, and 95 %) at one and ten parts per hundred of resin of compatibilizer. Melt neutralization of MAH was confirmed by X-ray fluorescence, FT–IR, and rheological properties. SEM micrographs showed a large reduction in the dispersed phase size in the compatibilized blends. Tensile measurements showed improvement of tensile strength for all compatibilized blends; moreover, the elongation at break of compatibilized blends at 10 phr of compatibilizer was improved. Blending increased the crystallization temperature for the PA-6, and the addition of compatibilizer reduced the crystallization temperature slightly. A significant increase in melt viscosity of the compatibilizer was found with zinc addition and adding compatibilizer increased the viscosity of the blends. However, the addition of zinc to the compatibilizer did not change the viscosity in the PA-6-rich blends and actually led to a decrease in viscosity in the HDPE-rich blends. 相似文献
ABSTRACT Appropriate strategy for drying chopped spring onion with a batchwise flat bed was investigated. Both experimental and simulated results such as product quality, drying capacity and energy consumption were taken into consideration. For simulation work, equations of drying parameters such as specific heat, equilibrium moisture content and thin layer drying were first developed from the lab-scale experimental results. Then a mathematical model including shrinkage for a batchwix flat bed drying was developed. The model was lested with the results obtained from a food processing plant with an acceptable accuracy. Appropriate drying strategy war then investigated. The approximate conclusion was that the drying should be devided into 3 stages. In the 1st stage, drying air temperature was 80°C, specific air flow rate was 33.9 m3/min -kg dry matter and drying time was 0.5 h. In the 2nd stage, drying air temperature and drying time were kept unchanged but specific air flow rate was decreased to 13.5 m3/min - kg dry matter. In the final stage, drying air temperature was decreased to 67°C, specific air flow rate was also decreased to 6.8 m3/min - kg dry matter and drying time was approximately 1.7 h. Following the suggested strategy, specific primary energy cornsumption was 6.2 MJ/kg H2O, drying time was 2.7 h and product quality was maintained. It was proven that energy consumption was approximalcly 70% of that of the present practice in the plant. 相似文献