Sustainable Synthesis of Biaryls Using Silica Supported Ferrocene Appended N-Heterocyclic Carbene-Palladium Complex

Catalysis Letters - A novel silica supported ferrocene appended N-heterocyclic carbene-palladium complex (SilFemBenzNHC@Pd) has been prepared and characterized by using fourier transform infrared...     

Delay composition in preemptive and non-preemptive real-time pipelines

Uniprocessor schedulability theory made great strides, in part, due to the simplicity of composing the delay of a job from the execution times of higher-priority jobs that preempt it. In this paper, we bound the end-to-end delay of a job in a multistage pipeline as a function of job execution times on different stages under preemptive as well as non-preemptive scheduling. We show that the end-to-end delay is bounded by that of a single virtual “bottleneck” stage plus a small additive component. This contribution effectively transforms the pipeline into a single stage system. The wealth of schedulability analysis techniques derived for uniprocessors can then be applied to decide the schedulability of the pipeline. The transformation does not require imposing artificial per-stage deadlines, but rather models the pipeline as a whole and uses the end-to-end deadlines directly in the single-stage analysis. It also does not make assumptions on job arrival patterns or periodicity and thus can be applied to periodic and aperiodic tasks alike. We show through simulations that this approach outperforms previous pipeline schedulability tests except for very short pipelines or when deadlines are sufficiently large. The reason lies in the way we account for execution overlap among stages. We discuss how previous approaches account for overlap and point out interesting differences that lead to different performance advantages in different cases. Further, we also show that in certain cases non-preemptive scheduling can result in higher system utilization than preemptive scheduling in pipelined systems. We hope that the pipeline delay composition rule, derived in this paper, may be a step towards a general schedulability analysis foundation for large distributed systems.

A silicone-based microfluidic chip grafted with carboxyl functionalized hyperbranched polyglycerols for selective protein capture

A poly(dimethylsiloxane) (PDMS)-based functional microfluidic device containing a charged matrix of PDMS pillar arrays grafted with hyperbranched polyglycerols (HPGs) was developed. Samples of PDMS were modified with allylamine plasma to form amine groups on the surface prior to the covalent grafting of succinimdyl ester-functionalized HPGs. The anionic functionality of the PDMS channel matrices was developed by altering the number of carboxyl groups present on the HPGs. The grafting of HPGs onto PDMS plates was investigated via contact angle measurement and attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), while the grafting of the inside channel was investigated by electroosmotic flow (EOF) measurements. The charge density on grafted HPG was optimized to minimize the nonspecific protein adsorption and increase the selective capture of positively charged proteins. A proof-of-concept device was fabricated on PDMS and demonstrated that the device selectively captures positively charged protein (avidin) from a mixture of bovine serum albumin (BSA)-avidin at pH 7.4 in phosphate buffered saline (PBS). In order to increase the capture efficiency of the proteins in this PDMS-based device, pillar arrays have been fabricated within the channel. As a demonstration, the new device separated two proteins with an avidin capture efficiency of 100 ± 2.95% per 3 min from a 0.02 mg/ml protein solution (avidin:BSA wt ratio: 1:1). This new microfluidic-based device shows a great deal of promise as a tool for protein capture and analysis.     

Providing reliable and link stability‐based geocasting model in underwater environment

This paper presents a geocast technique for underwater sensor networks. The model named as Routing and Multicast Tree based Geocasting (RMTG) (TRACE'10, Bhopal, India, 2010; ICWET'10, Mumbai, India, 2010) has been designed for underwater sensor networks. In our previous work (TRACE'10, Bhopal, India, 2010; ICWET'10, Mumbai, India, 2010) we proposed only a theoretical model for underwater geocasting. The RMTG technique uses greedy forwarding and previous hop handshaking to route the packets towards the geocast region and further disseminates the data within the geocast region by creating a multicast shortest path tree. We also presented various link broken scenarios along with their solutions. The proposed model does not use the flooding technique to deliver the packets inside the geocast region that is used in most of the geocasting techniques. In this paper, we present the simulated RMTG model. The simulation results show that the proposed model provides an efficient distribution of data in the geocast region in terms of node mobility handling, packet delivery ratio and a better end‐to‐end latency. Most of the work on geocasting has been done for mobile and vehicular ad hoc networks; hence we present in this paper a novel simulated model for underwater environment. Copyright © 2011 John Wiley & Sons, Ltd.     

Electrochemical corrosion and materials properties of reactively sputtered TiN/TiAlN multilayer coatings

TiN/TiAlN multilayers of 2 μm thickness were successfully prepared by reactive DC magnetron sputtering method. XRD pattern showed the (1 1 1) preferential orientation for both TiN and TiAlN layers. XPS characterization showed the presence of different phases like TiN, TiO₂, TiON, AlN and Al₂O₃. Cross sectional TEM indicated the columnar growth of the coatings. The average RMS roughness value of 4.8 nm was observed from AFM analysis. TiN/TiAlN coating showed lower friction coefficient and lower wear rate than single layer coatings. The results of electrochemical experiments indicated that a TiN/TiAlN multilayer coating has superior corrosion resistance in 3.5% NaCl solution.     

A Comparison of Reliability Growth Models

A reliability growth model is an analytic tool that accounts for changes in reliability due to design modifications and other corrective actions taken during the develpment, production, and use of a new piece of equipment. This paper describes a simulation study, and its conclusions, comparing four general reliability growth models that have been proposed in the reliability literature. Details of the simulation results are available in a separate Supplement.     

Health and wellness monitoring through wearable and ambient sensors: exemplars from home-based care of elderly with mild dementia

Monitoring and timely intervention are extremely important in the continuous management of health and wellness among all segments of the population, but particularly among those with mild dementia. In relation to this, we prescribe three design principles for the construction of services and applications. These are ambient intelligence, service continuity, and micro-context. In this paper, we provide three exemplars from our research and development activities that illustrate the use of these design principles in the construction of services and applications. All the applications are drawn from the field of care for mild dementia patients in their living quarters.     

Evaluation of connection flexibility in cold formed steel racks

Steel storage racks are three-dimensional framed structures fabricated from cold formed steel sections, wherein hook-in end connectors are used to make beam-column connections which are basically boltless and semi-rigid in nature. Different types of beam end connectors with different geometry of the connected members are available, making it impossible to develop a generalized analytical model. Only very few theoretical models are available to evaluate the performance of the joints for some typical connectors. More often experimental evaluation and numerical studies are needed to predict the behaviour of every different type of connectors. In the present study eighteen experiments were conducted on a commercially available pallet rack connection by varying the most influencing parameters such as thickness of the column, depth of the connector and the depth of the beam. The main objective of this work is to quantify the beam to column joint, flexibility of commonly used pallet rack frame and to develop a general Frye-Morris type/three parameter power model type moment versus relative rotation relationship. A companion finite element shell model that simulates the experimental behaviour closely is developed using ABAQUS finite element software, which is also used for further parametric studies. Using the three major variables as size parameters, a Frye-Morris type of equation has been proposed. Some calibration studies have also been carried out. Using the ultimate moment capacity, initial connection stiffness and the shape parameter obtained, a three parameter power model has also been proposed to represent the moment-rotation behaviour of the boltless connections.