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1.
Supported metal catalysts, particularly noble metals supported on SiO2, have attracted considerable attention due to the importance of the silica–metal interface in heterogeneous catalysis and in electronic device fabrication. Several important issues, e.g., the stability of the metal–oxide interface at working temperatures and pressures, are not well-understood. In this review, the present status of our understanding of the metal–silica interface is reviewed. Recent results of model studies in our laboratories on Pd/SiO2/Mo(1 1 2) using LEED, AES and STM are reported. In this work, epitaxial, ultrathin, well-ordered SiO2 films were grown on a Mo(1 1 2) substrate to circumvent complications that frequently arise from the silica–silicon interface present in silica thin films grown on silicon. 相似文献
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In colloidal suspensions of silica, particles undergo constant collisions. By controlling various parameters, the repulsive barrier can be reduced, thereby substantially increasing the number of collision‐induced dimerization events. Xia and co‐workers report on p. 1627 that the dimers could be arrested and then permanently fixed by introducing a small amount of fresh tetraethylorthosilicate into the colloidal suspension, with monodisperse dimer yields of up to 50 %. This yield could be increased to 80 % by centrifugation in a density gradient medium. When fresh tetraethylorthosilicate is introduced into a colloidal suspension of silica spheres, it hydrolyzes and condenses in situ to arrest and fix the dimers resulting from constant collisions between the spheres. By optimizing the experimental parameters (including the length of aging time) and the diameter of the silica spheres, as well as the concentrations of counterions, water, and ammonia, it is possible to routinely produce monodisperse dimers with a yield as high as 50 %. When combined with centrifugation using a density gradient medium, the yield of such dimers could be further increased to 80 %. It is believed that this method will provide a simple and versatile approach to the high‐volume production of dimers from spherical colloids composed of different materials. These dimers may find widespread use in a range of applications such as fabrication of photonic crystals and fundamental studies related to colloidal science. 相似文献
4.
含硫化氢气井钻井过程中的腐蚀因素与防护研究 总被引:1,自引:0,他引:1
在含硫气井的钻井过程中对于HRC大于22的钻具钢材除了腐蚀疲劳之外,在pH值小于9的环境中会发生硫化物应力腐蚀破裂,这种破坏比腐蚀疲劳更突然、更快,使钻杆大量损坏。含硫气井在钻井过程中,由于湿硫化氢的出现,常常会出现油管、套管、钻井设备、钻井仪器以及对支持保护管柱的水泥环柱等腐蚀和损坏问题,为此,阐述了湿硫化氢的腐蚀特点、机理,归纳总结了影响腐蚀的因素,综述了如何在这些方面防止其腐蚀,使损失减小,为指导油管、套管防腐工程实践提供了依据。建议在钻井过程中采用碱性钻井液,其pH值可到9或更高(至pH值12),以减缓或防止钻井过程中电化学从硫化物应力腐蚀破裂;含硫气井用的钻杆应该间歇使用。钻杆停用堆置时间可使其放氢,使钻杆恢复韧性,防止硫化物应力腐蚀断裂。 相似文献
5.
A new detection algorithm (NDA) based on fuzzy cellular neural networks for white blood cell detection. 总被引:1,自引:0,他引:1
White blood cell detection is one of the most basic and key steps in the automatic recognition system of white blood cells in microscopic blood images. Its accuracy and stability greatly affect the operating speed and recognition accuracy of the whole system. But there are only a few methods available for cell detection or segmentation due to the complexity of the microscopic images. This paper focuses on this issue. Based on the detailed analysis of the existing two methods--threshold segmentation followed by mathematical morphology (TSMM), and the fuzzy logic method--a new detection algorithm (NDA) based on fuzzy cellular neural networks is proposed. NDA combines the advantages of TSMM and the fuzzy logic method, and overcomes their drawbacks. With NDA, we can detect almost all white blood cells, and the contour of each detected cell is nearly complete. Its adaptability is strong and the running speed is expected to be comparatively high due to the easy hardware implementation of FCN. Experimental results show good performance. 相似文献
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对三网互联的几个关键技术进行分析与研究,介绍利用IP技术解决有线电视网地址选择问题,探讨怎样将ATM技术与IP技术相互融合,使真正的信息高速公路成为现实,阐述利用H.323标准全面解决视频网络方案。 相似文献
9.
Min Song Weiying Zhu 《Communications Letters, IEEE》2004,8(7):479-481
This letter analyzes the saturated throughput for multicast switches with multiple input queues per input port. Under the assumptions of a Poisson uniform traffic model and random packet scheduling policy, we derive the multicast switch saturated throughput under different fanouts. To verify the analysis, extensive simulations are conducted with different switch sizes and fanouts. It is shown that the theoretical analysis and the simulation results have a discrepancy less than 1.9%. Results from this letter can be used as a guidance to design the optimal queuing for multicast switches. 相似文献
10.
浅谈如何有效学习计算机软件知识 总被引:1,自引:0,他引:1
黄霞 《湖南工业职业技术学院学报》2003,3(2):79-80
计算机软件知识的学习并不是完全线性的,而是不断循环往复、迭代的过程。本对如何深入、广泛、有效地学习计算机软件知识做出了一些探讨。 相似文献