Highly efficient synthesis of coumarin derivatives in the presence of H14[NaP5W30O110] as a green and reusable catalyst

A variety of heteropolyanions including: Keggin, Dawson, Preyssler, mixed addenda and sandwich types, catalyzed the formation of 4-methylnaphtho-(1,2-b)-pyran-2-one (coumarin) from the condensation of α-naphthol and ethylacetoacetate in a solvent free system and under heating conditions. Our data vividly indicate that sodium30–tungsto pentaphosphate, [NaP₅W₃₀O₁₁₀]¹⁴⁻, which so-called Preyssler’s anion, with high hydrolytic (pH 0–12) and thermal stability is the catalyst of choice. This catalyst catalyzed the synthesis of other coumarin derivatives in high yields and good selectivity.     

Linear-time snapshot implementations in unbalanced systems

Anatomic snapshot memory object in shared memory systems enables a set of processes, calledscanners, to obtain a consistent picture of the shared memory while other processes, calledupdaters, keep updating memory locations concurrently. In this paper we present two conversion methods of snapshot implementations. Using the first conversion method we obtain a new snapshot implementation in which the scan operation has linear time complexity and the time complexity of the update operation becomes the sum of the time complexities of the original implementation. Applying the second conversion method yields similar results, where in this case the time complexity of the update protocol becomes linear. Although our conversion methods use unbounded space, their space complexity can be bounded using known techniques. One of the most intriguing open problems in distributed wait-free computing is the existence of a linear-time implementation of this object. Using our conversion methods and known constructions we obtain the following results:

?Consider a system ofn processes, each an updater and a scanner. We present an implementation in which the time complexity of either the update or the scan operation is linear, while the time complexity of the second operation isO(n logn).

?We present an implementation with linear time complexity when the number of either updaters or scanners isO(n/logn), wheren is the total number of processes.

?We present an implementation with amortized linear time complexity when one of the protocols (either upate or scan) is executed significantly more often than the other protocol.

     

Fuzzy Bayesian system reliability assessment based on Pascal distribution

The main purpose of this paper is to provide a methodology for discussing the fuzzy. Bayesian system reliability from the fuzzy component reliabilities, actually we discuss on the Fuzzy Bayesian system reliability assessment based on Pascal distribution, because the data sometimes cannot be measured and recorded precisely. In order to apply the Bayesian approach, the fuzzy parameters are assumed as fuzzy random variables with fuzzy prior distributions. The (conventional) Bayes estimation method will be used to create the fuzzy Bayes point estimator of system reliability by invoking the well-known theorem called ‘Resolution Identity’ in fuzzy sets theory. On the other hand, we also provide the computational procedures to evaluate the membership degree of any given Bayes point estimate of system reliability. In order to achieve this purpose, we transform the original problem into a nonlinear programming problem. This nonlinear programming problem is then divided into four sub-problems for the purpose of simplifying computation. Finally, the sub problems can be solved by using any commercial optimizers, e.g. GAMS or LINGO.     

Experimental investigation on the stability of bride girder against tsunami forces

Bridges are the most useful part in the transportation network. Any disruption of the bridge structures may hamper the whole transportation system. In the last recent tsunamis, numerous number of bridges were structurally damaged by the tsunami waves. Lack of proper provisions of tsunami forces in the design guidelines also contributes to the augmentations of the damage level. Therefore, proper evaluation of the tsunami forces on the bridge girder should be introduced in the design promptly. In this study, laboratory experiments were carried out to reveal the damage mechanism of the bridge girder by assessing the exerted tsunami forces. Both broken and unbroken waves were considered for the analysis. The results showed that measured forces were larger for broken waves than those of unbroken waves. Maximum force of the broken waves was 4.59 times as large as the hydrostatic pressure. Also, waves reached the peak value more rapidly for larger wave heights than those of smaller ones. Additionally, a girder that is placed at a higher position is much vulnerable to tsunami hazard.     

An elliptical disc anchor in a damage‐susceptible poroelastic medium

A flat rigid elliptical anchorage located in a damage‐susceptible fluid‐saturated poroelastic medium is subjected to an in‐plane load, which induces a pure translation in the plane of the anchor. This paper develops computational estimates for the time‐dependent displacement of the disc anchor for the classical problem that involves Biot consolidation and compares the results with situations where the porous skeleton can experience micro‐mechanical damage that leads to an alteration in both its elasticity and fluid transport characteristics. Copyright © 2005 John Wiley & Sons, Ltd.     

Thermal–economic–environmental analysis and multi-objective optimization of an internal-reforming solid oxide fuel cell–gas turbine hybrid system

In this article, an internal-reforming solid oxide fuel cell–gas turbine (IRSOFC–GT) hybrid system is modeled and analyzed from thermal (energy and exergy), economic, and environmental points of view. The model is validated using available data in the literature. Utilizing the genetic algorithm optimization technique, multi-objective optimization of modeled system is carried out and the optimal values of system design parameters are obtained. In the multi-objective optimization procedure, the exergy efficiency and the total cost rate of the system (including the capital and maintenance costs, operational cost (fuel cost), and social cost of air pollution for CO, NO_x, and CO₂) are considered as objective functions. A sensitivity analysis is also performed in order to study the effect of variations of the fuel unit cost on the Pareto optimal solutions and their corresponding design parameters. The optimization results indicate that the final optimum design chosen from the Pareto front results in exergy efficiency of 65.60% while it leads to total cost of 3.28 million US$ year⁻¹. It is also demonstrated that the payback time of the chosen design is 6.14 years.     

Grain Refinement by Cyclic Displacive Forward/Reverse Transformation in Fe-High-Ni Alloys

A novel method for grain refinement of martensite structures was proposed, in which transformation strain is accumulated by cyclic displacive forward and reverse transformations. This method can refine martensite structures in an Fe-18Ni alloy because a high density of austenite dislocations is introduced by a displacive reverse transformation in addition to an inheritance of dislocations in body-centered cubic martensite into austenite during cyclic transformation. The addition of a small amount of carbon accelerates structure refinement significantly, which results in the formation of ultra-fine-grained structures after ten cycles.

     

A novel multilayer AAA model for integrated applications

Neural Computing and Applications - Nowadays, one of the problems in current authentication, authorization and accounting (AAA) model is lack of accurate roadmap of access management in integrated...